Reactivation of Limestone-Derived Sorbents using Hydration: Preliminary Results From a Fluidised Bed

A simple method of CO~2~ capture is by using the calcium looping cycle. The calcium looping cycle uses CaCO~3~ as a CO~2~ carrier, via the reversible reaction CaO(s) + CO~2~(g) = CaCO~3~(s), to extract CO2 from the exhaust stream and provide a pure stream of CO~2~ suitable for sequestration. 
A problem associated with the technology is that the capacity of the sorbent to absorb CO~2~ reduces significantly with the number of cycles of carbonation and calcination. The energy penalty of the cycle is considerably increased by cycling unreacted sorbent: hydration of unreactive sorbent has emerged as a promising strategy of reducing this penalty by regenerating the reactivity of exhausted sorbent.
A small atmospheric pressure fluidised bed reactor has been built and tested, that allows repeated cycling between two temperatures up to 1000 °C. 
Work presented here focuses on the effects of variation of the calcination temperature before hydration. Hydration has been found to more than double the reactivity of a spent sorbent cycled under the mildest conditions studied (calcination temperature of 840 °C). However, as calcination temperature is increased the observed reactivation decreases until little reactivation is observed for the sorbent cycled at 950 °C. The primary reason for this appears to be a substantial increase in friability of particles, with reactivity normalised for mass losses appearing similar independent of cycling temperature

Integrated airframe propulsion control

Perturbation equations which describe flight dynamics and engine operation about a given operating point are combined to form an integrated aircraft/propulsion system model. Included in the model are the dependence of aerodynamic coefficients upon atmospheric variables along with the dependence of engine variables upon flight condition and inlet performance. An off-design engine performance model is used to identify interaction parameters in the model. Inclusion of subsystem interaction effects introduces coupling between flight and propulsion variables. To analyze interaction effects on control, consideration is first given to control requirements for separate flight and engine models. For the separate airframe model, feedback control provides substantial improvement in short period damping. For the integrated system, feedback control compensates for the coupling present in the model and provides good overall system stability. However, this feedback control law involves many non-zero gains. Analysis of suboptimal control strategies indicates that performance of the closed loop integrated system can be maintained with a feedback matrix in which the number of non-zero gains is small relative to the number of components in the feedback matrix

Excisional treatment of cavernous hemangioma of the liver

Fifteen patients had hepatic hemangiomas removed with liver resections that ranged in extent from local excision to right trisegmentectomy. There was no mortality and little morbidity. The propriety and feasibility of extirpative treatment of such liver tumors has been emphasized by this experience

A shrinking core model for steam hydration of CaO-based sorbents cycled for CO2 capture

Calcium looping is a developing CO2 capture technology. It is based on the reversible carbonation of CaO sorbent, which becomes less reactive upon cycling. One method of increasing the reactivity of unreactive sorbent is by hydration in the calcined (CaO) form. Here, sorbent has been subjected to repeated cycles of carbonation and calcination within a small fluidised bed reactor. Cycle numbers of 0 (i.e., one calcination), 2, 6 and 13 have been studied to generate sorbents that have been deactivated to different extents. Subsequently, the sorbent generated was subjected to steam hydration tests within a thermogravimetric analyser, using hydration temperatures of 473, 573 and 673 K. Sorbents that had been cycled less prior to hydration hydrated rapidly. However, the more cycled sorbents exhibited behaviour where the hydration conversion tended towards an asymptotic value, which is likely to be associated with pore blockage. This asymptotic value tended to be lower at higher hydration temperatures; however, the maximum rate of hydration was found to increase with increasing hydration temperature. A shrinking core model has been developed and applied to the data. It fits data from experiments that did not exhibit extensive pore blockage well, but fits data from experiments that exhibited pore blockage less well

Experimental Proof of a Magnetic Coulomb Phase

Spin ice materials are magnetic substances in which the spin directions map onto hydrogen positions in water ice. Recently this analogy has been elevated to an electromagnetic equivalence, indicating that the spin ice state is a Coulomb phase, with magnetic monopole excitations analogous to ice's mobile ionic defects. No Coulomb phase has yet been proved in a real magnetic material, as the key experimental signature is difficult to resolve in most systems. Here we measure the scattering of polarised neutrons from the prototypical spin ice Ho2Ti2O7. This enables us to separate different contributions to the magnetic correlations to clearly demonstrate the existence of an almost perfect Coulomb phase in this material. The temperature dependence of the scattering is consistent with the existence of deconfined magnetic monopoles connected by Dirac strings of divergent length.Comment: 18 pages, 4 fig

First energetic neutral atom images from Polar

Energetic neutral atoms are created when energetic magnetospheric ions undergo charge exchange with cold neutral atoms in the Earth\u27s tenuous extended atmosphere (the geocorona). Since they are unaffected by the Earth\u27s magnetic field, these energetic neutrals travel away in straight line trajectories from the points of charge exchange. The remote detection of these particles provides a powerful means through which the global distribution and properties of the geocorona and ring current can be inferred. Due to its 2 × 9 RE polar orbit, the Polar spacecraft provides an excellent platform from which to observe ENAs because it spends much of its time in the polar caps which are usually free from the contaminating energetic charged particles that make observations of ENAs more difficult. In this brief report, we present the first ENA imaging results from Polar. Storm-time ENA images are presented for a northern polar cap apogee pass on August 29, 1996 and for a southern polar cap perigee pass on October 23, 1996. As well, we show with a third event (July 31, 1996) that ENA emissions can also be detected in association with individual substorm