Office paper recyclability: fibrous characteristics

Recyclability is the ability of a material to reacquire the same properties it had originally. The aim of this work was to verify the recyclability of three printing and writing papers, from the characteristics of their fibers after two recycles. Three ECF bleached kraft eucalyptus commercial bond papers from Argentina and Brazil were studied (A, B, C). The papers were repulped and refined using different levels and intensities of energy (1st recycle). Laboratory sheets were produced, and they were repulped and refined again (2nd recycle). The microscopic characteristics of repulped papers were obtained by automatic equipment based on image analysis. Differences found in the behavior of the different samples can be explained by fiber parameters. The fiber length was significantly different in the three papers (A > B > C) and globally decreased in the second recycle (about 6%). Sample A had the highest initial fiber length and length/width, but it largely decreased with refining conditions in the 1st recycle (length fall 12%, generating fines by cutting), whereas it fall 9% between the 1st and 2nd recycles, and nothing with refining conditions in the 2nd recycle. Sample B fall by 5% with refining conditions in the 1st recycle, and 9% between the 1st and the 2nd recycle, but suffered few alteration in the second recycle. Fiber length of sample C was unaffected by refining conditions and only decreased 9% between the 1st and 2nd recycles. In all cases, the generated fines increased lightly with refining in the first recycle, but were two-fold higher in the second recycle than in the first one. The fiber coarseness of the 3 samples was similar in the first recycle, but decreases significantly in the 2nd recycleFil: Benitez, Julieta Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Cs.exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Koga, Mariza E. T.. Instituto de Pesquisas Tecnologicas de Sao Paulo; BrasilFil: Otero D'Almeida, Maria L.. Instituto de Pesquisas Tecnologicas de Sao Paulo; BrasilFil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Cs.exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Park, Song W.. Universidade de Sao Paulo; BrasilFil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Cs.exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentin

Chemimechanical Pulping of Eucalyptus Grandis

Eucayptus is currently one of the main fibrous raw materials used in the pulp and paper industry in given parts of the world. The objective of the present paper is to optimize the chemimechanical pulping conditions for Eucalyptus grandis. evaluate the pulp quality obtained, and draw conclusions regarding its potential use. The raw material used was Eucalyptus grandis industrial chips obtained at a Celulosa Argentina mill in Puerto Piray, Misiones, Argentina. For all the experiments, the chemical stage was carried out in a stainless steel digester with a liquor recirculation system. The mechanical stage was carried out in an 8-in. atmospheric disk refiner. Sodium sulfite and sodium hydroxide were added as chemical reactives. The central composite experimental design used involved five levels for the two variables studied (LL factorial design + star + central point). Three repetitions of the central point were carried out to check for errors. The variables studied were: initial amount of sodium sulfite in the wood (0.9 to 3.5% oven-dry wood) and reaction temperature (96 to 124 C). Times until maximum temperature and time at maximum temperature were, respectively, 20 and 90 minutes. A constant level of sodium hydroxide was maintained in all the experiments (1.5% oven-dry wood). Pulp evaluation was carried out using the usual characterization techniques. Chemical and physical evaluations, including optical testing, were, for the most part, done in accordance with TAPPI procedures.The results obtained indicate that the central point of the design used in our research (110 C and 2.5% oven-dry wood sulfite), appears to represent the optimal conditions for the variables studied for the chemimechanical pulping of Eucalyptus grandis. The pulps obtained could be used as furnish in printing and writing paper grades. The positive correlation between sulfonate concentration and water retention value (WRV) suggests that by increasing fiber wall swelling, the number of sites accessible to sulfonation is increased. The tensile index correlates positively with the degree of sulfonation and with the water retention value of the pulps. It decreases according to the fraction retained in a 30-mesh screen (due to the presence of numerous shives) and increases according to the fraction of fines passing through a 270-mesh screen

Optimization of the properties of poplar and willow chemimechanical pulps by a mixture design of juvenile and mature wood

Forest plantations of Salicaceae (poplars and willows) in Argentina are mainly used for the manufacture of pulp for newsprint. The rapid growth of these species results in a decrease in rotation age, which increases the proportion of juvenile wood. The aim of this work was to define the proportions of juvenile wood (JW) and mature wood (MW) of these species that can optimize the mechanical and optical properties of chemimechanical pulps for newsprint production. A two-component mixture type experimental design was used with proportions (JW:MW) of 0:100%, 25:75%, 50:50%, 75:25%, and 100:0%. When the mechanical properties were optimized, the highest desirability function was obtained with a JW:MW ratio of 100:0%, and the optimal ratio for optical properties was 0:100%. The pattern of variation of mechanical properties can be attributed to the higher density of MW, whilst that of the optical properties can be attributed to the higher content of extractives in the JW.Facultad de Ciencias Agrarias y Forestale

