Constant-length substitutions and countable scrambled sets

In this paper we provide examples of topological dynamical systems having either finite or countable scrambled sets. In particular we study conditions for the existence of Li-Yorke, asymptotic and distal pairs in constant--length substitution dynamical systems. Starting from a circle rotation we also construct a dynamical system having Li--Yorke pairs, none of which is recurrent

Novel Porous Polymorphs of Zinc Cyanide with Rich Thermal and Mechanical Behavior

We investigate the feasibility of four-connected nets as hypothetical zinc cyanide polymorphs, as well as their thermal and mechanical properties, through quantum chemical calculations and molecular dynamics simulations. We confirm the metastability of the two porous phases recently discovered experimentally (Lapidus, S. H.; et al. J. Am. Chem. Soc. 2013, 135, 7621-7628), suggest the existence of seven novel porous phases of Zn(CN)2, and show that isotropic negative thermal expansion is a common occurrence among all members of this family of materials, with thermal expansion coefficients close to that of the dense dia-c phase. In constrast, we find a wide variety in the mechanical behavior of these porous structures with framework-dependent anisotropic compressibilities. All porous structures, however, show pressure-induced softening leading to a structural transition at modest pressure.Comment: Chem. Mater. 201

Flows and heterogeneities with a vane tool: Magnetic resonance imaging measurements

We study the local flow properties of various materials in a vane-in-cup geometry. We use magnetic resonance imaging techniques to measure velocities and particle concentrations in flowing Newtonian fluid, yield stress fluid, and in a concentrated suspension of noncolloidal particles in a yield stress fluid. In the Newtonian fluid, we observe that the $\theta$-averaged strain rate component $d_{r,\theta}$ decreases as the inverse squared radius in the gap, in agreement with a Couette analogy. This allows direct comparison (without end-effect corrections) of the resistances to shear in vane and Couette geometries. Here, the mean shear stress in the vane-in-cup geometry is slightly lower than in a Couette cell of same dimensions, and a little higher than when the vane is embedded in an infinite medium. We also observe that the flow enters deeply the region between the blades, leading to significant extensional flow. In the yield stress fluid, in contrast with the usually accepted picture based on simulation results from the literature, we find that the layer of material that is sheared near the blades at low velocity is not cylindrical. There is thus a significant extensional component of shear that should be taken into account in the analysis. Finally and surprisingly, in the suspension, we observe that a thin non-cylindrical slip layer made of the pure interstitial yield stress fluid appears quickly at the interface between the sheared material and the material that moves as a rigid body between the blades. This feature can be attributed to the non-symmetric trajectories of the noncolloidal particles around the edges of the blades. This new important observation is in sharp contradiction with the common belief that the vane tool prevents slippage and may preclude the use of the vane tool for studying the flows of pasty materials with large particles

Unraveling radial dependency effects in fiber thermal drawing

Fiber-based devices with advanced functionalities are emerging as promising solutions for various applications in flexible electronics and bioengineering. Multimaterial thermal drawing, in particular, has attracted strong interest for its ability to generate fibers with complex architectures. Thus far, however, the understanding of its fluid dynamics has only been applied to single material preforms for which higher order effects, such as the radial dependency of the axial velocity, could be neglected. With complex multimaterial preforms, such effects must be taken into account, as they can affect the architecture and the functional properties of the resulting fiber device. Here, we propose a versatile model of the thermal drawing of fibers, which takes into account a radially varying axial velocity. Unlike the commonly used cross section averaged approach, our model is capable of predicting radial variations of functional properties caused by the deformation during drawing. This is demonstrated for two effects observed, namely, by unraveling the deformation of initially straight, transversal lines in the preform and the dependence on the draw ratio and radial position of the in-fiber electrical conductivity of polymer nanocomposites, an important class of materials for emerging fiber devices. This work sets a thus far missing theoretical and practical understanding of multimaterial fiber processing to better engineer advanced fibers and textiles for sensing, health care, robotics, or bioengineering applications

Revisiting Chase Termination for Existential Rules and their Extension to Nonmonotonic Negation

Existential rules have been proposed for representing ontological knowledge, specifically in the context of Ontology- Based Data Access. Entailment with existential rules is undecidable. We focus in this paper on conditions that ensure the termination of a breadth-first forward chaining algorithm known as the chase. Several variants of the chase have been proposed. In the first part of this paper, we propose a new tool that allows to extend existing acyclicity conditions ensuring chase termination, while keeping good complexity properties. In the second part, we study the extension to existential rules with nonmonotonic negation under stable model semantics, discuss the relevancy of the chase variants for these rules and further extend acyclicity results obtained in the positive case.Comment: This paper appears in the Proceedings of the 15th International Workshop on Non-Monotonic Reasoning (NMR 2014

