Inelastic fingerprints of hydrogen contamination in atomic gold wire systems

We present series of first-principles calculations for both pure and hydrogen contaminated gold wire systems in order to investigate how such impurities can be detected. We show how a single H atom or a single H2 molecule in an atomic gold wire will affect forces and Au-Au atom distances under elongation. We further determine the corresponding evolution of the low-bias conductance as well as the inelastic contributions from vibrations. Our results indicate that the conductance of gold wires is only slightly reduced from the conductance quantum G0=2e^2/h by the presence of a single hydrogen impurity, hence making it difficult to use the conductance itself to distinguish between various configurations. On the other hand, our calculations of the inelastic signals predict significant differences between pure and hydrogen contaminated wires, and, importantly, between atomic and molecular forms of the impurity. A detailed characterization of gold wires with a hydrogen impurity should therefore be possible from the strain dependence of the inelastic signals in the conductance.Comment: 5 pages, 3 figures, Contribution to ICN+T2006, Basel, Switzerland, July-August 200

The retina visual cycle is driven by cis retinol oxidation in the outer segments of cones

Vertebrate rod and cone photoreceptors require continuous supply of chromophore for regenerating their visual pigments after photoactivation. Cones, which mediate our daytime vision, demand a particularly rapid supply of 11-cis retinal chromophore in order to maintain their function in bright light. An important contribution to this process is thought to be the chromophore precursor 11-cis retinol, which is supplied to cones from Müller cells in the retina and subsequently oxidized to 11-cis retinal as part of the retina visual cycle. However, the molecular identity of the cis retinol oxidase in cones remains unclear. Here, as a first step in characterizing this enzymatic reaction, we sought to determine the subcellular localization of this activity in salamander red cones. We found that the onset of dark adaptation of isolated salamander red cones was substantially faster when exposing directly their outer vs. their inner segment to 9-cis retinol, an analogue of 11-cis retinol. In contrast, this difference was not observed when treating the outer vs. inner segment with 9-cis retinal, a chromophore analogue which can directly support pigment regeneration. These results suggest, surprisingly, that the cis-retinol oxidation occurs in the outer segments of cone photoreceptors. Confirming this notion, pigment regeneration with exogenously added 9-cis retinol was directly observed in the truncated outer segments of cones, but not in rods. We conclude that the enzymatic machinery required for the oxidation of recycled cis retinol as part of the retina visual cycle is present in the outer segments of cones

The Old Common Law and the New Trusts

T HE Civil Code of Porto Rico, our latest Roman American code, gives interesting proof of the fact that the two systems of law, the Roman and the English, which control most of the nations of the civilized world and their dependencies, are, in their essence, but slightly different enunciations of the same principles of natural justice. The parent of the Civil Code of Porto Rico1 is the Spanish Civil Code,2 in force in Spain since May I, 1889, and extended to Cuba, Porto Rico, and the Philippines on July 31, 1889. The Spanish Civil-Code is the result of the agitatio

Nanomechanics of a Hydrogen Molecule Suspended between Two Equally Charged Tips

Geometric configuration and energy of a hydrogen molecule centered between two point-shaped tips of equal charge are calculated with the variational quantum Monte-Carlo (QMC) method without the restriction of the Born-Oppenheimer (BO) approximation. Ground state nuclear distribution, stability, and low vibrational excitation are investigated. Ground state results predict significant deviations from the BO treatment that is based on a potential energy surface (PES) obtained with the same QMC accuracy. The quantum mechanical distribution of molecular axis direction and bond length at a sub-nanometer level is fundamental for understanding nanomechanical dynamics with embedded hydrogen. Because of the tips' arrangement, cylindrical symmetry yields a uniform azimuthal distribution of the molecular axis vector relative to the tip-tip axis. With approaching tips towards each other, the QMC sampling shows an increasing loss of spherical symmetry with the molecular axis still uniformly distributed over the azimuthal angle but peaked at the tip-tip direction for negative tip charge while peaked at the equatorial plane for positive charge. This directional behavior can be switched between both stable configurations by changing the sign of the tip charge and by controlling the tip-tip distance. This suggests an application in the field of molecular machines.Comment: 20 pages, 10 figure

Controlled Contact to a C60 Molecule

The conductance of C60 on Cu(100) is investigated with a low-temperature scanning tunneling microscope. At the transition from tunneling to the contact regime the conductance of C60 adsorbed with a pentagon-hexagon bond rises rapidly to 0.25 conductance quanta G0. An abrupt conductance jump to G0 is observed upon further decreasing the distance between the instrument's tip and the surface. Ab-initio calculations within density functional theory and non-equilibrium Green's function techniques explain the experimental data in terms of the conductance of an essentially undeformed C60. From a detailed analysis of the crossover from tunneling to contact we conclude that the conductance in this region is strongly affected by structural fluctuations which modulate the tip-molecule distance.Comment: 4 pages, 3 figure

