11 research outputs found

    Correlating electronic and magnetic coupling in large magnetic molecules via scanning tunneling microscopy

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    Contains fulltext : 175413.pdf (publisher's version ) (Open Access)7 p

    Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes

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    Feldscher B, Theil H, Stammler A, Bögge H, Glaser T. Bioinspired Enhancement of Superexchange: From 1,3,5-Trihydroxybenzene-Bridged to 1,3,5-Trimercaptobenzene-Bridged Trinuclear Copper(II) Complexes. Inorganic Chemistry. 2012;51(16):8652-8654.An unprecedented trinucleating ligand with a central 1,3,5-trimercaptobenzene unit and its trinuclear Cu-3(II) complex are presented. The high covalency of the difficult-to-realize Cu-II-SR bond provides an order of magnitude increase in the superexchange interaction in comparison to its oxygen analogue
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