110 research outputs found
Detecting the local transport properties and the dimensionality of transport of epitaxial graphene by a multi-point probe approach
The electronic transport properties of epitaxial monolayer graphene (MLG) and
hydrogen-intercalated quasi free-standing bilayer graphene (QFBLG) on SiC(0001)
are investigated by micro multi-point probes. Using a probe with 12 contacts,
we perform four-point probe measurements with the possibility to effectively
vary the contact spacing over more than one order of magnitude, allowing us to
establish that the transport is purely two-dimensional. Combined with the
carrier density obtained by angle-resolved photoemission spectroscopy, we find
the room temperature mobility of MLG to be (870+-120)cm2/Vs. The transport in
QFBLG is also found to be two-dimensional with a mobility of (1600+-160)
cm2/Vs
Fabry-Perot enhanced Faraday rotation in graphene
We demonstrate that giant Faraday rotation in graphene in the terahertz range
due to the cyclotron resonance is further increased by constructive Fabry-Perot
interference in the supporting substrate. Simultaneously, an enhanced total
transmission is achieved, making this effect doubly advantageous for
graphene-based magneto-optical applications. As an example, we present
far-infrared spectra of epitaxial multilayer graphene grown on the C-face of
6H-SiC, where the interference fringes are spectrally resolved and a Faraday
rotation up to 0.15 radians (9{\deg}) is attained. Further, we discuss and
compare other ways to increase the Faraday rotation using the principle of an
optical cavity
FIGHTING FALSE INFORMATION - DESIGNING A CONVERSATIONAL AGENT FOR PUBLIC SECTOR ORGANIZATIONS
The digital transformation poses challenges for public sector organizations (PSOs) such as the dissemination of false information in social media which can cause uncertainty among citizens and decrease trust in the public sector. Some PSOs already successfully deploy conversational agents (CAs) to communicate with citizens and support digital service delivery. In this paper, we used design science research (DSR) to examine how CAs could be designed to assist PSOs in fighting false information online. We conducted a workshop with the municipality of Kristiansand, Norway to define objectives that a CA would have to meet for addressing the identified false information challenges. A prototypical CA was developed and evaluated in two iterations with the municipality and students from Norway. This research-in-progress paper presents findings and next steps of the DSR process. This research contributes to advancing the digital transformation of the public sector in combating false information problems
Ramifications of Optical Pumping on the Interpretation of Time-Resolved Photoemission Experiments on Graphene
In pump-probe time and angle-resolved photoemission spectroscopy (TR-ARPES)
experiments the presence of the pump pulse adds a new level of complexity to
the photoemission process in comparison to conventional ARPES. This is
evidenced by pump-induced vacuum space-charge effects and surface
photovoltages, as well as multiple pump excitations due to internal reflections
in the sample-substrate system. These processes can severely affect a correct
interpretation of the data by masking the out-of-equilibrium electron dynamics
intrinsic to the sample. In this study, we show that such effects indeed
influence TR-ARPES data of graphene on a silicon carbide (SiC) substrate. In
particular, we find a time- and laser fluence-dependent spectral shift and
broadening of the acquired spectra, and unambiguously show the presence of a
double pump excitation. The dynamics of these effects is slower than the
electron dynamics in the graphene sample, thereby permitting us to deconvolve
the signals in the time domain. Our results demonstrate that complex
pump-related processes should always be considered in the experimental setup
and data analysis.Comment: 9 pages, 4 figure
Surface Chemistry of the Molecular Solar Thermal Energy Storage System 2,3-Dicyano-Norbornadiene/Quadricyclane on Ni(111)
Molecular solar thermal (MOST) systems are a promising approach for the introduction of sustainable energy storage solutions. We investigated the feasibility of the dicyano-substituted norbornadiene/quadricyclane molecule pair on Ni(111) for catalytic model studies. This derivatization is known to lead to a desired bathochromic shift of the absorption maximum of the parent compound. In our experiments further favorable properties were found: At low temperatures, both molecules adsorb intact without any dissociation. In situ temperature-programmed HR-XPS experiments reveal the conversion of (CN)2-quadricyclane to (CN)2-norbornadiene under energy release between 175 and 260 K. The absence of other surface species due to side reactions indicates full isomerization. Further heating leads to the decomposition of the molecular framework into smaller carbonaceous fragments above 290 K and finally to amorphous structures, carbide and nitride above 400 K. DFT calculations gave insights into the adsorption geometries. (CN)2-norbornadiene is expected to interact stronger with the surface, with flat configurations being favorable. (CN)2-quadricyclane exhibits smaller adsorption energies with negligible differences for flat and side-on geometries. Simulated XP spectra are in good agreement with experimental findings further supporting the specific spectroscopic fingerprints for both valence isomers
Ultrafast Dynamics of Massive Dirac Fermions in Bilayer Graphene
Bilayer graphene is a highly promising material for electronic and
optoelectronic applications since it is supporting massive Dirac fermions with
a tuneable band gap. However, no consistent picture of the gap's effect on the
optical and transport behavior has emerged so far, and it has been proposed
that the insulating nature of the gap could be compromised by unavoidable
structural defects, by topological in-gap states, or that the electronic
structure could be altogether changed by many-body effects. Here we directly
follow the excited carriers in bilayer graphene on a femtosecond time scale,
using ultrafast time- and angle-resolved photoemission. We find a behavior
consistent with a single-particle band gap. Compared to monolayer graphene, the
existence of this band gap leads to an increased carrier lifetime in the
minimum of the lowest conduction band. This is in sharp contrast to the second
sub-state of the conduction band, in which the excited electrons decay through
fast, phonon-assisted inter-band transitions.Comment: 5 pages, 4 figure
Au-Catalyzed Energy Release in a Molecular Solar Thermal (MOST) System: A Combined Liquid-Phase and Surface Science Study
Molecular solar thermal systems (MOSTs) are molecular systems based on couples of photoisomers (photoswitches), which combine solar energy conversion, storage, and release. In this work, we address the catalytically triggered energy release in the promising MOST couple phenylethylesternorbornadiene/quadricyclane (PENBD/PEQC) on a Au(111) surface in a combined liquid-phase and surface science study. We investigated the system by photoelectrochemical infrared reflection absorption spectroscopy (PEC-IRRAS) in the liquid phase, conventional IRRAS and synchrotron radiation photoelectron spectroscopy (SRPES) in ultra-high vacuum (UHV). Au(111) is highly active towards catalytically triggered energy release. In the liquid phase, we did not observe any decomposition of the photoswitch, no deactivation of the catalyst within 100 conversion cycles and we could tune the energy release rate of the heterogeneously catalyzed process by applying an external potential. In UHV, submonolayers of PEQC on Au(111) are back-converted to PENBD instantaneously, even at 110 K. Multilayers of PEQC are stable up to ~220 K. Above this temperature, the intrinsic mobility of the film is high enough that PEQC molecules come into direct contact with the Au(111) surface, which catalyzes the back-conversion. We suggest that this process occurs via a singlet–triplet mechanism induced by electronic coupling between the PEQC molecules and the Au(111) surface
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