Gap nodes induced by coexistence with antiferromagnetism in iron-based superconductors

We investigate the pairing in iron pnictides in the coexistence phase, which displays both superconducting and antiferromagnetic orders. By solving the pairing problem on the Fermi surface reconstructed by long-range magnetic order, we find that the pairing interaction necessarily becomes angle-dependent, even if it was isotropic in the paramagnetic phase, which results in an angular variation of the superconducting gap along the Fermi surfaces. We find that the gap has no nodes for a small antiferromagnetic order parameter M, but may develop accidental nodes for intermediate values of M, when one pair of the reconstructed Fermi surface pockets disappear. For even larger M, when the other pair of reconstructed Fermi pockets is gapped by long-range magnetic order, superconductivity still exists, but the quasiparticle spectrum becomes nodeless again. We also show that the application of an external magnetic field facilitates the formation of nodes. We argue that this mechanism for a nodeless-nodal-nodeless transition explains recent thermal conductivity measurements of hole-doped Ba_{1-x}K_xFe_2As_2. [J-Ph. Read et.al. arXiv:1105.2232].Comment: 13 pages, 10 figures, submitted to PR

Collapse of the Cooper pair phase coherence length at a superconductor to insulator transition

We present investigations of the superconductor to insulator transition (SIT) of uniform a-Bi films using a technique sensitive to Cooper pair phase coherence. The films are perforated with a nanohoneycomb array of holes to form a multiply connected geometry and subjected to a perpendicular magnetic field. Film magnetoresistances on the superconducting side of the SIT oscillate with a period dictated by the superconducting flux quantum and the areal hole density. The oscillations disappear close to the SIT critical point to leave a monotonically rising magnetoresistance that persists in the insulating phase. These observations indicate that the Cooper pair phase coherence length, which is infinite in the superconducting phase, collapses to a value less than the interhole spacing at this SIT. This behavior is inconsistent with the gradual reduction of the phase coherence length expected for a bosonic, phase fluctuation driven SIT. This result starkly contrasts with previous observations of oscillations persisting in the insulating phase of other films implying that there must be at least two distinct classes of disorder tuned SITs

Probing the ejecta of evolved massive stars in transition: A VLT/SINFONI K-band survey

Massive evolved stars in transition phases, such as Luminous Blue Variables (LBVs), B[e] Supergiants (B[e]SGs), and Yellow Hypergiants (YHGs), are not well understood, and yet crucial steps in determining accurate stellar and galactic evolution models. The circumstellar environments of these stars reveal their mass-loss history, identifying clues to both their individual evolutionary status and the connection between objects of different phases. Here we present a survey of 25 such evolved massive stars (16 B[e]SGs, 6 LBVs, 2 YHGs, and 1 Peculiar Oe star), observed in the K-band with the Spectrograph for INtegral Field Observation in the Near-Infrared (SINFONI; R = 4500) on the ESO VLT UT4 8 m telescope. The sample can be split into two categories based on spectral morphology: one group includes all of the B[e]SGs, the Peculiar Oe star, and two of the LBVs, while the other includes the YHGs and the rest of the LBVs. The difference in LBV spectral appearance is due to some objects being in a quiescent phase and some objects being in an active or outburst phase. CO emission features are found in 13 of our targets, with first time detections for MWC 137, LHA 120-S 35, and LHA 115-S 65. From model fits to the CO band heads, the emitting regions appear to be detached from the stellar surface. Each star with ^12CO features also shows ^13CO emission, signaling an evolved nature. Based on the level of ^13C enrichment, we conclude that many of the B[e]SGs are likely in a pre-Red Supergiant phase of their evolution. There appears to be a lower luminosity limit of log L/L_solar = 5.0 below which CO is not detected. The lack of CO features in several high luminosity B[e]SGs and variability in others suggests that they may in fact be LBV candidates, strengthening the connection between these two very similar transition phases.Comment: 20 pages, 13 figures, 7 tables. Accepted for publication in A&

Büchwald-Hartwig reaction applied to synthesis of new luminescent liquid crystal triarylamines derived from isoxazoles

© 2015 Taylor & Francis Group, LLC. The present work describes the synthesis and characterization of novel series of triarylamines isoxazoles (TAA) addressed to the organic photovoltaic materials. Diarylisoxazoles were synthesized by sequential [3+2] 1,3-dipolar cycloaddition reaction between arylnitrile oxides and selected arylalkenes followed by MnO2-oxidation. Isoxazoles were coupled to diarylamines by Büchwald-Hartwig reaction to afford desired compounds 6a-k. Some TAA display liquid-crystalline behaviour and UV-Vis absorption and fluorescence emission were analysed for all samples of TAA 6a-k

