445 research outputs found

    Pathwise uniqueness and continuous dependence for SDEs with nonregular drift

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    A new proof of a pathwise uniqueness result of Krylov and R\"{o}ckner is given. It concerns SDEs with drift having only certain integrability properties. In spite of the poor regularity of the drift, pathwise continuous dependence on initial conditions may be obtained, by means of this new proof. The proof is formulated in such a way to show that the only major tool is a good regularity theory for the heat equation forced by a function with the same regularity of the drift

    Tribological Properties of Nanometric Atomic Layer Depositions Applied on AISI 420 Stainless Steel

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    Atomic Layer Deposition ( ALD ) is a modern technique that Allows to deposit nanometric, conformal coatings on almost any kind of substrates, from plastics to ceramic, metals or even composites. ALD coatings are not dependent on the morphology of the substrate and are only regulated by the composition of the precursors, the chamber temperature and the number of cycles. In this work, mono- and bi -layer nanometric, protective low-temperature ALD Coatings, based on Al2O3 and TiO2 were applied on AISI 420 Stainless Steel in orderto enhance its relatively low corrosion resistance in chloride containing environments. Tribological testing were also performed on the ALD coated AISI 420 in order to evaluate the wear and scratch resistance of these nanometric layers and thus evaluate their durability. Scratch tests were performed using a standard Rockwell C indenter, under a variable load condition, in order to evaluate the critical loading condition for each coating. Wear testing were performed using a stainless steel counterpart, in ball-on-discconfiguration, in order to measure the friction coefficient and wear to confront the resistance. All scratch tests scars and wear tracks were then observed by means of Scanning Electron Microscopy (SEM) in order to understand the wear mechanisms that occurred on the sample surfaces. Corrosion testing, performed under immersion in 0.2 M NaCl solutions, clearly showed that the ALD coatings have a strong effect in protecting the Stainless Steel Substrate against corrosion, reducing the corrosion current density by two orders of magnitude.Tribological The preliminary results showed that ALD depositions obtained at low Temperatures have a brittle behavior caused by the amorphous nature of their structure, and thus undergo delamination phenomena during Scratch Testing at relatively low applied loads. During ball-on-disc testing, the coatings were removed from the substrate, in particular for monolayer ALD configurations, Which seem to have a lower toughness when compared to bi-layer configurations

    Quantum entanglement distribution with 810 nm photons through telecom fibers

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    We demonstrate the distribution of polarization entangled photons of wavelength 810 nm through standard telecom fibers. This technique allows quantum communication protocols to be performed over established fiber infrastructure, and makes use of the smaller and better performing setups available around 800 nm, as compared to those which use telecom wavelengths around 1550 nm. We examine the excitation and subsequent quenching of higher-order spatial modes in telecom fibers up to 6 km in length, and perform a distribution of high quality entanglement (visibility 95.6%). Finally, we demonstrate quantum key distribution using entangled 810 nm photons over a 4.4 km long installed telecom fiber link.Comment: 5 pages, 5 figures, 1 tabl

    Noise Prevents Singularities in Linear Transport Equations

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    A stochastic linear transport equation with multiplicative noise is considered and the question of no-blow-up is investigated. The drift is assumed only integrable to a certain power. Opposite to the deterministic case where smooth initial conditions may develop discontinuities, we prove that a certain Sobolev degree of regularity is maintained, which implies H\"older continuity of solutions. The proof is based on a careful analysis of the associated stochastic flow of characteristics

    Tribological Behavior of Thermal Spray Coatings, Deposited by HVOF and APS Techniques, and Composite Electrodeposits Ni/SiC at Both Room Temperature and 300 °C

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    The Both the thermal spray and the electroplating coatings are widely used because of their high wear resistance combined with good corrosion resistance. In particular the addition of both micro particles or nano‐particles to the electro deposited coatings could lead to an increase of the mechanical properties, caused by the change of the coating microstructure. The thermal spray coatings were deposited following industrial standards procedures, while the Ni/SiC composite coatings were produced at laboratory scale using both micro‐and nano‐sized ceramic particles. All the produced coatings were characterized regarding their microstructure,mechanical properties and the wear resistance. The tribological properties were analyzed using a tribometer under ball on disk configuration at both room temperature and 300oC. The results showed that the cermet thermal spray coatings have a high wear resistance, while the Ni nano‐composite showed good anti wear properties compared to the harder ceramic/cermet coatings deposited by thermal spray technique

    A novel thermo-geometrical model for accurate keyhole porosity prediction in Laser Powder-Bed Fusion

