Prediction of Room Temperature High Thermoelectric Performance in n-type La(Ru,Rh)4Sb12

First principles calculations are used to investigate the band structure and the transport related properties of unfilled and filled 4d skutterudite antimonides. The calculations show that, while RhSb3 and p-type La(Rh,Ru)4Sb12 are unfavorable for thermoelectric application, n-type La(Rh,Ru)4Sb12 is very likely a high figure of merit thermoelectric material in the important temperature range 150-300 K.Comment: 3 pages, 3 figures. To appear, Appl. Phys. Let

Deep-sea image processing

High-resolution seafloor mapping often requires optical methods of sensing, to confirm interpretations made from sonar data. Optical digital imagery of seafloor sites can now provide very high resolution and also provides additional cues, such as color information for sediments, biota and divers rock types. During the cruise AT11-7 of the Woods Hole Oceanographic Institution (WHOI) vessel R/V Atlantis (February 2004, East Pacific Rise) visual imagery was acquired from three sources: (1) a digital still down-looking camera mounted on the submersible Alvin, (2) observer-operated 1-and 3-chip video cameras with tilt and pan capabilities mounted on the front of Alvin, and (3) a digital still camera on the WHOI TowCam (Fornari, 2003). Imagery from the first source collected on a previous cruise (AT7-13) to the Galapagos Rift at 86°W was successfully processed and mosaicked post-cruise, resulting in a single image covering area of about 2000 sq.m, with the resolution of 3 mm per pixel (Rzhanov et al., 2003). This paper addresses the issues of the optimal acquisition of visual imagery in deep-seaconditions, and requirements for on-board processing. Shipboard processing of digital imagery allows for reviewing collected imagery immediately after the dive, evaluating its importance and optimizing acquisition parameters, and augmenting acquisition of data over specific sites on subsequent dives.Images from the deepsea power and light (DSPL) digital camera offer the best resolution (3.3 Mega pixels) and are taken at an interval of 10 seconds (determined by the strobe\u27s recharge rate). This makes images suitable for mosaicking only when Alvin moves slowly (≪1/4 kt), which is not always possible for time-critical missions. Video cameras provided a source of imagery more suitable for mosaicking, despite its inferiority in resolution. We discuss required pre-processing and imageenhancement techniques and their influence on the interpretation of mosaic content. An algorithm for determination of camera tilt parameters from acquired imagery is proposed and robustness conditions are discussed

Electronic Structure and Thermoelectric Prospects of Phosphide Skutterudites

The prospects for high thermoelectric performance in phosphide skutterudites are investigated based on first principles calculations. We find that stoichiometric CoP_3 differs from the corresponding arsenide and antimonide in that it is metallic. As such the band structure must be modified if high thermopowers are to be achieved. In analogy to the antimonides it is expected that this may be done by filling with La. Calculations for LaFe_4P_12 show that a gap can in fact be opened by La filling, but that the valence band is too light to yield reasonable p-type thermopowers at appropriate carrier densities; n-type La filled material may be more favorable.Comment: 3 pages, 3 figures, 1 tabl

Low temperature superlattice in monoclinic PZT

TEM has shown that the strongly piezoelectric material Pb(Zr0.52Ti0.48)O3 separates into two phases at low temperatures. The majority phase is the monoclinic phase previously found by x-ray diffraction. The minority phase, with a nanoscale coherence length, is a slightly distorted variant of the first resulting from the anti-phase rotation of the oxygen octahedra about [111]. This work clears up a recent controversy about the origin of superlattice peaks in these materials, and supports recent theoretical results predicting the coexistence of ferroelectric and rotational instabilities.Comment: REVTeX4, 4 eps figures embedded. JPG version of figs. 2&4 is also include

Angular momentum effects in weak gravitational fields

It is shown that, contrary to what is normally expected, it is possible to have angular momentum effects on the geometry of space time at the laboratory scale, much bigger than the purely Newtonian effects. This is due to the fact that the ratio between the angular momentum of a body and its mass, expressed as a length, is easily greater than the mass itself, again expressed as a length.Comment: LATEX, 8 page

Electronic, vibrational and transport properties of pnictogen substituted ternary skutterudites

First principles calculations are used to investigate electronic band structure and vibrational spectra of pnictogen substituted ternary skutterudites. We compare the results with the prototypical binary composition CoSb$_3$ to identify the effects of substitutions on the Sb site, and evaluate the potential of ternary skutterudites for thermoelectric applications. Electronic transport coefficients are computed within the Boltzmann transport formalism assuming a constant relaxation time, using a new methodology based on maximally localized Wannier function interpolation. Our results point to a large sensitivity of the electronic transport coefficients to carrier concentration and to scattering mechanisms associated with the enhanced polarity. The ionic character of the bonds is used to explain the detrimental effect on the thermoelectric properties

A very general rate expression for charge hopping in semiconducting polymers

We propose an expression of the hopping rate between localized states in semiconducting disordered polymers that contains the most used rates in the literature as special cases. We stress that these rates cannot be obtained directly from electron transfer rate theories as it is not possible to define diabatic localized states if the localization is caused by disorder, as in most polymers, rather than nuclear polarization effects. After defining the separate classes of accepting and inducing nuclear modes in the system, we obtain a general expression of the hopping rate. We show that, under the appropriate limits, this expression reduces to (i) single-phonon rate expression or (ii) the Miller-Abrahams rate or (iii) a multi-phonon expression. The description of these limits from a more general expression is useful to interpolate between them, to validate the assumptions of each limiting case, and to define the simplest rate expression that still captures the main features of the charge transport. When the rate expression is fed with a range of realistic parameters the deviation from the Miller-Abrahams rate is large or extremely large, especially for hopping toward lower energy states, due to the energy gap law

Correlation Between Volcanic and Tectonic Segmentation of Fast-Spreading Ridges: Evidence from Volcanic Structures and Lava Flow Morphology on the East Pacific Rise at 9˚-10˚N

Combined analyses of volcanic features in DSL-120 sonar data and Argo I images along the ridge crest of the East Pacific Rise, 9_090–540N reveal a consistent decrease in inferred lava effusion rate toward the ends of third-order segments. The correlation of tectonic segmentation and volcanic style suggests that third-order segmentation corresponds to the volcanic segmentation of the ridge. Along-axis changes in volcanic structures (from collapse troughs to basaltic lava domes) and lava morphology (from sheet to pillow flows) coincide with the boundaries of morphologically defined third order tectonic segments of the ridge crest visible in shipboard multibeam bathymetry. Pillow lava flows cover 25% of the surveyed area of the ridge crest and are closely associated with small lava domes that occur primarily at third-order segment ends. An additional 25% of the surveyed area of the ridge crest is covered by sheet lava flows found in close association with an axial collapse trough. The remaining terrain consists of lobate lava flows. We interpret the spatial correlations of morphologic, structural, seismic, and petrologic data as evidence that individual volcanic plumbing systems are organized at _20 km spacing along the ridge axis (third-order segment scale) in agreement with the hypothesis that volcanic and tectonic segmentations are correlated. For fast spreading ridges, we estimate that the longevity of volcanic segments is _104–105 years, 1–3 orders of magnitude longer than fourth-order segments (_102–103 years). This implies the present pattern of hydrothermal activity may reorganize tens or hundreds of times while volcanic segmentation remains fairly stable