Improved calorimeter provides accurate thermal measurements of space batteries

Isothermal continuous flow calorimeter measures the thermal characteristics of space batteries undergoing typical orbital cycling. This is 28 times as sensitive as calorimeters previously used

Research into fundamental phenomena associated with spacecraft electrochemical devices - calorimetry of nickel-cadmium cells Progress report, 1 Oct. 1966 - 31 Dec. 1966

Cycling, charge efficiency, and transducer studies with nickel-cadmium cell for spacecraft power supply system

Dual task impairments in vascular dementia

Several studies have shown that people with Alzheimer's disease (AD) demonstrate difficulties in doing two things at once or 'dual-tasking' and that this dual task impairment is insensitive to normal ageing, chronic depression or prodromal conditions like Mild Cognitive Impairment. It is not known, however, if this impairment is specific to AD, or also present in other dementias, such as vascular dementia (VaD). In this study 15 people with VaD, 25 healthy age-matched and 25 healthy young controls were assessed using a paper and pencil dual tasking paradigm and several measures of working and episodic memory. Age had no effect on dual task performance, but the VaD patients demonstrated a significant impairment in dual tasking ability. Performance on the memory measures was instead affected by age with a further deterioration in the VaD patients. Both dual tasking and memory ability were significantly correlated with disease severity, as assessed by the MMSE. These results indicate that performance on the dual task could be a specific indicator of pathological ageing

Nanocrystal dispersed amorphous alloys

Compositions and methods for obtaining nanocrystal dispersed amorphous alloys are described. A composition includes an amorphous matrix forming element (e.g., Al or Fe); at least one transition metal element; and at least one crystallizing agent that is insoluble in the resulting amorphous matrix. During devitrification, the crystallizing agent causes the formation of a high density nanocrystal dispersion. The compositions and methods provide advantages in that materials with superior properties are provided

Rotational Dynamics of Organic Cations in CH3NH3PbI3 Perovskite

Methylammonium lead iodide (CH3NH3PbI3) based solar cells have shown impressive power conversion efficiencies of above 20%. However, the microscopic mechanism of the high photovoltaic performance is yet to be fully understood. Particularly, the dynamics of CH3NH3+ cations and their impact on relevant processes such as charge recombination and exciton dissociation are still poorly understood. Here, using elastic and quasi-elastic neutron scattering techniques and group theoretical analysis, we studied rotational modes of the CH3NH3+ cation in CH3NH3PbI3. Our results show that, in the cubic (T > 327K) and tetragonal (165K < T < 327K) phases, the CH3NH3+ ions exhibit four-fold rotational symmetry of the C-N axis (C4) along with three-fold rotation around the C-N axis (C3), while in orthorhombic phase (T < 165K) only C3 rotation is present. Around room temperature, the characteristic relaxation times for the C4 rotation is found to be ps while for the C3 rotation ps. The -dependent rotational relaxation times were fitted with Arrhenius equations to obtain activation energies. Our data show a close correlation between the C4 rotational mode and the temperature dependent dielectric permittivity. Our findings on the rotational dynamics of CH3NH3+ and the associated dipole have important implications on understanding the low exciton binding energy and slow charge recombination rate in CH3NH3PbI3 which are directly relevant for the high solar cell performance

Identification of Electron Donor States in N-doped Carbon Nanotubes

Nitrogen doped carbon nanotubes have been synthesized using pyrolysis and characterized by Scanning Tunneling Spectroscopy and transmission electron microscopy. The doped nanotubes are all metallic and exhibit strong electron donor states near the Fermi level. Using tight-binding and ab initio calculations, we observe that pyridine-like N structures are responsible for the metallic behavior and the prominent features near the Fermi level. These electron rich structures are the first example of n-type nanotubes, which could pave the way to real molecular hetero-junction devices.Comment: 5 pages, 4 figures, revtex, submitted to PR

Low Carbon Abundance in Type Ia Supernovae

We investigate the quantity and composition of unburned material in the outer layers of three normal Type Ia supernovae (SNe Ia): 2000dn, 2002cr and 20 04bw. Pristine matter from a white dwarf progenitor is expected to be a mixture of oxygen and carbon in approximately equal abundance. Using near-infrared (NIR, 0.7-2.5 microns) spectra, we find that oxygen is abundant while carbon is severely depleted with low upper limits in the outer third of the ejected mass. Strong features from the OI line at rest wavelength = 0.7773 microns are observed through a wide range of expansion velocities approx. 9,000 - 18,000 km/s. This large velocity domain corresponds to a physical region of the supernova with a large radial depth. We show that the ionization of C and O will be substantially the same in this region. CI lines in the NIR are expected to be 7-50 times stronger than those from OI but there is only marginal evidence of CI in the spectra and none of CII. We deduce that for these three normal SNe Ia, oxygen is more abundant than carbon by factors of 100 - 1,000. MgII is also detected in a velocity range similar to that of OI. The presence of O and Mg combined with the absence of C indicates that for these SNe Ia, nuclear burning has reached all but the extreme outer layers; any unburned material must have expansion velocities greater than 18,000 km/s. This result favors deflagration to detonation transition (DD) models over pure deflagration models for SNe Ia.Comment: accepted for publication in Ap