2,731 research outputs found

    Evidence of a structural anomaly at 14 K in polymerised CsC60

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    We report the results of a high-resolution synchrotron X-ray powder diffraction study of polymerised CsC60_{60} in the temperature range 4 to 40 K. Its crystal structure is monoclinic (space group I2/m), isostructural with RbC60_{60}. Below 14 K, a spontaneous thermal contraction is observed along both the polymer chain axis, aa and the interchain separation along [111], d1d_1. This structural anomaly could trigger the occurrence of the spin-singlet ground state, observed by NMR at the same temperature.Comment: 8 pages, 5 figures, submitte

    Bootstrapping navigation and path planning using human positional traces

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    Navigating and path planning in environments with limited a priori knowledge is a fundamental challenge for mobile robots. Robots operating in human-occupied environments must also respect sociocontextual boundaries such as personal workspaces. There is a need for robots to be able to navigate in such environments without having to explore and build an intricate representation of the world. In this paper, a method for supplementing directly observed environmental information with indirect observations of occupied space is presented. The proposed approach enables the online inclusion of novel human positional traces and environment information into a probabilistic framework for path planning. Encapsulation of sociocontextual information, such as identifying areas that people tend to use to move through the environment, is inherently achieved without supervised learning or labelling. Our method bootstraps navigation with indirectly observed sensor data, and leverages the flexibility of the Gaussian process (GP) for producing a navigational map that sampling based path planers such as Probabilistic Roadmaps (PRM) can effectively utilise. Empirical results on a mobile platform demonstrate that a robot can efficiently and socially-appropriately reach a desired goal by exploiting the navigational map in our Bayesian statistical framework. © 2013 IEEE

    Spin-driven Phase Transitions in ZnCr2_2Se4_4 and ZnCr2_2S4_4 Probed by High Resolution Synchrotron X-ray and Neutron Powder Diffraction

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    The crystal and magnetic structures of the spinel compounds ZnCr2_2S4_4 and ZnCr2_2Se4_4 were investigated by high resolution powder synchrotron and neutron diffraction. ZnCr2_2Se4_4 exhibits a first order phase transition at TN=21T_N=21 K into an incommensurate helical magnetic structure. Magnetic fluctuations above TNT_N are coupled to the crystal lattice as manifested by negative thermal expansion. Both, the complex magnetic structure and the anomalous structural behavior can be related to magnetic frustration. Application of an external magnetic field shifts the ordering temperature and the regime of negative thermal expansion towards lower temperatures. Thereby, the spin ordering changes into a conical structure. ZnCr2_2S4_4 shows two magnetic transitions at TN1=15T_{N1}=15 K and TN2=8T_{N2}=8 K that are accompanied by structural phase transitions. The crystal structure transforms from the cubic spinel-type (space group FdFd\={3}mm) at high temperatures in the paramagnetic state, via a tetragonally distorted intermediate phase (space group I41I4_1 / amdamd) for TN2<T<TN1T_{N2} < T < T_{N1} into a low temperature orthorhombic phase (space group ImmaI m m a) for T<TN2T < T_{N2}. The cooperative displacement of sulfur ions by exchange striction is the origin of these structural phase transitions. The low temperature structure of ZnCr2_2S4_4 is identical to the orthorhombic structure of magnetite below the Verwey transition. When applying a magnetic field of 5 T the system shows an induced negative thermal expansion in the intermediate magnetic phase as observed in ZnCr2_2Se4_4.Comment: 11 pages, 13 figures, to be published in PR

    Action at a distance: Dependency sensitivity in a New World primate

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    Sensitivity to dependencies (correspondences between distant items) in sensory stimuli plays a crucial role in human music and language. Here, we show that squirrel monkeys (Saimiri sciureus) can detect abstract, non-adjacent dependencies in auditory stimuli. Monkeys discriminated between tone sequences containing a dependency and those lacking it, and generalized to previously unheard pitch classes and novel dependency distances. This constitutes the first pattern learning study where artificial stimuli were designed with the species' communication system in mind. These results suggest that the ability to recognize dependencies represents a capability that had already evolved in humans' last common ancestor with squirrel monkeys, and perhaps before. © 2013 The Authors. Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/3.0/, which permits unrestricted use, provided the original author and source are credited

    Linear fuzzy gene network models obtained from microarray data by exhaustive search

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    BACKGROUND: Recent technological advances in high-throughput data collection allow for experimental study of increasingly complex systems on the scale of the whole cellular genome and proteome. Gene network models are needed to interpret the resulting large and complex data sets. Rationally designed perturbations (e.g., gene knock-outs) can be used to iteratively refine hypothetical models, suggesting an approach for high-throughput biological system analysis. We introduce an approach to gene network modeling based on a scalable linear variant of fuzzy logic: a framework with greater resolution than Boolean logic models, but which, while still semi-quantitative, does not require the precise parameter measurement needed for chemical kinetics-based modeling. RESULTS: We demonstrated our approach with exhaustive search for fuzzy gene interaction models that best fit transcription measurements by microarray of twelve selected genes regulating the yeast cell cycle. Applying an efficient, universally applicable data normalization and fuzzification scheme, the search converged to a small number of models that individually predict experimental data within an error tolerance. Because only gene transcription levels are used to develop the models, they include both direct and indirect regulation of genes. CONCLUSION: Biological relationships in the best-fitting fuzzy gene network models successfully recover direct and indirect interactions predicted from previous knowledge to result in transcriptional correlation. Fuzzy models fit on one yeast cell cycle data set robustly predict another experimental data set for the same system. Linear fuzzy gene networks and exhaustive rule search are the first steps towards a framework for an integrated modeling and experiment approach to high-throughput "reverse engineering" of complex biological systems
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