Optical and electrical activity of defects in rare earth implanted Si

A common technique for introducing rare earth atoms into Si and related materials for photonic applications is ion implantation. It is compatible with standard Si processing, and also allows high, non-equilibrium concentrations of rare earths to be introduced. However, the high energies often employed mean that there are collision cascades and potentially severe end-of-range damage. This paper reports on studies of this damage, and the competition it may present to the optical activity of the rare earths. Er-, Si, and Yb-implanted Si samples have been investigated, before and after anneals designed to restore the sample crystallinity. The electrical activity of defects in as-implanted Er, Si, and Yb doped Si has been studied by Deep Level Transient Spectroscopy (DTLS) and the related, high resolution technique, Laplace DLTS (LDLTS), as a function of annealing. Er-implanted Si, regrown by solid phase epitaxy at 600degrees C and then subject to a rapid thermal anneal, has also been studied by time-resolved photoluminescence (PL). The LDLTS studies reveal that there are clear differences in the defect population as a function of depth from the surface, and this is attributed to different defects in the vacancy-rich and interstitial-rich regions. Defects in the interstitial-rich region have electrical characteristics typical of small extended defects, and these may provide the precursors for larger structural defects in annealed layers. The time-resolved PL of the annealed layers, in combination with electron microscopy, shows that the Er emission at 1.54microns contains a fast component attributed to non-radiative recombination at deep states due to small dislocations. It is concluded that there can be measurable competition to the radiative efficiency in rare-earth implanted Si that is due to the implantation and is not specific to Er.</p

Sedimentary organic molecules: Origins and information content

To progress in the study of organic geochemistry, we must dissect the processes controlling the composition of sedimentary organic matter. Structurally, this has proven difficult. Individual biomarkers can often be recognized, but their contribution to total organic materials is small, and their presence does not imply that their biochemical cell mates have survived. We are finding, however, that a combination of structural and isotopic lines of evidence provides new information. A starting point is provided by the isotopic compositions of primary products (degradation products of chlorophylls, alkenones derived from coccoliths). We find strong evidence that the isotopic difference between primary carbonate and algal organic material can be interpreted in terms of the concentration of dissolved CO2. Moreover, the isotopic difference between primary and total organic carbon can be interpreted in terms of characteristic isotopic shifts imposed by secondary processes (responsive, for example, to O2 levels in the depositional environment. In favorable cases, isotopic compositions of a variety of secondary products can be interpreted in terms of flows of carbon, and, therefore, in terms of specific processes and environmental conditions within the depositional environment

Absolute absorption cross sections of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm

An account is given of progress of work on absorption cross section measurements of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm. In this wavelength region, the penetration of solar radiation into the Earth's atmosphere is controlled by O2 and O3. The transmitted radiation is available to dissociate trace species such as halocarbons and nitrous oxide. We have recently measured absolute absorption cross sections of O3 in the wavelength region 240-350 nm (Freeman et al., 1985; Yoshino et al., 1988). We apply these proven techniques to the determination of the absorption cross section of O3 at 300 K, 228 K and 195 K throughout the wavelength region 185-240 nm. A paper titled 'Absolute Absorption Cross Section Measurements of Ozone in the Wavelength Region 185-254 nm and the Temperature Dependence' has been submitted for publication in the Journal of Geophysical Research

Determination of spectroscopic properties of atmospheric molecules from high resolution vacuum ultraviolet cross section and wavelength measurements

Progress is given on work on: cross section measurements in the transmission window regions of the Schumann-Runge bands of oxygen; the determinations of predissociation linewidths; the theoretical calculation of band oscillator strengths of the Schumann-Runge absorption bands of O-16O-18; the determination of molecular spectroscopic constants; and the combined Herzberg continuum cross sections. The experimental investigations relevant to the cross section measurements, predissociation linewidths, and molecular spectroscopic constants are effected at high resolution with a 6.65 m scanning spectrometer which is, by virtue of its small instrumental width (FWHM = 0.0013 nm), suitable for cross section measurements of molecular bands with discrete rotational structure. Such measurements are needed for accurate calculations of the stratospheric production of atomic oxygen and heavy ozone formed following the photo-predissociation of O-16O-18 by solar radiation penetrating between the absorption lines of O-16(sub 2)

First-principles investigation of magnetism and electronic structures of substitutional 3d3d transition-metal impurities in bcc Fe

