37 research outputs found
The variable polarization undulator beamline UE52 SGM at BESSY II
UE52 SGM is an open port beamline with a monochromator containing 3 spherical gratings covering the energy range of 100 to 1500 eV and allows for variable polarization (circular and in any orientation linear) with a focus of about 20 - 60 μm (horizontal) x beamline slit (vertical) spot in focus
The nature of frontier orbitals under systematic ligand exchange in (pseudo-)octahedral Fe(II) complexes
Cuts through the manifold of molecular H2O potential energy surfaces in liquid water at ambient conditions
The fluctuating hydrogen bridge bonded network of liquid water at ambient conditions entails a varied ensemble of the underlying constituting H2O molecular moieties.This is mirrored in a manifold of the H2O molecular potentials. Subnatural line width resonant inelastic X-ray scattering allowed us to quantify the manifold of molecular potential energy surfaces along the H2O symmetric normal mode and the local asymmetric O–H bond coordinate up to 1 and 1.5 A, respectively. The comparison of the single ˚ H2O molecular potentials and spectroscopic signatures with the ambient conditions liquid phase H2O molecular potentials is done on various levels. In the gas phase, first principles, Morse potentials, and stepwise harmonic potential reconstruction have been employed and benchmarked. In the liquid phase the determination of the potential energy manifold along the local asymmetric O–H bond coordinate from resonant inelastic X-ray scattering via the bound state oxygen 1s to 4a1 resonance is treated within these frameworks. The potential energy surface manifold along the symmetric stretch from resonant inelastic X-ray scattering via the oxygen 1s to 2b2 resonance is based on stepwise harmonic reconstruction. We find in liquid water at ambient conditions H2O molecular potentials ranging from the weak interaction limit to strongly distorted potentials which are put into perspective to established parameters, i.e., intermolecular O–H, H–H, and O–O correlation lengths from neutron scattering.</p
Compatibility of quantitative X-ray spectroscopy with continuous distribution models of water at ambient conditions
The phase diagram of water harbors controversial views on underlying structural properties of its constituting molecular moieties, its fluctuating hydrogen-bonding network, as well as pair-correlation functions. In this work, long energy-range detection of the X-ray absorption allows us to unambiguously calibrate the spectra for water gas, liquid, and ice by the experimental atomic ionization cross-section. In liquid water, we extract the mean value of 1.74 +/- 2.1% donated and accepted hydrogen bonds per molecule, pointing to a continuous-distribution model. In addition, resonant inelastic X-ray scattering with unprecedented energy resolution also supports continuous distribution of molecular neighborhoods within liquid water, as do X-ray emission spectra once the femtosecond scattering duration and proton dynamics in resonant X-ray-matter interaction are taken into account. Thus, X-ray spectra of liquid water in ambient conditions can be understood without a two-structure model, whereas the occurrence of nanoscale-length correlations within the continuous distribution remains open
Synthesis and Characterisation of Ultra Thin Film Oxides for Energy Applications
This thesis describes studies of materials which can be exploited for hydrogen production from water and sunlight. The materials investigated are maghemite (γ-Fe2O3), magnetite (Fe3O4) and especially hematite (α-Fe2O3), which is an iron oxide with most promising properties in this field. Hematite has been deposited using Atomic Layer Deposition (ALD) - a thin-film technique facilitating layer-by-layer growth with excellent thickness control and step coverage. The iron oxides were deposited using bis-cyclopentadienyl iron (Fe(Cp)2) or iron pentacarbonyl (Fe(CO)5) in combination with an O2 precursor. Since it is crucial to have good control of the deposition process, the influence of substrate, process temperature, precursor and carrier gas have been investigated systematically. By careful control of these deposition parameters, three polymorphs of iron oxide could be deposited: hematite (α-Fe2O3), maghemite (γ-Fe2O3) and magnetite (Fe3O4). The deposited materials were characterized using X-ray Diffraction, Raman and UV-VIS Spectroscopy, and Scanning Electron Microscopy. Hard X-ray Photoelectron Spectroscopy (HAXPES) was also used, since it is a non-destructive, chemically specific, surface sensitive technique – the surface sensitivity resulting from the short mean escape depth of the photoelectrons. The depth probed can be controlled by varying the excitation energy; higher photoelectron energies increasing the