Office paper recyclability: first recycling

Paper recyclability implies in the paper capacity to be recycled maintaining its properties to the maximum. Four commercial papers from Argentina and Brazil were studied, including three eucalyptus kraft (A, B, C) and one sugar cane bagasse soda-AQ (D), all with different bleaching processes. Their physical and chemical properties and a first laboratory recycling were evaluated. A refining of the pulp with a PFI mill, applying two energy levels at two different intensities - measured by number of revolutions and load - was accomplished to reach the same °SR (between 30 and 40, approximately). The refining energy and the yield were registered in each case. The properties of laboratory handsheets, and the aging to 24, 48, 72 and 144 hours were evaluated. The statistical analysis of the results indicates that the properties of the initial eucalyptus papers were similar, whereas they were generally inferior in the case of the bagasse paper. The bagasse and eucalyptus papers presented similar initial whiteness, but the first one had a higher reversion than the others. Once repulped, the eucalyptus papers A, B and C required, respectively, 4, 7 and 10 times greater energy than D, to obtain the same °SR. In all cases, the required energy to achieve the same °SR is slightly greater with the smaller refining intensity. The physical properties of the handsheets from the first recycle of paper D were, in general, lower. Among eucalyptus papers, B showed a slightly higher resistance and C, a slightly lower one. The mechanical properties of pulp sheets A, and D to a lesser extension, were more affected by the refining intensity than the rest, indicating a higher sensitivity of the fibers. The whiteness of the sheets of pulp B is lower than the rest. Opacity and light scattering coefficient of the sheets of pulp C were much higher than those of the other pulps.Fil: Benitez, Julieta Beatriz. Universidad Nacional de Misiones; ArgentinaFil: Koga, Mariza E. T.. Instituto de Pesquisas Tecnológicas de São Paulo (ipt); BrasilFil: Otero D'Almeida, Maria L.. Instituto de Pesquisas Tecnológicas de São Paulo (ipt); BrasilFil: Felissia, Fernando Esteban. Universidad Nacional de Misiones; ArgentinaFil: Park, Song W.. Escola Politecnica, Universidad de Sao Paulo (usp); BrasilFil: Area, Maria Cristina. Universidad Nacional de Misiones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentin

Pulping and pretreatment affect the characteristics of bagasse inks for 3D printing

Bagasse is an underutilized agro-industrial residue with great potential as raw material for the production of cellulose nanofibrils (CNF) for a range of applications. In this study, we have assessed the suitability of bagasse for production of CNF for three-dimensional (3D) printing. First, pulp fibers were obtained from the bagasse raw material using two fractionation methods, i.e. soda and hydrothermal treatment combined with soda. Second, the pulp fibers were pretreated by TEMPO-mediated oxidation using two levels of oxidation for comparison purposes. Finally, the CNF were characterized in detail and assessed as inks for 3D printing. The results show that CNF produced from fibers obtained by hydrothermal and soda pulping were less nanofibrillated than the corresponding material produced by soda pulping. However, the CNF sample obtained from soda pulp was cytotoxic, apparently due to a larger content of silica particles. All the CNF materials were 3D printable. We conclude that the noncytotoxic CNF produced from hydrothermally and soda treated pulp can potentially be used as inks for 3D printing of biomedical devices.Fil: Chinga Carrasco, Gary. RISE PFI; NoruegaFil: Ehman, Nanci Vanesa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Pettersson, Jennifer. RISE Bioscience and Materials; SueciaFil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Hakansson, Joakim. RISE Bioscience and Materials; SueciaFil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentin

Obtención de bietanol a partir de la celulosa presente en cascarilla de arroz y aserrín de algarrobo

El bioetanol producido a partir de residuos agro industriales es una alternativa muy interesante para diversificar la matriz energética Argentina. La cascarilla de arroz y el aserrín de algarrobo son residuos muy abundantes en la región del NEA y podrían ser aprovechados, utilizándolos como materia prima para la producción de bioetanol combustible. Por ello, el objetivo de este trabajo fue la obtención de bioetanol a partir de estos residuos lignocelulósicos a través de un proceso de pretratamiento ácido, seguido de hidrólisis enzimática y fermentación, evaluando la conveniencia de la primera etapa. El sólido pretratado de cascarilla de arroz presentó un 52,8% de glucanos, de los cuales se convirtieron el 55,7%, luego de la hidrólisis enzimática a las 72h y solo un 19,7% en cascarilla sin tratar. Para el caso del aserrín de algarrobo se encontró, luego del pretratamiento, un sólido con 51,2% de glucanos y a las 72h de hidrólisis enzimática se alcanzó un 41,5% de conversión en el material pretratado y solo un 9,6%, en el material original. Los rendimientos de la fermentación de los hidrolizados fueron aproximadamente del 100% en todos los casos.Bioethanol produced from agro-industrial waste is a very interesting alternative to diversify the energy matrix of Argentina. The rice husk and sawdust carob are abundant residues in the NEA region and could be exploited by using them as raw material for the production of bioethanol fuel. Therefore, the aim of this work was to obtain bioethanol from these lignocellulosic residues through a process of acid pretreatment followed by enzymatic hydrolysis and fermentation, assessing the appropriateness of the first stage. The solid pretreated rice hull presented glucan 52.8%, of which 55.7% are converted, after the enzymatic hydrolysis for 72 hours and only 19.7% in untreated scale. In the case of carob sawdust was found after pretreatment with a solid glucan 51.2% 72h and enzymatic hydrolysis reached 41.5% conversion to the pretreated material, and only 9.6%, in the original material. Fermentation yields of the hydrolysates were approximately 100% in all cases.Asociación Argentina de Energías Renovables y Medio Ambiente (ASADES

