Palladium-catalyzed coupling of functionalized primary and secondary amines with aryl and heteroaryl halides: two ligands suffice in most cases

We report our studies on the use of two catalyst systems, based on the ligands BrettPhos and RuPhos, which provide the widest scope for Pd-catalyzed C–N cross-coupling reactions to date. Often low catalyst loadings and short reaction times can be used with functionalized aryl and heteroaryl coupling partners. The reactions are highly robust and can be set up and performed without the use of a glovebox. These catalysts should find wide application in the synthesis of complex molecules including pharmaceuticals, natural products and functional materials.Amgen Inc.National Institutes of Health (U.S.) (Grant GM-58160)American Chemical SocietyBoehringer IngelheimNational Science Foundation (U.S.) (CHE 9808061)National Science Foundation (U.S.) (DBI 9729592

THE SCARAB BEETLES (COLEOPTERA : SCARABAEIDAE) OF PARQUE BICENTENARIO, EL SALVADOR

Parque Bicentenario in the Area Natural Protegida El Espino-Bosque Los Pericos, considered the "last green lung of San Salvador", is the most important forested area in central El Salvador. We performed a survey to provide the first inventory of scarab beetles (Scarabaeidae) of the park. Collections were conducted monthly for one year (August 2018-July 2019) by using baited pitfall, aerial, and ultraviolet light traps. Four subfamilies, nine tribes, 14 genera, 20 species (8% of the total richness of the family in El Salvador), and 1,584 individuals were captured. The most abundantly collected species in the park were the scarabaeines Onthophagus batesi Howden and Cartwright, Onthophagus belorhinus (Bates), Dichotomius centralis (Harold), Coprophanaeus corythus (Harold), Dichotomius yucatanus (Bates), and Coprophanaeus boucardi (Nevinson).Peer reviewe

Dark septate endophytic fungi associated with sugarcane plants cultivated in São Paulo, Brazil.

Dark septate endophytes (DSEs) constitute a polyphyletic group within the Ascomycota, with global distribution and a wide range of host plant species. The present study evaluated the diversity of DSE in sugarcane roots of the varieties RB867515, RB966928, and RB92579, and four varieties of not commercialized energy cane. A total of 16 DSE strains were isolated, mostly from the varieties RB966928 and RB867515, with six and five isolates, respectively. Just one of the four energy cane varieties had fungi with DSE appearance. The analyses of the DNA sequences from the internal transcribed spacer (ITS) and the large subunit (LSU), in association with the micromorphology of the isolates, allowed the differentiation of the 16 isolates in at least five species, within the families Periconiaceae, Pleosporaceae, Lentitheciaceae, Vibrisseaceae, and Apiosporaceae and the orders Pleosporales, Helotiales, and Xylariales. The order Pleosporales represented 80% of the isolates, and the species Periconia macrospinosa, with six isolates, accounted for the highest isolation frequency. The results confirm the natural occurrence of the DSE symbiosis in sugarcane varieties and the generalist character of these fungi as some of the detected species have already been reported associated with other host plants, ecosystems, and regions of the world

Abundance of White-fronted Parrots and diet of an urban parrot assemblage (Aves: Psittaciformes) in a green Neotropical city

Peer reviewe

Evryscope and K2 Constraints on TRAPPIST-1 Superflare Occurrence and Planetary Habitability

The nearby ultracool dwarf TRAPPIST-1 possesses several Earth-sized terrestrial planets, three of which have equilibrium temperatures that may support liquid surface water, making it a compelling target for exoplanet characterization. TRAPPIST-1 is an active star with frequent flaring, with implications for the habitability of its planets. Superflares (stellar flares whose energy exceeds 10^33 erg) can completely destroy the atmospheres of a cool star's planets, allowing ultraviolet radiation and high-energy particles to bombard their surfaces. However, ultracool dwarfs emit little ultraviolet flux when quiescent, raising the possibility of frequent flares being necessary for prebiotic chemistry that requires ultraviolet light. We combine Evryscope and Kepler observations to characterize the high-energy flare rate of TRAPPIST-1. The Evryscope is an array of 22 small telescopes imaging the entire Southern sky in g' every two minutes. Evryscope observations, spanning 170 nights over 2 years, complement the 80-day continuous short-cadence K2 observations by sampling TRAPPIST-1's long-term flare activity. We update TRAPPIST-1's superflare rate, finding a cumulative rate of 4.2 (+1.9 -0.2) superflares per year. We calculate the flare rate necessary to deplete ozone in the habitable-zone planets' atmospheres, and find that TRAPPIST-1's flare rate is insufficient to deplete ozone if present on its planets. In addition, we calculate the flare rate needed to provide enough ultraviolet flux to power prebiotic chemistry. We find TRAPPIST-1's flare rate is likely insufficient to catalyze some of the Earthlike chemical pathways thought to lead to RNA synthesis, and flux due to flares in the biologically relevant UV-B band is orders of magnitude less for any TRAPPIST-1 planet than has been experienced by Earth at any time in its history.Comment: 12 pages, 9 figures. Accepted to The Astrophysical Journal, in pres

Evryscope and K2 Constraints on TRAPPIST-1 Superflare Occurrence and Planetary Habitability

The nearby ultracool dwarf TRAPPIST-1 possesses several Earth-sized terrestrial planets, three of which have equilibrium temperatures that may support liquid surface water, making it a compelling target for exoplanet characterization. TRAPPIST-1 is an active star with frequent flaring, with implications for the habitability of its planets. Superflares (stellar flares whose energy exceeds 1033 erg) can completely destroy the atmospheres of a cool star's planets, allowing ultraviolet radiation and high-energy particles to bombard their surfaces. However, ultracool dwarfs emit little ultraviolet flux when quiescent, raising the possibility of frequent flares being necessary for prebiotic chemistry that requires ultraviolet light. We combine Evryscope and Kepler observations to characterize the high-energy flare rate of TRAPPIST-1. The Evryscope is an array of 22 small telescopes imaging the entire Southern sky in g' every two minutes. Evryscope observations, spanning 170 nights over 2 yr, complement the 80 day continuous short-cadence K2 observations by sampling TRAPPIST-1's long-term flare activity. We update TRAPPIST-1's superflare rate, finding a cumulative rate of 4.2−0.2+1.9 superflares per year. We calculate the flare rate necessary to deplete ozone in the habitable-zone planets' atmospheres, and find that TRAPPIST-1's flare rate is insufficient to deplete ozone if present on its planets. In addition, we calculate the flare rate needed to provide enough ultraviolet flux to power prebiotic chemistry. We find TRAPPIST-1's flare rate is likely insufficient to catalyze some of the Earthlike chemical pathways thought to lead to ribonucleic acid synthesis, and flux due to flares in the biologically relevant UV-B band is orders of magnitude less for any TRAPPIST-1 planet than has been experienced by Earth at any time in its history