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    When performing Laser Powder-Bed Fusion, undesired physical phenomena, such as balling, preballing and keyhole, must be avoided in order to achieve high-quality products. To date, keyhole-free process parameters can be identified either using demanding empirical methods or complex numerical simulations, while only a few analytical models can be found in literature for this purpose. In this work, state-of-the-art analytical models for predicting keyhole porosity were summarized and proved to be rather inaccurate because they are only based on thermodynamic principles, whereas they neglect the geometry and both the kinetics and kinematics of the keyhole cavity, which do also influence cavity collapse and porosity formation. Here an innovative physics-based semi-analytical model for predicting the formation of keyhole-related porosities was conceived, in which both thermodynamic and geometrical factors are taken into account. The proposed model was validated by performing single tracks experiments on Ti6Al4V according to a full factorial DoE on laser power and scanning speed. Produced samples were cross-sectioned and analyzed to evaluate keyhole porosity formation. The comparison between experimental data and model predictions confirmed the higher accuracy of the new model with respect to state of the art models. Besides improving the understanding of the keyhole phenomenon, the proposed model may provide a novel, effective and simple tool for fast process parameter optimization in industry

    Trace elements in home-processed food obtained from unconventional animals

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    Wild animals have been used as food since ancient times and, currently, the consumption of unconventional animals is increasing worldwide. The process of cooking meat using traditional recipes includes a variety of ingredients, which can influence the total metal intake from the diet. In this study, the concentrations of eight essential (Fe, Zn, Cu, Mn, Se, Ni, Mo, and Co) and six non-essential (Pb, Cd, Hg, Al, As, and Cr) trace elements were determined in home-processed food obtained from snails and from three common species of game animals (woodcock, pheasant, and hare), seasoned with anchovies, mushrooms, and different vegetables using inductively coupled plasma mass spectrometry (ICP-MS). In general, Fe was the most abundant trace element, ranging from 18 \ub1 8 \u3bcg/g in pheasant to 99 \ub1 76 \u3bcg/g in snail, and Co was the least abundant, ranging from 0.007 \ub1 0.003 \u3bcg/g in hare to 0.093 \ub1 0.048 \u3bcg/g in snail. Regarding the non-essential trace elements, Pb concentrations showed wide variations, reaching a concentration of 17.30 \u3bcg/g in hare, while Cd concentrations were higher in snail, ranging from 0.18 to 0.46 \u3bcg/g. These alternative food sources can offer an important contribution to the human nutritional requirements of essential trace elements, in particular of Fe. The high concentrations of Pb and Cd present in some samples should be considered as potentially dangerous for the consumers

    On growth and morphology of tio2 nanotubes on ti6al4v by anodic oxidation in ethylene glycol electrolyte: Influence of microstructure and anodization parameters

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    Different studies demonstrated the possibility to produce TiO2 nanotubes (TNTs) on Ti6Al4V alloy by electrochemical anodization. However, the anodizing behavior of \u3b1 and \u3b2-phases in organic electrolytes is not yet clarified. This study reports on the anodizing behavior of the two phases in an ethylene glycol electrolyte using different applied potentials and anodizing times. Atomic force and scanning electron microscopies were used to highlight the anodic oxides differences in morphology. It was demonstrated that the initial compact oxide grew faster over the \u3b2-phase as the higher Al content of the \u3b1-phase caused its re-passivation, and the higher solubility of the V-rich oxide led to earlier pores formation over the \u3b2-phase. The trend was inverted once the pores formed over the compact oxide of the \u3b1-phase. The growth rate of the \u3b1-phase TNTs was higher than that of the \u3b2-phase ones, leading to the formation of long and well defined nanotubes with thin walls and a honeycomb tubular structure, while the ones grown over the \u3b2-phase were individual, shorter, and with thicker walls

    The Effect of the P/Si Ratio on the Preparation and Properties of Phosphoric Acid-Metakaolin Geopolymers

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    The present research deals with the production and characterization of geopolymers prepared by mixing metakaolin, different amounts of phosphoric acid solution and water. Hardening was performed by aging the geopolymeric pastes in a climatic chamber. The workability of the pastes has been improved while the H2O/total solid content has been kept constant and the P/Si ratio increased. However, such a benefit implies considerable heat output, which must be controlled in order to limit the formation of extended fractures. The compressive strength of the hardened materials increases with increasing P/Si ratio at a constant H2O/total solid content, whereas their strength decreases with increasing H2O/ total solid content at a constant P/Si ratio. The open macroporosity, which is directly dependent on the total amount of water added to the geopolymeric pastes, may explain the above results better than the nano/microporosity and/or chemical bonds that contribute to building up the materials\u2019 textural features
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