Adsorbent filled membranes for gas separation. Part 1. Improvement of the gas separation properties of polymeric membranes by incorporation of microporous adsorbents

The effect of the introduction of specific adsorbents on the gas separation properties of polymeric membranes has been studied. For this purpose both carbon molecular sieves and zeolites are considered. The results show that zeolites such as silicate-1, 13X and KY improve to a large extent the separation properties of poorly selective rubbery polymers towards a mixture of carbon dioxide/methane. Some of the filled rubbery polymers achieve intrinsic separation properties comparable to cellulose acetate, polysulfone or polyethersulfone. However, zeolite 5A leads to a decrease in permeability and an unchanged selectivity. This is due to the impermeable character of these particles, i.e. carbon dioxide molecules cannot diffuse through the porous structure under the conditions applied. Using silicate-1 also results in an improvement of the oxygen/nitrogen separation properties which is mainly due to a kinetic effect. Carbon molecular sieves do not improve the separation performances or only to a very small extent. This is caused by a mainly dead-end (not interconnected) porous structure which is inherent to their manufacturing process

Membranes of semicrystalline aliphatic polyamide nylon 4,6: Formation by diffusion-induced phase separation

The preparation of membranes of nylon 4,6 by diffusion-induced phase separation (DIPS) using formic acid as a solvent and water as a nonsolvent was studied. Nylon 4,6 is a semi-crystalline polymer; phase separation from a solution can occur by solid-liquid (s-l) de-mixing as well as by liquid-liquid (l-l) demixing. Upon quenching films of solutions with low polymer concentration (< 17 wt %) in a nonsolvent bath containing water, the morphology of the membranes show a foam-like structure typical for l-l demixing. When phase separation is induced by water vapor a transition in structure occurs from the cellular type to a morphology typical for s-l phase separated films. At higher polymer concentrations membranes exhibit structures consisting of spheres or smaller crystal-like units resulting from an s-l phase separation process. The addition of 2 wt % or more of water to polymer solutions with low concentration (up to 15 wt %) resulted in s-l demixing as well. In a DIPS process s-l demixing is kinetically competitive with l-l demixing if nuclei are already present in the starting solutions (heterogeneous nucleation), or if a relatively long time is available for crystal nuclei to be formed. The morphology resulting from s-l demixing is a result of spherulitic crystallization. A certain concentration of nuclei or of precursor particles already present results in a small nucleation density during precipitation and thus large spherulites can be grown; at higher polymer and/or water concentrations the nucleation density increases resulting in an axialitic morphology of the membranes

A Comparison of Prospective Memory and Executive Processes in Patients with Subcortical Illness

Dementia is a common disorder affecting neuropsychological function in several spheres of mental activity including language memory, visuospatial function, and cognition. Studies into the cognitive deficits associated with dementia have allowed researchers to rank disorders into two subclasses: cortical and subcortical dementia. Cortical dementias such as Alzheimer\u27s disease have been the focus of a plethora of studies. Subcortical dementia, which is commonly found in Parkinson\u27s disease and Huntington\u27s disease patients, is marked by bradyphrenia, visuospatial abnormalities, personality alterations, memory disturbances primarily involving recall but not recognition, and loss of executive functions. The most recent disorder to be classified as a cause of subcortical dementia is Human Immunodeficiency Virus (HIV) infection. Several studies have focused on memory disturbances associated with HIV infection but few have looked at the affects of the disease on executive function. The current study examined executive functioning, immediate recall, and prospective memory in patients with HIV, HD, older adult controls, and younger adult controls. The young adults performed significantly higher than the older adults and the HIV group on the Color-Word score of the Stroop test. The HIV group did not perform significantly differently from either of the control groups on any of the other measures. A Huntington\u27s patient was analyzed using a case study method. The results suggest that HIV patients do not display significant signs of frontal mediated or executive function loss but several promising trends in the data are discussed. Further research is needed using larger group sizes and improving on several other limitations of the tests used in this study

Walmart Supercenters a suitable alternative to shopping at the commissary for eligible military patrons

MBA Professional ReportFrom 1961 to present day, Walmart has expanded its number of Supercenters to 3,336 locations throughout the continental United States, growing to be the most readily accessible grocer in the lower forty-eight states. This thesis will demonstrate that concentrated populations of active duty and retired military personnel are subject to shorter commutes when shopping at Walmart Supercenters rather than military commissaries. This thesis will further demonstrate that the average military base is closer to a Walmart than a military commissary and that the average number of Walmart Supercenters exceeds the number of commissaries within specific distances from military bases. With rising fuel costs and the number of Walmart Supercenters available nationwide, eligible commissary patrons may be less willing to drive long distances in order to save money on groceries. The closer and more convenient option may best serve the needs of the military customer. If better alternatives exist outside of the commissary, the government can reexamine the practicality of dedicating annual appropriations to the Defense Commissary Agency.http://archive.org/details/walmartsupercent1094544562Lieutenant, United States NavyLieutenant Commander, United States NavyApproved for public release; distribution is unlimited

