55 research outputs found
Metalloids in origin and evolution of life
Metalloids in origin and evolution of life. Metalloids have characteristics between metals and non-metals which give them, in some cases, specific properties. At least two of this chemical elements, boron and silicon, are essential to a significant number of living organisms and since some years ago it has been observed that the same metalloids may be involved in the synthesis and stabilization of some molecules relevant to the origin of life
Two approaches to the study of the origin of life.
This paper compares two approaches that attempt to explain the origin of life, or biogenesis. The more established approach is one based on chemical principles, whereas a new, yet not widely known approach begins from a physical perspective. According to the first approach, life would have begun with - often organic - compounds. After having developed to a certain level of complexity and mutual dependence within a non-compartmentalised organic soup, they would have assembled into a functioning cell. In contrast, the second, physical type of approach has life developing within tiny compartments from the beginning. It emphasises the importance of redox reactions between inorganic elements and compounds found on two sides of a compartmental boundary. Without this boundary, ¿life¿ would not have begun, nor have been maintained; this boundary - and the complex cell membrane that evolved from it - forms the essence of life
Atom Transfer Oxidative Radical Cascade of Aryl Alkynoates towards 1,1‐Dichalcogenide Olefins
D-aminoácidos em biologia: mais do que se julga
It is still frequently referred, even in reference text-books, that the D-enantiomers of amino acids are not present in living organisms, which is not right. In the present revision/informative paper we describe a large number of D-amino acids that are present in all forms of organisms, from bacteria to human beings, in the free state, in peptides and in proteins, and give a short overview of their characteristics, physiological interaction and roles
Activation of Organonitriles toward β-Electrophilic Attack. Synthesis and Characterization of Methyleneamide (Azavinylidene) Complexes of Rhenium
Evidence for a Michaelis−Menten Type Mechanism in the Electrocatalytic Oxidation of Mercaptopropionic Acid by an Amavadine
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