Supercritical multicomponent solvent coal extraction

The yield of organic extract from the supercritical extraction of coal with larger diameter organic solvents such as toluene is increased by use of a minor amount of from 0.1 to 10% by weight of a second solvent such as methanol having a molecular diameter significantly smaller than the average pore diameter of the coal

Magnetic resonance peak and nonmagnetic impurities

Nonmagnetic Zn impurities are known to strongly suppress superconductivity. We review their effects on the spin excitation spectrum in $\rm YBa_2Cu_3O_{7}$, as investigated by inelastic neutron scattering measurements.Comment: Proceedings of Mato Advanced Research Workshop BLED 2000. To appear in Nato Science Series: B Physic

Pi excitation of the t-J model

In this paper, we present analytical and numerical calculations of the pi resonance in the t-J model. We show in detail how the pi resonance in the particle-particle channel couples to and appears in the dynamical spin correlation function in a superconducting state. The contribution of the pi resonance to the spin excitation spectrum can be estimated from general model-independent sum rules, and it agrees with our detailed calculations. The results are in overall agreement with the exact diagonalization studies of the t-J model. Earlier calculations predicted the correct doping dependence of the neutron resonance peak in the YBCO superconductor, and in this paper detailed energy and momentum dependence of the spin correlation function is presented. The microscopic equations of motion obtained within current formalism agree with that of the SO(5) nonlinear sigma model, where the pi resonance is interpreted as a pseudo Goldstone mode of the spontaneous SO(5) symmetry breaking.Comment: 33 pages, LATEX, 14 eps fig

Excitations in antiferromagnetic cores of superconducting vortices

We study excitations of the predicted antiferromagnetically ordered vortex cores in the superconducting phase of the newly proposed SO(5) model of strongly correlated electrons. Using experimental data from the literature we show that the susceptibilities in the spin sector and the charge sector are nearly equal, and likewise for the stiffnesses. In the case of strict equality SO(5) symmetry is possible, and we find that if present the vortices give rise to an enhanced neutron scattering cross section near the so called pi resonance at 41 meV. In the case of broken SO(5) symmetry two effects are predicted. Bound excitations can exist in the vortex cores with ``high'' excitation energies slightly below 41 meV, and the massless Goldstone modes corresponding to the antiferromagnetic ordering of the core can acquire a mass and show up as core excitation with ``low'' excitation energies around 2 meV.Comment: 9 pages, RevTeX, including 3 postscript figures, submitted to Phys. Rev. B, July 10, 199

What the resonance peak cannot do

In certain cuprates, a spin 1 resonance mode is prominent in the magnetic structure measured by neutron scattering. It has been proposed that this mode is responsible for significant features seen in other spectroscopies, such as photoemission and optical absorption, which are sensitive to the charge dynamics, and even that this mode is the boson responsibile for ``mediating'' the superconducting pairing. We show that its small (measured) intensity and weak coupling to electron-hole pairs (as deduced from the measured lifetime) disqualifies the resonant mode from either proposed role.Comment: 4 pages, no figur

Flavoured soft leptogenesis and natural values of the B term

We revisit flavour effects in soft leptogenesis relaxing the assumption of universality for the soft supersymmetry breaking terms. We find that with respect to the case in which the heavy sneutrinos decay with equal rates and equal CP asymmetries for all lepton flavours, hierarchical flavour configurations can enhance the efficiency by more than two orders of magnitude. This translates in more than three order of magnitude with respect to the one-flavour approximation. We verify that lepton flavour equilibration effects related to off-diagonal soft slepton masses are ineffective for damping these large enhancements. We show that soft leptogenesis can be successful for unusual values of the relevant parameters, allowing for $B\sim {\cal O}({\rm TeV})$ and for values of the washout parameter up to $m_{\rm eff}/m_* \sim 5\times 10^{3}$.Comment: 23 pages, 5 figures postscript, Minor changes to match the published version in JHE

Neutron scattering search for static magnetism in oxygen ordered YBa2Cu3O6.5

We present elastic and inelastic neutron scattering results on highly oxygen ordered YBa2Cu3O6.5 ortho-II. We find no evidence for the presence of ordered magnetic moments to a sensitivity of 0.003 Bohr magnetons, an order of magnitude smaller than has been suggested in theories of orbital or d-density-wave (DDW) currents. The absence of sharp elastic peaks, shows that the d-density-wave phase is not present, at least for the superconductor with the doping of 6.5 and the ordered ortho-II structure. We cannot exclude the possibility that a broad peak may exist with extremely short-range DDW correlations. For less ordered or more doped crystals it is possible that disorder may lead to static magnetism. We have also searched for the large normal state spin gap that is predicted to exist in an ordered DDW phase. Instead of a gap we find that the Q-correlated spin susceptibility persists to the lowest energies studied, 6 meV. Our results are compatible with the coexistence of superconductivity with orbital currents, but only if they are dynamic, and exclude a sharp phase transition to an ordered d-density-wave phase.Comment: 6 pages 4 figures RevTex Submitted to Phys Rev B January 23, 200

Quantum Gravity, the Origin of Time and Time's Arrow

The local Lorentz and diffeomorphism symmetries of Einstein's gravitational theory are spontaneously broken by a Higgs mechanism by invoking a phase transition in the early Universe, at a critical temperature $T_c$ below which the symmetry is restored. The spontaneous breakdown of the vacuum state generates an external time and the wave function of the Universe satisfies a time dependent Schrodinger equation, which reduces to the Wheeler-deWitt equation in the classical regime for $T < T_c$, allowing a semi-classical WKB approximation to the wave function. The conservation of energy is spontaneously violated for $T > T_c$ and matter is created fractions of seconds after the big bang, generating the matter in the Universe. The time direction of the vacuum expectation value of the scalar Higgs field generates a time asymmetry, which defines the cosmological arrow of time and the direction of increasing entropy as the Lorentz symmetry is restored at low temperatures.Comment: 37 page