An isoperimetric problem for leaky loops and related mean-chord inequalities

We consider a class of Hamiltonians in $L^2(\R^2)$ with attractive interaction supported by piecewise $C^2$ smooth loops $\Gamma$ of a fixed length $L$, formally given by $-\Delta-\alpha\delta(x-\Gamma)$ with $\alpha>0$. It is shown that the ground state of this operator is locally maximized by a circular $\Gamma$. We also conjecture that this property holds globally and show that the problem is related to an interesting family of geometric inequalities concerning mean values of chords of $\Gamma$.Comment: LaTeX, 16 page

Leaky quantum graphs: approximations by point interaction Hamiltonians

We prove an approximation result showing how operators of the type $-\Delta -\gamma \delta (x-\Gamma)$ in $L^2(\mathbb{R}^2)$, where $\Gamma$ is a graph, can be modeled in the strong resolvent sense by point-interaction Hamiltonians with an appropriate arrangement of the $\delta$ potentials. The result is illustrated on finding the spectral properties in cases when $\Gamma$ is a ring or a star. Furthermore, we use this method to indicate that scattering on an infinite curve $\Gamma$ which is locally close to a loop shape or has multiple bends may exhibit resonances due to quantum tunneling or repeated reflections.Comment: LaTeX 2e, 31 pages with 18 postscript figure

On the discrete spectrum of spin-orbit Hamiltonians with singular interactions

We give a variational proof of the existence of infinitely many bound states below the continuous spectrum for spin-orbit Hamiltonians (including the Rashba and Dresselhaus cases) perturbed by measure potentials thus extending the results of J.Bruening, V.Geyler, K.Pankrashkin: J. Phys. A 40 (2007) F113--F117.Comment: 10 pages; to appear in Russian Journal of Mathematical Physics (memorial volume in honor of Vladimir Geyler). Results improved in this versio

Bound states in point-interaction star-graphs

We discuss the discrete spectrum of the Hamiltonian describing a two-dimensional quantum particle interacting with an infinite family of point interactions. We suppose that the latter are arranged into a star-shaped graph with N arms and a fixed spacing between the interaction sites. We prove that the essential spectrum of this system is the same as that of the infinite straight "polymer", but in addition there are isolated eigenvalues unless N=2 and the graph is a straight line. We also show that the system has many strongly bound states if at least one of the angles between the star arms is small enough. Examples of eigenfunctions and eigenvalues are computed numerically.Comment: 17 pages, LaTeX 2e with 9 eps figure

Schrödinger operators with δ and δ′-potentials supported on hypersurfaces

Self-adjoint Schrödinger operators with δ and δ′-potentials supported on a smooth compact hypersurface are defined explicitly via boundary conditions. The spectral properties of these operators are investigated, regularity results on the functions in their domains are obtained, and analogues of the Birman–Schwinger principle and a variant of Krein’s formula are shown. Furthermore, Schatten–von Neumann type estimates for the differences of the powers of the resolvents of the Schrödinger operators with δ and δ′-potentials, and the Schrödinger operator without a singular interaction are proved. An immediate consequence of these estimates is the existence and completeness of the wave operators of the corresponding scattering systems, as well as the unitary equivalence of the absolutely continuous parts of the singularly perturbed and unperturbed Schrödinger operators. In the proofs of our main theorems we make use of abstract methods from extension theory of symmetric operators, some algebraic considerations and results on elliptic regularity

Boundary relations and generalized resolvents of symmetric operators

The Kre\u{\i}n-Naimark formula provides a parametrization of all selfadjoint exit space extensions of a, not necessarily densely defined, symmetric operator, in terms of maximal dissipative (in \dC_+) holomorphic linear relations on the parameter space (the so-called Nevanlinna families). The new notion of a boundary relation makes it possible to interpret these parameter families as Weyl families of boundary relations and to establish a simple coupling method to construct the generalized resolvents from the given parameter family. The general version of the coupling method is introduced and the role of boundary relations and their Weyl families for the Kre\u{\i}n-Naimark formula is investigated and explained.Comment: 47 page

A Survey on the Krein-von Neumann Extension, the corresponding Abstract Buckling Problem, and Weyl-Type Spectral Asymptotics for Perturbed Krein Laplacians in Nonsmooth Domains

In the first (and abstract) part of this survey we prove the unitary equivalence of the inverse of the Krein--von Neumann extension (on the orthogonal complement of its kernel) of a densely defined, closed, strictly positive operator, $S\geq \varepsilon I_{\mathcal{H}}$ for some $\varepsilon >0$ in a Hilbert space $\mathcal{H}$ to an abstract buckling problem operator. This establishes the Krein extension as a natural object in elasticity theory (in analogy to the Friedrichs extension, which found natural applications in quantum mechanics, elasticity, etc.). In the second, and principal part of this survey, we study spectral properties for $H_{K,\Omega}$, the Krein--von Neumann extension of the perturbed Laplacian $-\Delta+V$ (in short, the perturbed Krein Laplacian) defined on $C^\infty_0(\Omega)$, where $V$ is measurable, bounded and nonnegative, in a bounded open set $\Omega\subset\mathbb{R}^n$ belonging to a class of nonsmooth domains which contains all convex domains, along with all domains of class $C^{1,r}$, $r>1/2$.Comment: 68 pages. arXiv admin note: extreme text overlap with arXiv:0907.144

Copper-Mediated Amidation of Heterocyclic and Aromatic C−H Bonds

A copper-mediated aerobic coupling reaction enables direct amidation of heterocycles or aromatics having weakly acidic C−H bonds with a variety of nitrogen nucleophiles. These reactions provide efficient access to many biologically important skeletons, including ones with the potential to serve as inhibitors of HMTs.Chemistry and Chemical Biolog