2,632 research outputs found
The effect of shear on persistence in coarsening systems
We analytically study the effect of a uniform shear flow on the persistence
properties of coarsening systems. The study is carried out within the
anisotropic Ohta-Jasnow-Kawasaki (OJK) approximation for a system with
nonconserved scalar order parameter. We find that the persistence exponent
theta has a non-trivial value: theta = 0.5034... in space dimension d=3, and
theta = 0.2406... for d=2, the latter being exactly twice the value found for
the unsheared system in d=1. We also find that the autocorrelation exponent
lambda is affected by shear in d=3 but not in d=2.Comment: 6 page
Orientations of the lamellar phase of block copolymer melts under oscillatory shear flow
We develop a theory to describe the reorientation phenomena in the lamellar
phase of block copolymer melt under reciprocating shear flow. We show that
similar to the steady-shear, the oscillating flow anisotropically suppresses
fluctuations and gives rise to the parallel-perpendicular orientation
transition. The experimentally observed high-frequency reverse transition is
explained in terms of interaction between the melt and the shear-cell walls.Comment: RevTex, 3 pages, 1 figure, submitted to PR
The Crystal Structure of the Extracellular 11-heme Cytochrome UndA Reveals a Conserved 10-heme Motif and Defined Binding Site for Soluble Iron Chelates
Members of the genus Shewanella translocate deca- or undeca-heme cytochromes to the external cell surface thus enabling respiration using extracellular minerals and polynuclear Fe(III) chelates. The high resolution structure of the first undeca-heme outer membrane cytochrome, UndA, reveals a crossed heme chain with four potential electron ingress/egress sites arranged within four domains. Sequence and structural alignment of UndA and the deca-heme MtrF reveals the extra heme of UndA is inserted between MtrF hemes 6 and 7. The remaining UndA hemes can be superposed over the heme chain of the decaheme MtrF, suggesting that a ten heme core is conserved between outer membrane cytochromes. The UndA structure has also been crystallographically resolved in complex with substrates, an Fe(III)-nitrilotriacetate dimer or an Fe(III)-citrate trimer. The structural resolution of these UndA-Fe(III)-chelate complexes provides a rationale for previous kinetic measurements on UndA and other outer membrane cytochromes
Orientational phase transitions in the hexagonal phase of a diblock copolymer melt under shear flow
We generalize the earlier theory by Fredrickson [J. Rheol. v.38, 1045 (1994)]
to study the orientational behaviour of the hexagonal phase of diblock
copolymer melt subjected to steady shear flow. We use symmetry arguments to
show that the orientational ordering in the hexagonal phase is a much weaker
effect than in the lamellae. We predict the parallel orientation to be stable
at low and the perpendicular orientation at high shear rates. Our analysis
reproduces the experimental results by Tepe et al. [Macromolecules v.28, 3008
(1995)] and explains the difficulties in experimental observation of the
different orientations in the hexagonal phase.Comment: 21 pages, 6 eps figures, submitted to Physical Review
Exploring the biochemistry at the extracellular redox frontier of bacterial mineral Fe(III) respiration
Many species of the bacterial Shewanella genus are notable for their ability to respire in anoxic environments utilizing insoluble minerals of Fe(III) and Mn(IV) as extracellular electron acceptors. In Shewanella oneidensis, the process is dependent on the decahaem electron-transport proteins that lie at the extracellular face of the outer membrane where they can contact the insoluble mineral substrates. These extracellular proteins are charged with electrons provided by an inter-membrane electron-transfer pathway that links the extracellular face of the outer membrane with the inner cytoplasmic membrane and thereby intracellular electron sources. In the present paper, we consider the common structural features of two of these outer-membrane decahaem cytochromes, MtrC and MtrF, and bring this together with biochemical, spectroscopic and voltammetric data to identify common and distinct properties of these prototypical members of different clades of the outer-membrane decahaem cytochrome superfamily
Influence of confinement on the orientational phase transitions in the lamellar phase of a block copolymer melt under shear flow
In this work we incorporate some real-system effects into the theory of
orientational phase transitions under shear flow (M. E. Cates and S. T. Milner,
Phys. Rev. Lett. v.62, p.1856 (1989) and G. H. Fredrickson, J. Rheol. v.38,
p.1045 (1994)). In particular, we study the influence of the shear-cell
boundaries on the orientation of the lamellar phase. We predict that at low
shear rates the parallel orientation appears to be stable. We show that there
is a critical value of the shear rate at which the parallel orientation loses
its stability and the perpendicular one appears immediately below the spinodal.
We associate this transition with a crossover from the fluctuation to the
mean-field behaviour. At lower temperatures the stability of the parallel
orientation is restored. We find that the region of stability of the
perpendicular orientation rapidly decreases as shear rate increases. This
behaviour might be misinterpreted as an additional perpendicular to parallel
transition recently discussed in literature.Comment: 25 pages, 4 figures, submitted to Phys. Rev.
Singularities in ternary mixtures of k-core percolation
Heterogeneous k-core percolation is an extension of a percolation model which
has interesting applications to the resilience of networks under random damage.
In this model, the notion of node robustness is local, instead of global as in
uniform k-core percolation. One of the advantages of k-core percolation models
is the validity of an analytical mathematical framework for a large class of
network topologies. We study ternary mixtures of node types in random networks
and show the presence of a new type of critical phenomenon. This scenario may
have useful applications in the stability of large scale infrastructures and
the description of glass-forming systems.Comment: To appear in Complex Networks, Studies in Computational Intelligence,
Proceedings of CompleNet 201
- …