Technical note: Introduction of a superconducting gravimeter as novel hydrological sensor for the Alpine research catchment Zugspitze

GFZ (German Research Centre for Geosciences) set up the Zugspitze Geodynamic Observatory Germany with a worldwide unique installation of a superconducting gravimeter at the summit of Mount Zugspitze on top of the Partnach spring catchment. This high alpine catchment is well instrumented, acts as natural lysimeter and has significant importance for water supply to its forelands, with a large mean annual precipitation of 2080ĝ€¯mm and a long seasonal snow cover period of 9 months, while showing a high sensitivity to climate change. However, regarding the majority of alpine regions worldwide, there is only limited knowledge on temporal water storage variations due to sparsely distributed hydrological and meteorological sensors and the large variability and complexity of signals in alpine terrain. This underlines the importance of well-equipped areas such as Mount Zugspitze serving as natural test laboratories for improved monitoring, understanding and prediction of alpine hydrological processes. The observatory superconducting gravimeter, OSG 052, supplements the existing sensor network as a novel hydrological sensor system for the direct observation of the integral gravity effect of total water storage variations in the alpine research catchment at Zugspitze. Besides the experimental set-up and the available data sets, the gravimetric methods and gravity residuals are presented based on the first 27 months of observations from 29 December 2018 to 31 March 2021. The snowpack is identified as being a primary contributor to seasonal water storage variations and, thus, to the gravity residuals with a signal range of up to 750ĝ€¯nms-2 corresponding to 1957ĝ€¯mm snow water equivalent measured with a snow scale at an altitude of 2420ĝ€¯m at the end of May 2019. Hydro-gravimetric sensitivity analysis reveal a snow-gravimetric footprint of up to 4ĝ€¯km distance around the gravimeter, with a dominant gravity contribution from the snowpack in the Partnach spring catchment. This shows that the hydro-gravimetric approach delivers representative integral insights into the water balance of this high alpine site. © Copyright

Two-Dimensional Molecular Patterning by Surface-Enhanced Zn-Porphyrin Coordination

In this contribution, we show how zinc-5,10,15,20-meso-tetradodecylporphyrins (Zn-TDPs) self-assemble into stable organized arrays on the surface of graphite, thus positioning their metal center at regular distances from each other, creating a molecular pattern, while retaining the possibility to coordinate additional ligands. We also demonstrate that Zn-TDPs coordinated to 3-nitropyridine display a higher tendency to be adsorbed at the surface of highly oriented pyrolytic graphite (HOPG) than noncoordinated ones. In order to investigate the two-dimensional (2D) self-assembly of coordinated Zn-TDPs, solutions with different relative concentrations of 3-nitropyridine and Zn-TDP were prepared and deposited on the surface of HOPG. STM measurements at the liquid-solid interface reveal that the ratio of coordinated Zn-TDPs over noncoordinated Zn-TDPs is higher at the n-tetradecane/HOPG interface than in n-tetradecane solution. This enhanced binding of the axial ligand at the liquid/solid interface is likely related to the fact that physisorbed Zn-TDPs are better binding sites for nitropyridines.

Sea level: measuring the bounding surfaces of the ocean

The practical need to understand sea level along the coasts, such as for safe navigation given the spatially variable tides, has resulted in tide gauge observations having the distinction of being some of the longest instrumental ocean records. Archives of these records, along with geological constraints, have allowed us to identify the century-scale rise in global sea level. Additional data sources, particularly satellite altimetry missions, have helped us to better identify the rates and causes of sea level rise and the mechanisms leading to spatial variability in the observed rates. Analysis of all of the data reveals the need for long-term and stable observation systems to assess accurately the regional changes as well as to improve our ability to estimate future changes in sea level. While information from many scientific disciplines is needed to understand sea level change, this paper focuses on contributions from geodesy and the role of the ocean’s bounding surfaces: the sea surface and the Earth’s crust

The relativistic precession of the orbits

The relativistic precession can be quickly inferred from the nonlinear polar orbit equation without actually solving it.Comment: Accepted for publication in Astrophysics & Space Scienc

Minimal clinically meaningful differences for the EORTC QLQ-C30 and EORTC QLQ-BN20 scales in brain cancer patients

Background: We aimed to determine the smallest changes in health-related quality of life (HRQoL) scores in the European Organisation for Research and Treatment of Cancer Quality of Life Questionnaire core 30 and the Brain Cancer Module (QLQ-BN20), which could be considered as clinically meaningful in brain cancer patients. Materials and methods: World Health Organisation performance status (PS) and mini-mental state examination (MMSE) were used as clinical anchors appropriate to related subscales to determine the minimal clinically important differences (MCIDs) in HRQoL change scores (range 0-100) in the QLQ-C30 and QLQ-BN20. A threshold of 0.2 standard deviation (SD) (small effect) was used to exclude anchor-based MCID estimates considered too small to inform interpretation. Results: Based on PS, our findings support the following integer estimates of the MCID for improvement and deterioration, respectively: physical (6, 9), role (14, 12), and cognitive functioning (8, 8); global health status (7, 4*), fatigue (12, 9), and motor dysfunction (4*, 5). Anchoring with MMSE, cognitive functioning MCID estimates for improvement and deterioration were (11, 2*) and for communication deficit were (9, 7). Estimates with asterisks were <0.2 SD and were excluded from our MCID range of 5-14. Conclusion: These estimates can help clinicians evaluate changes in HRQoL over time, assess the value of a health care intervention and can be useful in determining sample sizes in designing future clinical trial

Combination Service for Time-variable Gravity Fields: operational GRACE-FO combination and validation of Chinese GRACE time-series

The Combination Service for Time-variable Gravity Fields (COST-G) of the International Association of Geodesy (IAG) provides combined monthly gravity fields of its associated and partner Analysis Centers (ACs). In November 2020, the combination of monthly GRACE-FO gravity fields started its operational mode, providing consolidated L2 (spherical harmonics) and L3 (gridded and post-processed) products with a latency of currently 3 months. We present an overview and quality assessment of the available products. COST-G aims at the extension of its service to include further GRACE and GRACE-FO analysis centers. In January 2020 a collaboration with representatives of five Chinese ACs was initiated, who provided GRACE time-series according to the COST-G requirements. We present the results of a test combination with the Chinese AC models, including comparison and quality assessment of all contributing time-series and validation of the combined gravity fields