Local Intensity Enhancements in Spherical Microcavities: Implications for Photonic Chemical and Biological Sensors

In this report, we summarize recent findings regarding the use spherical microcavities in the amplification of light that is inelastically scattered by either fluorescent or Raman-active molecules. This discussion will focus on Raman scattering, with the understanding that analogous processes apply to fluorescence. Raman spectra can be generated through the use of a very strong light source that stimulates inelastic light scattering by molecules, with the scattering occurring at wavelengths shifted from that of the source and being most prominent at shifts associated with the molecules natural vibrational frequencies. The Raman signal can be greatly enhanced by exposing a molecule to the intense electric fields that arise near surfaces (typically of gold or silver) exhibiting nanoscale roughness. This is known as surface-enhanced Raman scattering (SERS). SERS typically produces gain factors of 103 - 106, but under special conditions, factors of 1010 - 1014 have been achieved

Cascaded Photoenhancement: Implications for Photonic Chemical and Biological Sensors

Our analysis shows that coupling of gold nanoparticles to microspheres will evoke a cascading effect from the respective photoenhancement mechanisms. We refer to this amplification process as cascaded photoenhancement, and the resulting cavity amplification of surface-enhanced Raman scattering (SERS) and fluorescence as CASERS and CAF, respectively. Calculations, based on modal analysis of scattering and absorption by compound spheres, presented herein indicate that the absorption cross sections of metal nanoparticles immobilized onto dielectric microspheres can be greatly enhanced by cavity resonances in the microspheres without significant degradation of the resonators. Gain factors associated with CSP of 10(exp 3) - 10(exp 4) are predicted for realistic experimental conditions using homogenous microspheres. Cascaded surface photoenhancement thus has the potential of dramatically increasing the sensitivities of fluorescence and vibrational spectroscopies

Progress in visibility modeling

December 1992.Includes bibliographical references.The cross section for total scattering by a cluster of spheres is derived from an integration, over a closed spherical surface, of the scattered Poynting flux associated with the different pairs of spheres in the ensemble. With the use of the addition theorem for vector spherical harmonics, the integral can be evaluated analytically. The pair-wise cross sections can be rearranged into an expression for the scattering cross section of sphere aggregates which is analogous to that obtained from Lorenz-Mie theory for a single sphere. This latter formulation, however, is more difficult to treat numerically than is the summation over pair-wise cross sections. The cross section for total scattering by a cluster of spheres thus derived is applied to a study of the effects of scavenging and aggregation on the specific absorption of carbon. Results are presented for polarization- and orientation-dependent absorption cross sections of sulfate haze elements and cloud droplets with small carbon grains (spheres) attached to their surfaces. Soot typically occurs as aggregates of carbon spherules. In order to address the validity of certain assumptions that are made in the analysis of such structures by fractal theory, comparisons between the absorption cross sections of free carbon, linear chains, and tightly clumped carbon spheres are also provided. Monte Carlo integration of the radiative transfer equation is the technique most easily adapted to complex scattering geometries. It is demonstrated that the multidimensional integrals can be evaluated more accurately and more efficiently with quasi Monte Carlo integration and that the convergence of the multiple scattering series can be accelerated by estimating the rate of decay of the tail of the series. Each of these techniques has been found to be robust and applicable to scattering with any geometry.Research supported by DOE DE-FG02-90ER61067 & NPSNOAA-NPS-NA90RAH00077

Crafting a critical technical practice

In recent years, the category of practice-based research has become an essential component of discourse around public funding and evaluation of the arts in British higher education. When included under the umbrella of public policy concerned with the creative industries", technology researchers often find themselves collaborating with artists who consider their own participation to be a form of practice-based research. We are conducting a study under the Creator Digital Economies project asking whether technologists, themselves, should be considered as engaging in practice-based research, whether this occurs in collaborative situations, or even as a component of their own personal research [1]

Low Mass Printable Devices for Energy Capture, Storage, and Use for Space Exploration Missions

The energy-efficient, environmentally friendly technology that will be presented is the result of a Space Act Agreement between -Technologies Worldwide, Inc., and the National Aeronautics and Space Administration s (NASA s) Marshall Space Flight Center (MSFC). This work combines semiconductor and printing technologies to advance lightweight electronic and photonic devices having excellent potential for commercial and exploration applications, and is an example of industry and government cooperation that leads to novel inventions. Device development involves three energy generation and consumption projects: 1) a low mass efficient (low power, low heat emission) micro light-emitting diode (LED) area lighting device; 2) a low-mass omni-directional efficient photovoltaic (PV) device with significantly improved energy capture; and 3) a new approach to building supercapacitors. These three technologies - energy capture, storage, and usage (e.g., lighting) - represent a systematic approach for building efficient local micro-grids that are commercially feasible; furthermore, these same technologies will be useful for lightweight power generation that enables inner planetary missions using smaller launch vehicles and facilitates surface operations. The PV device model is a two-sphere, light-trapped sheet approximately 2-mm thick. The model suggests a significant improvement over current thin film systems. All three components may be printed in line by printing sequential layers on a standard screen or flexographic direct impact press using the threedimensional printing technique (3DFM) patented by NthDegree. MSFC is testing the robustness of prototype devices in the harsh space and lunar surface environments, and available results will be reported. Unlike many traditional light sources, this device does not contain toxic compounds, and the LED component has passed stringent off-gassing tests required for potential manifesting on spacecraft such as the International Space Station. Future exploration missions will benefit from "green" technology lighting devices such as this, which show great promise for both terrestrial use and space missions

