Radiative corrections to the Dalitz plot of K_{l3}^\pm decays

We calculate the model-independent radiative corrections to the Dalitz plot of K_{l3}^\pm decays to order (\alpha/\pi)(q/M_1), where q is the momentum transfer and M_1 is the mass of the kaon. The final results are presented, first, with the triple integration over the variables of the bremsstrahlung photon ready to be performed numerically and, second, in an analytical form. These two forms are useful to crosscheck on one another and with other calculations. This paper is organized to make it accessible and reliable in the analysis of the Dalitz plot of precision experiments and is not compromised to fixing the form factors at predetermined values. It is assumed that the real photons are kinematically discriminated. Otherwise, our results have a general model-independent applicability.Comment: RevTex4, 38 pages, 5 figures, 5 tables; some typos corrected; discussion extended to compare with other result

Radiative corrections to all charge assignments of heavy quark baryon semileptonic decays

In semileptonic decays of spin-1/2 baryons containing heavy quarks up to six charge assignments for the baryons and lepton are possible. We show that the radiative corrections to four of these possibilities can be directly obtained from the final results of the two possibilities previously studied. There is no need to recalculate integrals over virtual or real photon momentum or any traces.Comment: 15 pages, 2 figures, RevTex. Extended discussion. Final version to appear in Physical Review

Numerical precision radiative corrections to the Dalitz plot of baryon semileptonic decays including the spin-momentum correlation of the decaying and emitted baryons

We calculate the radiative corrections to the angular correlation between the polarization of the decaying and the direction of the emitted spin one-half baryons in the semileptonic decay mode. The final results are presented, first, with the triple integration of the bremsstrahlung photon ready to be performed numerically and, second, in an analytical form. A third presentation of our results in the form of numerical arrays of coefficients to be multiplied by the quadratic products of form factors is discussed. This latter may be the most practical one to use in Monte Carlo simulations. A series of crosschecks is performed. Previous results to order (alpha/pi)(q/M_1) for the decays of unpolarized baryons are reviewed, too, where q is the momentum transfer and M_1 is the mass of the decaying baryon. This paper is self-contained and organized to make it accessible and reliable in the analysis of the Dalitz plot of precision experiments involving heavy quarks and is not compromised to fixing the form factors at predetermined values. It is assumed that the real photons are kinematically discriminated. Otherwise, our results have a general model-independent applicability.Comment: 34 pages, 4 tables, no figures. Some sections have been shortened. Conclusions remain unchange

Kinematic study of planetary nebulae in NGC 6822

By measuring precise radial velocities of planetary nebulae (which belong to the intermediate age population), H II regions, and A-type supergiant stars (which are members of the young population) in NGC 6822, we aim to determine if both types of population share the kinematics of the disk of H I found in this galaxy. Spectroscopic data for four planetary nebulae were obtained with the high spectral resolution spectrograph Magellan Inamori Kyocera Echelle (MIKE) on the Magellan telescope at Las Campanas Observatory. Data for other three PNe and one H II region were obtained from the SPM Catalog of Extragalactic Planetary Nebulae which employed the Manchester Echelle Spectrometer attached to the 2.1m telescope at the Observatorio Astron\'omico Nacional, M\'exico. In the wavelength calibrated spectra, the heliocentric radial velocities were measured with a precision better than 5-6 km s$^{-1}$. Data for three additional H II regions and a couple of A-type supergiant stars were collected from the literature. The heliocentric radial velocities of the different objects were compared to the velocities of the H i disk at the same position. From the analysis of radial velocities it is found that H II regions and A-type supergiants do share the kinematics of the H I disk at the same position, as expected for these young objects. On the contrary, planetary nebula velocities differ significantly from that of the H I at the same position. The kinematics of planetary nebulae is independent from the young population kinematics and it is closer to the behavior shown by carbon stars, which are intermediate-age members of the stellar spheroid existing in this galaxy. Our results are confirming that there are at least two very different kinematical systems in NGC 6822

Improvement of scanning tunneling microscopy resolution with H-sensitized tips

Recent scanning tunneling hydrogen microscopy (STHM) experiments on PTCDA (perylene-3,4,9,10- tetracarboxylic-3,4,9,10-dianhydride)/Au(111) have shown unprecedented intramolecular and intermolecular spatial resolution. The origin of this resolution is studied using an accurate STHM theoretical simulation technique that includes a detailed description of the electronic structure of both the tip and sample. Our results show that H2 molecules are dissociated on the Au tip; the adsorbed H atoms change the density of states at the Fermi level (EF) of the tip, increasing its p-orbital character and reducing the s-orbital contribution. Also, due to the interaction with the H-decorated tip, EF is shifted to the middle of the PTCDA lowest unoccupied molecular orbital peak, increasing dramatically the density of states of the sample at EF. These effects give rise to the enhanced STHM resolutionThis work is supported by Spanish MICIIN under Contract No. FIS2010-16046, the CAM under Contract No. S2009/MAT-1467, and the European Project MINOTOR (Grant No. FP7-NMP-228424). J. I. M. acknowledges funding from Spanish MICINN through Juan de la Cierva Program, E. A. the financial support by Consejería de Educación de la CAM, FSE, and European Project MINOTOR, and C. G. the CSIC JA