Clinical, histological and prognostic features of a novel nail-bed lesion of cats: 41 cases

There is a distinct subset of lesions arising on the digits of cats, located at or close to the nail-bed epithelium, which are typically composed of proliferative fibroblast-like cells, multinucleate giant cells and areas of osseous metaplasia, but currently there is no published literature detailing the clinical or histological features of these lesions. This study identified 41 such cases from two large commercial diagnostic laboratories and assessed various histological and clinical features; 22 cases had additional follow-up data available

Complex critical exponents for percolation transitions in Josephson-junction arrays, antiferromagnets, and interacting bosons

We show that the critical behavior of quantum systems undergoing a percolation transition is dramatically affected by their topological Berry phase $2\pi\rho$. For irrational $\rho$, we demonstrate that the low-energy excitations of diluted Josephson-junctions arrays, quantum antiferromagnets, and interacting bosons are spinless fermions with fractal spectrum. As a result, critical properties not captured by the usual Ginzburg-Landau-Wilson description of phase transitions emerge, such as complex critical exponents, log-periodic oscillations and dynamically broken scale-invariance.Comment: revised version accepted for publication in Phys. Rev. Let

Impacts of in vivo and in vitro exposures to tamoxifen: comparative effects on human cells and marine organisms

Tamoxifen (TAM) is a first generation-SERM administered for hormone receptor-positive (HER+) breast cancer in both pre- and post-menopausal patients and may undergo metabolic activation in organisms that share similar receptors and thus face comparable mechanisms of response. The present study aimed to assess whether environmental trace concentrations of TAM are bioavailable to the filter feeder M. galloprovincialis (100 ng L-1) and to the deposit feeder N. diversicolor (0.5, 10, 25 and 100 ng L-1) after 14 days of exposure. Behavioural impairment (burrowing kinetic), neurotoxicity (AChE activity), endocrine disruption by alkali-labile phosphate (ALP) content, oxidative stress (SOD, CAT, GPXs activities), biotransformation (GST activity), oxidative damage (LPO) and genotoxicity (DNA damage) were assessed. Moreover, this study also pertained to compare TAM cytotoxicity effects to mussels and targeted human (i.e. immortalized retinal pigment epithelium - RPE; and human transformed endothelial cells - HeLa) cell lines, in a range of concentrations from 0.5 ng L-1 to 50 μg L-1. In polychaetes N. diversicolor, TAM exerted remarkable oxidative stress and damage at the lowest concentration (0.5 ng L-1), whereas significant genotoxicity was reported at the highest exposure level (100 ng L-1). In mussels M. galloprovincialis, 100 ng L-1 TAM caused endocrine disruption in males, neurotoxicity, and an induction in GST activity and LPO byproducts in gills, corroborating in genotoxicity over the exposure days. Although cytotoxicity assays conducted with mussel haemocytes following in vivo exposure was not effective, in vitro exposure showed to be a feasible alternative, with comparable sensitivity to human cell line (HeLa).info:eu-repo/semantics/publishedVersio

Synthesis and characterization of novel thienyl-phthalazine based heterocyclic systems functionalized with (bi)thiophene moieties

The phthalazine moiety has a highly -deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good deficient aromatic character that makes it a good candidate to be incorporated as electron acceptor group, or even as spacer with auxiliary electron withdrawing abilities, into push-pull systems. Additionally, offers the possibility of protonation, hydrogen bond formation, and chelation through the nitrogen atoms. Phthalazine derivatives have applications as therapeutic agents, chemiluminescent materials, ligands in transition metal catalysis, and as optical materials. Some time ago, our research group developed a methodology for the preparation of phthalazine derivatives in three steps, affording halo-thienyl-phthalazine derivatives that play an important role in diazine chemistry since they offer great potential for further functionalization by nucleophilic displacement of the halogen, making numerous otherwise inaccessible diazines become available. In continuation of the work developed before by our research group, we report in this communication the synthesis and the evaluation of the optical properties of two novel thienyl-phthalazine derivatives, having in mind further functionalization to prepare push-pull heterocyclic systems for several optical and photovoltaic applications. These studies showed that the optical properties could be readily tuned by varying the π-conjugation path length through the introduction of a second thiophene unit.Thank are due to Fundação para a Ciência e Tecnologia (Portugal) and FEDER-COMPETE for financial support through Centro de Química (UID/QUI/00686/2013 and UID/ QUI/0686/2016), and a PhD grant to S. S. M. Fernandes (SFRH/BD/87786/2012). The NMR spectrometer Bruker Avance III 400 is part of the National NMR Network and was purchased within the framework of the National Program for Scientific Re-equipment, contract REDE/1517/RMN/2005 with funds from POCI 2010 (FEDER) and FCT.info:eu-repo/semantics/publishedVersio