Charging Ultra-nanoporous Electrodes with Size-asymmetric Ions Assisted by Apolar Solvent

We develop a statistical theory of charging quasi single-file pores with cations and anions of different sizes as well as solvent molecules or voids. This is done by mapping the charging onto a one-dimensional Blume–Emery–Griffith model with variable coupling constants. The results are supported by three-dimensional Monte Carlo simulations in which many limitations of the theory are lifted. We explore the different ways of enhancing the energy storage which depend on the competitive adsorption of ions and solvent molecules into pores, the degree of ionophilicity and the voltage regimes accessed. We identify new solvent-related charging mechanisms and show that the solvent can play the role of an “ionophobic agent”, effectively controlling the pore ionophobicity. In addition, we demonstrate that the ion-size asymmetry can significantly enhance the energy stored in a nanopore

The production of a non-homogeneous classical pion field and the distribution of the neutral and charged pions

The probability distribution $dw/df$ as a function of the ratio $f=n_0/n_{tot}$ of the neutral to total multiplicities is calculated for the classical pion fields quickly varying in space and time.Comment: 6 pages, 1 .eps figure, using epsfig, submitted to Phys.Let

The effects of numerical resolution on hydrodynamical surface convection simulations and spectral line formation

The computationally demanding nature of radiative-hydrodynamical simulations of stellar surface convection warrants an investigation of the sensitivity of the convective structure and spectral synthesis to the numerical resolution and dimension of the simulations, which is presented here. With too coarse a resolution the predicted spectral lines tend to be too narrow, reflecting insufficient Doppler broadening from the convective motions, while at the currently highest affordable resolution the line shapes have converged essentially perfectly to the observed profiles. Similar conclusions are drawn from the line asymmetries and shifts. In terms of abundances, weak FeI and FeII lines show a very small dependence (~0.02 dex) while for intermediate strong lines with significant non-thermal broadening the sensitivity increases (~0.10 dex). Problems arise when using 2D convection simulations to describe an inherent 3D phenomenon, which translates to inaccurate atmospheric velocity fields and temperature and pressure structures. In 2D the theoretical line profiles tend to be too shallow and broad compared with the 3D calculations and observations, in particular for intermediate strong lines. In terms of abundances, the 2D results are systematically about 0.1 dex lower than for the 3D case for FeI lines. Furthermore, the predicted line asymmetries and shifts are much inferior in 2D. Given these shortcomings and computing time considerations it is better to use 3D simulations of even modest resolution than high-resolution 2D simulations.Comment: Accepted for A&

Algebraic Properties of Valued Constraint Satisfaction Problem

The paper presents an algebraic framework for optimization problems expressible as Valued Constraint Satisfaction Problems. Our results generalize the algebraic framework for the decision version (CSPs) provided by Bulatov et al. [SICOMP 2005]. We introduce the notions of weighted algebras and varieties and use the Galois connection due to Cohen et al. [SICOMP 2013] to link VCSP languages to weighted algebras. We show that the difficulty of VCSP depends only on the weighted variety generated by the associated weighted algebra. Paralleling the results for CSPs we exhibit a reduction to cores and rigid cores which allows us to focus on idempotent weighted varieties. Further, we propose an analogue of the Algebraic CSP Dichotomy Conjecture; prove the hardness direction and verify that it agrees with known results for VCSPs on two-element sets [Cohen et al. 2006], finite-valued VCSPs [Thapper and Zivny 2013] and conservative VCSPs [Kolmogorov and Zivny 2013].Comment: arXiv admin note: text overlap with arXiv:1207.6692 by other author

Nasal lysine aspirin challenge in the diagnosis of aspirin - exacerbated respiratory disease

Background Aspirin-exacerbated respiratory disease is under-diagnosed and therefore effective and inexpensive therapy with aspirin desensitization is rarely performed. Methods We present an audit of 150 patients with difficult to treat nasal polyposis, 132 of whom also had asthma, 131 of whom underwent challenge with the only soluble form of aspirin, lysine aspirin (LAS), to confirm or exclude the diagnosis of aspirin-exacerbated respiratory disease (AERD). Results One hundred patients proved positive on nasal challenge, 31 who were negative went onto oral LAS challenge and a further 14 gave positive results, leaving 17 who were negative to a dose equivalent to over 375 mg of aspirin. Nineteen were not challenged because of contraindications. With the exception of one patient who developed facial angioedema and two patients with > 20% drop in FEV1 (following nasal plus oral challenge) no other severe adverse events occurred. No hospitalization was required for these three patients. Nasal inspiratory peak flow monitoring was less sensitive to obstruction caused by aspirin than was acoustic rhinometry – which should be employed when aspirin challenge is an outpatient procedure. Conclusions Provided patients are carefully chosen and monitored LAS challenge is suitable for ENT day case practice where respiratory physician help with asthma is available and should reduce the under-diagnosis of this condition

Odin observations of ammonia in the Sgr A +50 km/s Cloud and Circumnuclear Disk

Context. The Odin satellite is now into its sixteenth year of operation, much surpassing its design life of two years. One of the sources which Odin has observed in great detail is the Sgr A Complex in the centre of the Milky Way. Aims. To study the presence of NH3 in the Galactic Centre and spiral arms. Methods. Recently, Odin has made complementary observations of the 572 GHz NH3 line towards the Sgr A +50 km/s Cloud and Circumnuclear Disk (CND). Results. Significant NH3 emission has been observed in both the +50 km/s Cloud and the CND. Clear NH3 absorption has also been detected in many of the spiral arm features along the line of sight from the Sun to the core of our Galaxy. Conclusions. The very large velocity width (80 km/s) of the NH3 emission associated with the shock region in the southwestern part of the CND may suggest a formation/desorption scenario similar to that of gas-phase H2O in shocks/outflows.Comment: 5 pages, 3 figures, 3 table

Achievement flourishes in larger classes: Secondary school students in most countries achieved better literacy in larger classes

There is no consensus among academics about whether children benefit from smaller classes. We analysed the data from the 2012 Programme for International Student Assessment (PISA) to test if smaller classes lead to higher performance. Advantages of using this data set are not only its size (478,120 15-year old students in 63 nations) and representativeness but also that the 2012 PISA data set, for the first time, includes the class size for each participating child. We found that, in most countries, children in smaller classes had a lower performance score in solving reading comprehension problems than those in larger classes. We further analysed the relationship between class size and factors that can explain this paradoxical phenomenon. Although grouping of students by ability and the socioeconomic status of parents played some role in some countries, these factors cannot fully explain the effect. We finish by discussing the overlooked potential advantages of larger classes

Hortibot: Feasibility study of a plant nursing robot performing weeding operations – part IV

Based on the development of a robotic tool carrier (Hortibot) equipped with weeding tools, a feasibility study was carried out to evaluate the viability of this innovative technology. The feasibility was demonstrated through a targeted evaluation adapted to the obtainable knowledge on the system performance in horticulture. A usage scenario was designed to set the implementation of the robotic system in a row crop of seeded bulb onions considering operational and functional constraints in organic crop, production. This usage scenario together with the technical specifications of the implemented system provided the basis for the feasibility analysis, including a comparison with a conventional weeding system. Preliminary results show that the automation of the weeding tasks within a row crop has the potential of significantly reducing the costs and still fulfill the operational requirements set forth. The potential benefits in terms of operational capabilities and economic viability have been quantified. Profitability gains ranging from 20 to 50% are achievable through targeted applications. In general, the analyses demonstrate the operational and economic feasibility of using small automated vehicles and targeted tools in specialized production settings