Project Minerva: A low cost manned Mars mission based on indigenous propellant production

Project Minerva is a low-cost manned Mars mission designed to deliver a crew of four to the Martian surface using only two sets of two launches from the Kennedy Space Center. Key concepts which make this mission realizable are the use of near-term technologies and in-situ propellant production, following the scenario originally proposed by R. Zubrin. The first set of launches delivers two unmanned payloads into low Earth orbit (LEO): the first payload consists of an Earth Return Vehicle (ERV), a propellant production plant, and a set of robotic vehicles; the second payload consists of the trans-Mars injection (TMI) upper stage. In LEO, the two payloads are docked and the configuration is injected into a Mars transfer orbit. The landing on Mars is performed with the aid of multiple aerobraking maneuvers. On the Martian surface, the propellant production plant uses a Sabatier/electrolysis type process to combine nine tons of hydrogen with carbon dioxide from the Martian atmosphere to produce over a hundred tons of liquid oxygen and liquid methane, which are later used as the propellants for the rover expeditions and the manned return journey of the ERV. The systems necessary for the flights to and from Mars, as well as those needed for the stay on Mars, are discussed. These systems include the transfer vehicle design, life support, guidance and communications, rovers and telepresence, power generation, and propellant manufacturing. Also included are the orbital mechanics, the scientific goals, and the estimated mission costs

Preparation of zeolite filled glassy polymer membranes

The incorporation of zeolite particles in the micrometer range into polymeric matrices was investigated as a way to improve the gas separation properties of the polymer materials used in the form of membranes. The adhesion between the polymer phase and the external surface of the particles appeared to be a major problem in the preparation of such membranes when the polymer is in the glassy state at room temperature. Various methods were investigated to improve the internal membrane structure, that is, surface modification of the zeolite external surface, preparation above the glass-transition temperature, and heat treatment. Improved structures were obtained as observed by scanning electron microscopy, but the influence on the gas separation properties was not in agreement with the observed structural improvements

The Potential Cost to New Zealand Dairy Farmers from the Introduction of Nitrate-Based Stocking Rate Restrictions

Introducing a stocking rate restriction is one possible course of action for regulators to improve water quality where it is affected by nitrate pollution. To determine the impact of a stocking rate restriction on a range of New Zealand dairy farms, a whole-farm model was optimised with and without a maximum stocking rate of 2.5 cows per hectare. Three farm systems, which differ by their level of feed-related capital, were examined for the changes to the optimal stocking rate and optimal level of animal milk production genetics when utility was maximised. The whole-farm model was optimised through the use of an evolutionary algorithm called differential evolution. The introduction of a stocking rate restriction would have a very large impact on the optimally organised high feed-related capital farm systems, reducing their certainty equivalent by almost half. However, there was no impact on the certainty equivalent of low feed-related capital systems.environmental regulation, dairy farms, whole-farm model, evolutionary algorithm, Environmental Economics and Policy, Livestock Production/Industries, Q12, Q52, C61,

Fine specificity of antigen binding to two class I major histocompatibility proteins (B*2705 and B*2703) differing in a single amino acid residue

Starting from the X-ray structure of a class I majorhistocompatibility complex (MHC)-encoded protein (HLA-B*2705), a naturallypresented self-nonapeptide and two synthetic analogues were simulated in thebinding groove of two human leukocyte antigen (HLA) alleles (B*2703 andB*2705) differing in a single amino acid residue. After 200 ps moleculardynamics simulations of the solvated HLA-peptide pairs, some molecularproperties of the complexes (distances between ligand and protein center ofmasses, atomic fluctuations, buried versus accessible surface areas,hydrogen-bond frequencies) allow a clear discrimination of potent from weakMHC binders. The binding specificity of the three nonapeptides for the twoHLA alleles could be explained by the disruption of one hydrogen-bondingnetwork in the binding pocket of the HLA-B*2705 protein where the singlemutation occurs. Rearrangements of interactions in the B pocket, which bindsthe side chain of peptidic residue 2, and a weakening of interactionsinvolving the C-terminal end of the peptide also took place. In addition,extension of the peptide backbone using a β-Ala analogue did notabolish binding to any of the two HLA-B27 subtypes, but increased theselectivity for B*2703, as expected from the larger peptide binding groovein this subtype. A better understanding of the atomic details involved inpeptide selection by closely related HLA alleles is of crucial importancefor unraveling the molecular features linking particular HLA alleles toautoimmune diseases, and for the identification of antigenic peptidestriggering such pathologie