Advances in freight transport demand modelling: an assessment with research perspectives

International audienceNumeric, spatialised models for the simulation of freight transport demand have long been inspired by the models for passenger demand. However, in recent years, specific methods have been developped to represent some aspects that are specific to freight transport, including the relationship between freight transport and logistics, and the specific techniques used to carry merchandises. These recent advances are presented, with a distinction of supply oriented models, demand oriented models, and equilibrium models. assessment oi

Construction sociale du changement en ergonomie et réseaux sociaux : vers une conduite de projet orientée "conception d'organisations capacitantes"

International audienceThe involvement of the actors of the company in the change processes encompasses various stakes in terms of efficiency of the workplaces and of workers' health. It is first proposed to describe the complexity and ambivalence of this participation. Then the authors describe the recent developments of ergonomics as regards social construction of change. Project management in ergonomics is based on several fundamentals, three of which are described: the articulation between the Client group and the Design group, the notion of Typical Action Situations, and the collective building of a shared representation of the future work. In a third part, the authors underline the current limitations of social dialogue in France, and propose to consider that a future work centred project management may be a pertinent alternative to some highly debatable forms of implication of workers in the change processes.L'implication des acteurs de l'entreprise dans les changements qui la concerne revêt de nombreux enjeux en termes de d'efficacité des situations conçues et de santé pour les salariés. Les auteurs proposent dans un premier temps d'en identifier la complexité et l'ambivalence. Dans un second temps, les auteurs rappellent les récents développements en ergonomie dans la construction sociale du changement. La conduite de projet en ergonomie s'organise autour de fondamentaux dont trois sont rappelés par les auteurs : la distinction entre Maîtrise d'Ouvrage et Maîtrise d'oeuvre, la notion de Situation d'Action Caractéristique, et enfin la construction collective d'une représentation partagée du travail futur. Enfin, dans une troisième partie, les auteurs élargissent la discussion pour souligner les difficultés actuelles du "dialogue social" en France et souligner l'intérêt d'envisager la conduite de projet autour du travail futur comme une alternative pertinente à certaines formes contemporaines très discutables d'implication des salariés des entreprise françaises

Compiling for an Heterogeneous Vector Image Processor

International audienceWe present a new compilation strategy, implemented at a small cost, to optimize image applications developed on top of a high level image processing library for an heterogeneous processor with a vector image processing accelerator. The library provides the semantics of the image computations. The pipelined structure of the accelerator allows to compute whole expressions with dozens of elementary image instructions, but is constrained as intermediate image values cannot be extracted. We adapted standard compilation techniques to perform this task automatically. Our strategy is implemented in PIPS, a source-to-source compiler which greatly reduces the development cost as standard phases are reused and parameterized for the target. Experiments were run on the hardware functional simulator. We compile 1217 cases, from elementary tests to full applications. All are optimal but a few which are mostly within a mere accelerator call of optimality. Our contribu- tions include: 1) a general low cost compilation strategy for image processing applications, based on the semantics provided by library calls, which improves locality by an order of magnitude; 2) a specific heuristic to minimize execution time on the target vector accelerator; 3) numerous experiments that show the effectiveness of our strategy

Toxicokinetics of fumonisin B1 in turkey poults and tissue persistence after exposure to a diet containing the maximum European tolerance for fumonisins in avian feeds

The kinetic of fumonisin B1 (FB1) after a single IV and oral dose, and FB1 persistence in tissue were investigated in turkey poults by HPLC after purification of samples on columns. After IV administration (single-dose: 10 mg FB1/kg bw), serum concentration–time curves were best described by a three-compartment open model. Elimination half-life and mean residence time of FB1 were 85 and 52 min, respectively. After oral administration (single-dose: 100 mg FB1/kg bw) bioavailability was 3.2%; elimination half-life and mean residence time were 214 and 408 min, respectively. Clearance of FB1 was 7.6 and 7.5 ml/min/kg for IV and oral administration respectively. Twenty four hours after the administration of FB1 by the intravenous route, liver and kidney contained the highest levels of FB1 in tissues, level in muscle was low or below the limit of detection (LD, 13 µg/kg). The persistence of FB1 in tissue was also studied after administration for nine weeks of a feed that contained 5, 10 and 20 mg FB1+FB2/kg diet. Eight hours after the last intake of 20 mg FB1+FB2/kg feed (maximum recommended concentration of fumonisins established by the EU for avian feed), hepatic and renal FB1 concentrations were 119 and 22 µg/kg, level in muscles was below the LD