Efficient UC Commitment Extension with Homomorphism for Free (and Applications)

Homomorphic universally composable (UC) commitments allow for the sender to reveal the result of additions and multiplications of values contained in commitments without revealing the values themselves while assuring the receiver of the correctness of such computation on committed values. In this work, we construct essentially optimal additively homomorphic UC commitments from any (not necessarily UC or homomorphic) extractable commitment. We obtain amortized linear computational complexity in the length of the input messages and rate 1. Next, we show how to extend our scheme to also obtain multiplicative homomorphism at the cost of asymptotic optimality but retaining low concrete complexity for practical parameters. While the previously best constructions use UC oblivious transfer as the main building block, our constructions only require extractable commitments and PRGs, achieving better concrete efficiency and offering new insights into the sufficient conditions for obtaining homomorphic UC commitments. Moreover, our techniques yield public coin protocols, which are compatible with the Fiat-Shamir heuristic. These results come at the cost of realizing a restricted version of the homomorphic commitment functionality where the sender is allowed to perform any number of commitments and operations on committed messages but is only allowed to perform a single batch opening of a number of commitments. Although this functionality seems restrictive, we show that it can be used as a building block for more efficient instantiations of recent protocols for secure multiparty computation and zero knowledge non-interactive arguments of knowledge

Error growth and dynamical vectors during southern hemisphere blocking

International audienceThe structural organization of initially random perturbations or "errors" evolving in a barotropic tangent linear model with time-dependent basic states taken from observations, is examined for cases of block development, maturation and decay in the Southern Hemisphere atmosphere during April, November and December 1989. We determine statistical results relating the structures of evolved errors to singular vectors (SVs), Lyapunov vectors (LVs) and finite-time normal modes (FTNMs). The statistics of 100 evolved error fields are studied for six day periods or longer and compared with the growth and structures of leading fast growing SVs, LVs and FTNMs. The SVs are studied in the kinetic energy (KE), enstrophy (EN) and streamfunction (SF) norms, while all FTNMs and the first LV are norm independent. The mean of the largest pattern correlations between the 100 error fields and dynamical vectors, taken over the five fastest growing SVs, in any of the three norms, or over the five fastest growing FTNMs, increases with increasing time interval to a value close to 0.6 after six days. Corresponding pattern correlations with the five fastest growing LVs are slightly lower. The leading dynamical vectors (SVs 1, FTNM1 or LV 1) generally, but not always, give the largest pattern correlations with the error fields. It is found that viscosity slightly increases the average correlations between the evolved errors and LV 1 and evolved SVs 1. Mean pattern correlations with fast growing dynamical vectors increase further for time intervals longer than six days. The properties of the dynamical vectors during Southern Hemisphere blocking are briefly outlined. After a few days integration, the structures of the leading evolved SVs in the KE, EN and SF norms, are in general quite similar and also similar to some of the dominant FTNMs that are norm independent. For optimization times of six days or less, the evolved SVs and FTNMs are, in general, different from the dominant LVs on the same day. Nevertheless, amplification factors of the first FTNMs and first LVs are very similar, and also similar to, but slightly larger than, the mean amplification factor of 100 initially random perturbations in the SF norm, while the amplification factors in the SF norm of KE SVs 1 and SF SV 1 are much higher. For longer optimization times, the first SVs and the first FTNM increasingly turn towards the leading LV with convergence achieved within a month

Estimating true age-dependence in survival when only adults can be observed: an example with Black-legged Kittiwakes

In long-lived birds, pre-breeders are often difficult or impossible to observe, and even though a proportion of marked adults may be of known age, the estimation of age-specific survival is complicated by the absence of observations during the first years of life. New developments in MARK now allow use of an updated individual covariate. We used this powerful approach to model age-dependence in survival of Black-legged Kittiwakes (Rissa tridactyla) at a North Sea colony. Although only 69 marked breeders were of known age, there was strong evidence for a quadratic relationship between true age and survival. We believe that this simple but powerful approach could be implemented for many species and could provide improved estimates of how survival changes with age, a central theme in life history theory

Engineering Negative Differential Conductance with the Cu(111) Surface State

Low-temperature scanning tunneling microscopy and spectroscopy are employed to investigate electron tunneling from a C60-terminated tip into a Cu(111) surface. Tunneling between a C60 orbital and the Shockley surface states of copper is shown to produce negative differential conductance (NDC) contrary to conventional expectations. NDC can be tuned through barrier thickness or C60 orientation up to complete extinction. The orientation dependence of NDC is a result of a symmetry matching between the molecular tip and the surface states.Comment: 5 pages, 4 figures, 1 tabl