inelastic mean-free-path in the material. HAXPES studies of atomic diffusion from F-doped SnO2 substrates showed increased doping levels of Sn, Si and F in the deposited films. Diffusion from the substrate was detected at annealing temperatures between 550 °C and 800 °C. Films annealed in air exhibited improved photocatalytic behavior; a photocurrent of 0.23 mA/cm2 was observed for those films, while the as-deposited hematite films showed no photo-activity whatsoever. The optical properties of low-dimensional hematite were studied in a series of ultra-thin films (thicknesses in the 2-70 nm range). The absorption maxima were shifted to higher energies for films thinner than 20 nm, revealing a different electronic structure in thin films
Synthesis and Characterisation of Ultra Thin Film Oxides for Energy Applications
This thesis describes studies of materials which can be exploited for hydrogen production from water and sunlight. The materials investigated are maghemite (γ-Fe2O3), magnetite (Fe3O4) and especially hematite (α-Fe2O3), which is an iron oxide with most promising properties in this field. Hematite has been deposited using Atomic Layer Deposition (ALD) - a thin-film technique facilitating layer-by-layer growth with excellent thickness control and step coverage. The iron oxides were deposited using bis-cyclopentadienyl iron (Fe(Cp)2) or iron pentacarbonyl (Fe(CO)5) in combination with an O2 precursor. Since it is crucial to have good control of the deposition process, the influence of substrate, process temperature, precursor and carrier gas have been investigated systematically. By careful control of these deposition parameters, three polymorphs of iron oxide could be deposited: hematite (α-Fe2O3), maghemite (γ-Fe2O3) and magnetite (Fe3O4). The deposited materials were characterized using X-ray Diffraction, Raman and UV-VIS Spectroscopy, and Scanning Electron Microscopy. Hard X-ray Photoelectron Spectroscopy (HAXPES) was also used, since it is a non-destructive, chemically specific, surface sensitive technique – the surface sensitivity resulting from the short mean escape depth of the photoelectrons. The depth probed can be controlled by varying the excitation energy; higher photoelectron energies increasing the inelastic mean-free-path in the material. HAXPES studies of atomic diffusion from F-doped SnO2 substrates showed increased doping levels of Sn, Si and F in the deposited films. Diffusion from the substrate was detected at annealing temperatures between 550 °C and 800 °C. Films annealed in air exhibited improved photocatalytic behavior; a photocurrent of 0.23 mA/cm2 was observed for those films, while the as-deposited hematite films showed no photo-activity whatsoever. The optical properties of low-dimensional hematite were studied in a series of ultra-thin films (thicknesses in the 2-70 nm range). The absorption maxima were shifted to higher energies for films thinner than 20 nm, revealing a different electronic structure in thin films
Surface modification of iron oxides by ion bombardment – comparing depth profiling by HAXPES and Ar ion sputtering
Iron oxide in the form of maghemite  γ-Fe2O3 and hematite α-Fe2O3 has been studied with x-ray photoelectron spectroscopy. It is found that even low energy sputtering induces a reduction of the surface layer into FeO. Satellites in the Fe 2p core level spectra are used to determine the oxidation state of iron. Depth profiling with changing photon energy shows that the unsputtered films are homogeneous and that the information obtained from sputtering thus, in this instance, represents sputter damages to the sample
HAXPES study of Sn core levels and their plasmon loss features
Hard X-ray Photoelectron spectra have been recorded for elemental Sn. Electron loss features, prominent in all core level spectra of the metal, are analyzed at several photo energies for the 3p core level. For higher photoelectron kinetic energies the intensity of the plasmonic features follows a simple exponential law. The data and models presented here will aid the modeling of spectra where tin is present and especially if its spectrum overlaps with those from other sources
HAXPES study of Sn core levels and their plasmon loss features
Hard X-ray Photoelectron spectra have been recorded for elemental Sn. Electron loss features, prominent in all core level spectra of the metal, are analyzed at several photo energies for the 3p core level. For higher photoelectron kinetic energies the intensity of the plasmonic features follows a simple exponential law. The data and models presented here will aid the modeling of spectra where tin is present and especially if its spectrum overlaps with those from other sources
Electrodeposited zinc oxide nanorods coated with atomic-layer-deposited hematite film
Poster presented at IPS-19, 2012.<br