The magnetic and electronic structures of $3d$ impurity atoms from Sc to Zn in ferromagnetic body-centered cubic iron are investigated using the all-electron full-potential linearized augmented plane-wave method based on the generalized gradient approximation (GGA). We found that in general, the GGA results are closer to the experimental values than those of the local spin density approximation. The calculated formation enthalpy data indicate the importance of a systematic study on the ternary Fe-C-$X$ systems rather than the binary Fe-$X$ systems, in steel design. The lattice parameters are optimized and the conditions for spin polarization at the impurity sites are discussed in terms of the local Stoner model. Our calculations, which are consistent with previous work, imply that the local spin-polarizations at Sc, Ti, V, Cu, and Zn are induced by the host Fe atoms. The early transition-metal atoms couple antiferromagnetically, while the late transition-metal atoms couple ferromagnetically, to the host Fe atoms. The calculated total magnetization ($M$) of bcc Fe is reduced by impurity elements from Sc to Cr as a result of the antiferromagnetic interaction, with the opposite effect for solutes which couple ferromagnetically. The changes in $M$ are attributed to nearest neighbor interactions, mostly between the impurity and host atoms. The atom averaged magnetic moment is shown to follow generally the well-known Slater-Pauling curve, but our results do not follow the linearity of the Slater-Pauling curve. We attribute this discrepancy to the weak ferromagnetic nature of bcc Fe. The calculated Fermi contact hyperfine fields follow the trend of the local magnetic moments. The effect of spin-orbit coupling is found not to be significant although it comes into prominence at locations far from the impurity sites.Comment: 26 pages, 11 figure

Thin Films of 3He -- Implications on the Identification of 3 He -A

Recently the identification of 3He-A with the axial state has been questioned. It is suggested that the A-phase can actually be in the axiplanar state. We point out in the present paper that experiments in a film geometry may be useful to distinguish the above two possibilities. In particular a second order phase transition between an axial and an axiplanar state would occur as a function of thickness or temperature.Comment: 3 pages, no figures latex- revtex aps accepted by J. of Low Temperature Physic

Radiolysis of Macromolecular Organic Material in Mars-Relevant Mineral Matrices

The fate of organic material on Mars after deposition is crucial to interpreting the source of these molecules. Previous work has addressed how various organic compounds at millimeter depths in sediments respond to ultraviolet radiation. In contrast, this study addressed how highenergy particle radiation (200MeV protons, simulating the effect of galactic cosmic rays and solar wind at depths of <45 cm) inuences organic macromolecules in sediments. Specically, we report the generation of organicacid radiolysis products after exposure to radiation doses equivalent to geological time scales (17 Myr). We found that formate and oxalate were produced from a variety of organic starting materials and mineral matrices. Unlike ultravioletdriven reactions that can invoke Fenton chemistry to produce organic acids, our work suggests that irradiation of semiconductor surfaces, such as TiO2 or possible clay minerals found on Mars, forms oxygen and hydroxyl radical species, which can break down macromolecules into organic acids. We also investigated the metastability of benzoate in multiple mineral matrices. Benzoate was added to samples prior to irradiation and persisted up to 500 kGys of exposure. Our ndings suggest that organic acids are likely a major component of organic material buried at depth on Mars

The intrinsic strangeness and charm of the nucleon using improved staggered fermions

We calculate the intrinsic strangeness of the nucleon, - , using the MILC library of improved staggered gauge configurations using the Asqtad and HISQ actions. Additionally, we present a preliminary calculation of the intrinsic charm of the nucleon using the HISQ action with dynamical charm. The calculation is done with a method which incorporates features of both commonly-used methods, the direct evaluation of the three-point function and the application of the Feynman- Hellman theorem. We present an improvement on this method that further reduces the statistical error, and check the result from this hybrid method against the other two methods and find that they are consistent. The values for and found here, together with perturbative results for heavy quarks, show that dark matter scattering through Higgs-like exchange receives roughly equal contributions from all heavy quark flavors.Comment: 17 pages, 14 figure

Robust Logic Gates and Realistic Quantum Computation

The composite rotation approach has been used to develop a range of robust quantum logic gates, including single qubit gates and two qubit gates, which are resistant to systematic errors in their implementation. Single qubit gates based on the BB1 family of composite rotations have been experimentally demonstrated in a variety of systems, but little study has been made of their application in extended computations, and there has been no experimental study of the corresponding robust two qubit gates to date. Here we describe an application of robust gates to Nuclear Magnetic Resonance (NMR) studies of approximate quantum counting. We find that the BB1 family of robust gates is indeed useful, but that the related NB1, PB1, B4 and P4 families of tailored logic gates are less useful than initially expected.Comment: 6 pages RevTex4 including 5 figures (3 low quality to save space). Revised at request of referee and incorporting minor corrections and updates. Now in press at Phys Rev