New Type of sub-THz Frequency-Doubling Gyro-TWT with Helically Corrugated Circuit

A novel type of frequency doubling gyrotron traveling wave amplifier (FD-GTWT) for applications that require high-power microwave in the sub-THz frequency range is presented. The proposed FD-GTWT delivers high power and high gain over a broad bandwidth and simultaneously doubling the frequency of the input signal. Simulations of a first 263GHz FD-GTWT design are presented, which show for a 10mW driving signal at 131.5GHz an RF output power of 250Wat 263 GHz and a gain of >40 dB over a bandwidth of 17.5 GHz. The basis of the FD-GTWT are two interaction circuits separated by a long drift section. In the first circuit, the electron beam is pre-bunched at the fundamental cyclotron harmonic. In the second one, high-power RF is induced by the pre-bunched electron beam at the 2nd cyclotron harmonic. Both sections consist of helically corrugated waveguides that efficiently suppress parasitic interactions and allow broad bandwidth

Time-Domain Simulation of Helical Gyro-TWTs With Coupled Modes Method and 3-D Particle Beam

A new self-consistent time-domain model for the simulation of gyrotron traveling-wave tubes with a helically corrugated interaction space (helical gyro-TWTs) is presented. The new model links classical methods using the approach of slowly varying variables together with an expansion of the electromagnetic field in eigenmodes and advanced full-wave particle-in-cell (PIC) solvers. The aim is to significantly reduce the required calculation time compared to full-wave PIC solvers, while less strict assumptions are introduced as in the classical approaches of slowly varying variables. For the first time, the classical theory of coupled circular waveguide modes for the description of the operating electromagnetic eigenmode in the helical interaction space is combined with a 3-D PIC representation of the electron beam. This allows the simulation of the beam–wave interaction over a broad bandwidth and at arbitrary harmonics of the cyclotron frequency. In addition, arbitrary electron beams (with spreads, offsets of the guiding center from the symmetry axis, and so on) can be investigated. The new approach is compared with the full-wave 3-D PIC code CST Microwave Studio. A good agreement of the simulation results is achieved, while the computing time is significantly reduced

Testing phosphanes in the palladium catalysed allylation of secondary and primary amines.

sous-presseThe electronic nature of the ligand plays a crucial role in the palladium-catalysed allylation of amines with allylic alcohols. The better the ligand is as a acceptor, the more active the catalyst. Experiments with a series with mono- and bidentate ligands featuring phosphanes and phospholes applied in the catalytic allylation of aniline clearly demonstrate this. Bolstered by DFT calculations, we have devised a new efficient catalyst for this process which carries the strong acceptor 1,2,5-triphenylphosphole as a ligand