Method of manufacturing a light emitting, photovoltaic or other electronic apparatus and system

The present invention provides a method of manufacturing an electronic apparatus, such as a lighting device having light emitting diodes (LEDs) or a power generating device having photovoltaic diodes. The exemplary method includes depositing a first conductive medium within a plurality of channels of a base to form a plurality of first conductors; depositing within the plurality of channels a plurality of semiconductor substrate particles suspended in a carrier medium; forming an ohmic contact between each semiconductor substrate particle and a first conductor; converting the semiconductor substrate particles into a plurality of semiconductor diodes; depositing a second conductive medium to form a plurality of second conductors coupled to the plurality of semiconductor diodes; and depositing or attaching a plurality of lenses suspended in a first polymer over the plurality of diodes. In various embodiments, the depositing, forming, coupling and converting steps are performed by or through a printing process

Star formation in Perseus: III. Outflows

We present a search for outflows towards 51 submillimetre cores in Perseus. With consistently derived outflow properties from a large homogeneous dataset within one molecular cloud we can investigate further the mass dependence and time evolution of protostellar mass loss. Of the 51 cores, 37 show broad linewings indicative of molecular outflows. In 13 cases, the linewings could be due to confusion with neighbouring flows but 9 of those sources also have near-infrared detections confirming their protostellar nature. The total fraction of protostars in our sample is 65%. All but four outflow detections are confirmed as protostellar by Spitzer IR detections and only one Spitzer source has no outflow, showing that outflow maps at this sensitivity are equally good at identifying protostars as Spitzer. Outflow momentum flux correlates both with source luminosity and with core mass but there is considerable scatter even within this one cloud despite the homogeneous dataset. We fail to confirm the result of Bontemps et al. (1996) that Class I sources show lower momentum fluxes on average than Class 0 sources, with a KS test showing a significant probability that the momentum fluxes for both Class 0s and Class Is are drawn from the same distribution. We find that outflow power may not show a simple decline between the Class 0 to Class I stages. Our sample includes low momentum flux, low-luminosity Class 0 sources, possibly at a very early evolutionary stage. If the only mass loss from the core were due to outflows, cores would last for 10^5-10^8 years, longer than current estimates of 1.5-4 x 10^5 years for the mean lifetime for the embedded phase. Additional mechanisms for removing mass from protostellar cores may be necessary.Comment: 26 pages, 21 figures. Version with full colour figures from http://www.astro.ex.ac.uk/people/hatchell/RecentPapers/hatchell07_outflows.pd

Light Emitting, Photovoltaic or Other Electronic Apparatus and System

The present invention provides an electronic apparatus, such as a lighting device comprised of light emitting diodes (LEDs) or a power generating apparatus comprising photovoltaic diodes, which may be created through a printing process, using a semiconductor or other substrate particle ink or suspension and using a lens particle ink or suspension. An exemplary apparatus comprises a base; at least one first conductor; a plurality of diodes coupled to the at least one first conductor; at least one second conductor coupled to the plurality of diodes; and a plurality of lenses suspended in a polymer deposited or attached over the diodes. The lenses and the suspending polymer have different indices of refraction. In some embodiments, the lenses and diodes are substantially spherical, and have a ratio of mean diameters or lengths between about 10:1 and 2:1. The diodes may be LEDs or photovoltaic diodes, and in some embodiments, have a junction formed at least partially as a hemispherical shell or cap

Light Emitting, Photovoltaic or Other Electronic Apparatus and System

The present invention provides an electronic apparatus, such as a lighting device comprised of light emitting diodes (LEDs) or a power generating apparatus comprising photovoltaic diodes, which may be created through a printing process, using a semiconductor or other substrate particle ink or suspension and using a lens particle ink or suspension. An exemplary apparatus comprises a base; at least one first conductor; a plurality of diodes coupled to the at least one first conductor; at least one second conductor coupled to the plurality of diodes; and a plurality of lenses suspended in a polymer deposited or attached over the diodes. The lenses and the suspending polymer have different indices of refraction. In some embodiments, the lenses and diodes are substantially spherical, and have a ratio of mean diameters or lengths between about 10:1 and 2:1. The diodes may be LEDs or photovoltaic diodes, and in some embodiments, have a junction formed at least partially as a hemispherical shell or cap

Method of Manufacturing a Light Emitting, Photovoltaic or Other Electronic Apparatus and System

The present invention provides a method of manufacturing an electronic apparatus, such as a lighting device having light emitting diodes (LEDs) or a power generating device having photovoltaic diodes. The exemplary method includes depositing a first conductive medium within a plurality of channels of a base to form a plurality of first conductors; depositing within the plurality of channels a plurality of semiconductor substrate particles suspended in a carrier medium; forming an ohmic contact between each semiconductor substrate particle and a first conductor; converting the semiconductor substrate particles into a plurality of semiconductor diodes; depositing a second conductive medium to form a plurality of second conductors coupled to the plurality of semiconductor diodes; and depositing or attaching a plurality of lenses suspended in a first polymer over the plurality of diodes. In various embodiments, the depositing, forming, coupling and converting steps are performed by or through a printing process