Biorefineries: Achievements and challenges for a bio-based economy

Funding This work was supported by a project (FQM-176) financed by the Junta de Andalucía. FM-M, acknowledges the support from the Global Challenges Research Fund from Swansea University, and from the Royal Society of Chemistry Enablement Grant (E21-7051491439).Climate change, socioeconomical pressures, and new policy and legislation are driving a decarbonization process across industries, with a critical shift from a fossil-based economy toward a biomass-based one. This new paradigm implies not only a gradual phasing out of fossil fuels as a source of energy but also a move away from crude oil as a source of platform chemicals, polymers, drugs, solvents and many other critical materials, and consumer goods that are ubiquitous in our everyday life. If we are to achieve the United Nations’ Sustainable Development Goals, crude oil must be substituted by renewable sources, and in this evolution, biorefineries arise as the critical alternative to traditional refineries for producing fuels, chemical building blocks, and materials out of non-edible biomass and biomass waste. State-of-the-art biorefineries already produce cost-competitive chemicals and materials, but other products remain challenging from the economic point of view, or their scaled-up production processes are still not sufficiently developed. In particular, lignin’s depolymerization is a required milestone for the success of integrated biorefineries, and better catalysts and processes must be improved to prepare bio-based aromatic simple molecules. This review summarizes current challenges in biorefinery systems, while it suggests possible directions and goals for sustainable development in the years to come.Project (FQM-176) financed by the Junta de AndalucíaGlobal Challenges Research Fund from Swansea UniversityRoyal Society of Chemistry Enablement Grant (E21-7051491439

C6H6/Au(111): Interface dipoles, band alignment, charging energy, and van der Waals interaction

The following article appeared in Journal of Chemical Physics 134.4 (2011): 044701 and may be found at http://scitation.aip.org/content/aip/journal/jcp/134/4/10.1063/1.3521271.We analyze the benzene/Au(111) interface taking into account chargingenergy effects to properly describe the electronic structure of the interface and van der Waals interactions to obtain the adsorption energy and geometry. We also analyze the interface dipoles and discuss the barrier formation as a function of the metal work-function. We interpret our DFT calculations within the induced density of interface states (IDIS) model. Our results compare well with experimental and other theoretical results, showing that the dipole formation of these interfaces is due to the charge transfer between the metal and benzene, as described in the IDIS model.This work is supported by Spanish MICIIN under Contracts No. MAT2007-60966 and No. FIS2010-16046, the CAM under Contract No. S2009/MAT-1467, and the European Project MINOTOR (Grant No. FP7-NMP-228424). E.A. gratefully acknowledges financial support by the Consejería de Educación of the CAM and the FSE. J.I.M. acknowledges funding from Spanish MICINN through Juan de la Cierva Program

Bio-renewable enantioselective aldol reaction in natural deep eutectic solvents

Among the deep eutectic solvents (DES), natural deep eutectic solvents (NADES) formed by D-glucose and racemic malic acid are suitable media to perform the enantioselective L-proline catalyzed intermolecular aldol reaction, creating simultaneously and selectively a C–C bond and a new stereocenter. The scope of the reaction was found to be broad, with products being obtained with good levels of diastereo- and enantioselectivities. Furthermore, when the reaction was performed at a large scale, the catalyst together with the reaction media can be recovered by simple water extraction and reused at least three times affording similar results. Therefore, the use of NADES as reaction media to carry out a VOC-free selective process has been demonstrated for the first time. The process is clean, cheap, simple and scalable and meets most of the criteria to be considered as a sustainable and bio-renewable process, with the reaction media and catalyst arising directly from Nature.This work was supported by the University of Alicante (VIGROB-173 and UAUSTI13-09)

Surface modification of polyethylene terephthalate (PET) by corona discharge plasma

Surface modification of polyethylene terephthalate (PET) was studied by corona discharge plasma at different exposure times using air as working gas. The modification of the surface properties are characterized, those are morphology and wettability. Corona plasma treatment was found to modify the PET surface in both morphology and wettability. The corona discharge at atmospheric pressure is a heterogeneous with multiple current pulses, which generates an asymmetric pattern of erosion on the PET surface. The corona discharge treatment erodes the surface and therefore modifies the surface morphology. The roughness of the PET surface increases in the impact point of the corona discharge on the PET surface. An increase in the wettability of PET was also observed after corona discharge treatment at atmospheric pressure