Optimization of the properties of poplar and willow chemimechanical pulps by a mixture design of juvenile and mature wood

Forest plantations of Salicaceae (poplars and willows) in Argentina are mainly used for the manufacture of pulp for newsprint. The rapid growth of these species results in a decrease in rotation age, which increases the proportion of juvenile wood. The aim of this work was to define the proportions of juvenile wood (JW) and mature wood (MW) of these species that can optimize the mechanical and optical properties of chemimechanical pulps for newsprint production. A two-component mixture type experimental design was used with proportions (JW:MW) of 0:100%, 25:75%, 50:50%, 75:25%, and 100:0%. When the mechanical properties were optimized, the highest desirability function was obtained with a JW:MW ratio of 100:0%, and the optimal ratio for optical properties was 0:100%. The pattern of variation of mechanical properties can be attributed to the higher density of MW, whilst that of the optical properties can be attributed to the higher content of extractives in the JW.Facultad de Ciencias Agrarias y Forestale

Evaluación de Cepas Fermentativas en la Hidrólisis y Fermentación Simultáneas (SSF) de Cascarilla de Arroz para la Producción de Bioetanol

La disminución en las reservas de petróleo a nivel mundial y los problemas medioambientales ocasionados por su utilización, propician la búsqueda de nuevas alternativas renovables y menos contaminantes. En este trabajo se estudió el comportamiento de enzimas celulasas y celobiosas, junto con cepas de Saccharomyces cerevisiae, Candida kefyr, Candida tropicalis y Candida guilliermondii en el proceso de hidrólisis y fermentación simultánea (SSF) conducido a 35°C para la producción de bioetanol, a partir de los carbohidratos presentes en cascarilla de arroz. Este proceso busca hidrolizar la celulosa y aprovechar de inmediato los azúcares fermentables, atravesando la dificultad de la diferencia entre la temperatura óptima para el desempeño de enzimas (50°C) y la de levaduras (25°C a 35°C). La cascarilla fue pretratada con una secuencia ácido-alcalina para la separación de los carbohidratos. Los mayores % de bioetanol se obtuvieron con Saccharomyces cerevisiae (68%) y Candida kefyr (75%)

REDUCTION OF THE RECALCITRANT COD OF HIGH YIELD PULP MILLS EFFLUENTS BY AOP. PART 1. COMBINATION OF OZONE AND ACTIVATED SLUDGE

The aim of this work was to study the effect of ozone, either alone or combined with an activated sludge system, on the reduction of the recalcitrant COD in the effluent of a chemimechanical pulping (NaOH -Na2SO3) integrated mill. Several alternative schemes involving ozonation were tested on liquors and effluents of the pulp mill, and on two kinds of effluents were taken at different points of an activated sludge pilot plant. The largest decrease in COD was 33%, whereas that in aromatic compounds (absorbance at 232.5 nm) was of 73%. The most obvious result of the ozone treatment was effluent decolorization. It was not possible to use ozonation as tertiary treatment, as ozone was necessary to treat the BOD generated, and therefore the effluent must necessarily pass through a biological treatment. With a scheme including an intermediate ozonation between two secondary treatments (post-activated sludge and pre-aeration lagoon), the maximum reductions achieved were of 70% in COD, of 93% in aromatics, and of 96% in color

Integrating the New Age of Bioeconomy and Industry 4.0 into Biorefinery Process Design

Manufacturing processes and their economy are dramatically evolving due to machinery and digital control improvements. Artificial intelligence, big data analytics, and the Internet of Things are key tools for this new industrial revolution era based on Industry 4.0. Bioeconomy and circular economy concepts have appeared in the forest, agriculture, food, pharmaceutical, pulp and paper, chemical, biotechnological, and energy areas, etc., to achieve sustainable economic growth development via biomass valorization in a biorefinery platform. Biorefinery process development at an industrial scale requires the previous design and assessment of processes and technologies. Therefore, economic, environmental, and social factors should be evaluated to prevent the failure in one of these issues that could affect the performance of the others. With a growing interest in sustainable economic development, there is a need to incorporate new technologies early enough in the process design. This study aims to better understand how Industry 4.0 era tools can bring new solutions to the biorefinery process design, in terms of the technical, economic, environmental, and social factors. Thus, these tools could improve and revolutionize the process selection optimization, provide alternatives for biomass valorization, integration strategies, and the metrics selection for process evaluation, adding the approach toward sustainable economic development