Spin-dependent charge recombination along para-phenylene molecular wires

We have used an efficient new quantum mechanical method for radical pair recombination reactions to study the spin-dependent charge recombination along PTZ$^{\bullet+}$--Ph$_n$--PDI$^{\bullet-}$ molecular wires. By comparing our results to the experimental data of E. Weiss {\em et al.} [J. Am. Chem. Soc. {\bf 126}, 5577 (2004)], we are able to extract the spin-dependent (singlet and triplet) charge recombination rate constants for wires with $n=2-5$. These spin-dependent rate constants have not been extracted previously from the experimental data because they require fitting its magnetic field-dependence to the results of quantum spin dynamics simulations. We find that the triplet recombination rate constant decreases exponentially with the length of the wire, consistent with the superexchange mechanism of charge recombination. However, the singlet recombination rate constant is nearly independent of the length of the wire, suggesting that the singlet pathway is dominated by an incoherent hopping mechanism. A simple qualitative explanation for the different behaviours of the two spin-selective charge recombination pathways is provided in terms of Marcus theory. We also find evidence for a magnetic field-independent background contribution to the triplet yield of the charge recombination reaction, and suggest several possible explanations for it. Since none of these explanations is especially compelling given the available experimental evidence, and since the result appears to apply more generally to other molecular wires, we hope that this aspect of our study will stimulate further experimental work.Comment: 12 pages, 10 figure

Self heating and nonlinear current-voltage characteristics in bilayer graphene

We demonstrate by experiments and numerical simulations that the low-temperature current-voltage characteristics in diffusive bilayer graphene (BLG) exhibit a strong superlinearity at finite bias voltages. The superlinearity is weakly dependent on doping and on the length of the graphene sample. This effect can be understood as a result of Joule heating. It is stronger in BLG than in monolayer graphene (MLG), since the conductivity of BLG is more sensitive to temperature due to the higher density of electronic states at the Dirac point.Comment: 9 pages, 7 figures, REVTeX 4.

An accurate formula for the period of a simple pendulum oscillating beyond the small-angle regime

A simple approximation formula is derived here for the dependence of the period of a simple pendulum on amplitude that only requires a pocket calculator and furnishes an error of less than 0.25% with respect to the exact period. It is shown that this formula describes the increase of the pendulum period with amplitude better than other simple formulas found in literature. A good agreement with experimental data for a low air-resistance pendulum is also verified and it suggests, together with the current availability/precision of timers and detectors, that the proposed formula is useful for extending the pendulum experiment beyond the usual small-angle oscillations.Comment: 15 pages and 4 figures. to appear in American Journal of Physic

Effect of spin orbit scattering on the magnetic and superconducting properties of nearly ferromagnetic metals: application to granular Pt

We calculate the effect of scattering on the static, exchange enhanced, spin susceptibility and show that in particular spin orbit scattering leads to a reduction of the giant moments and spin glass freezing temperature due to dilute magnetic impurities. The harmful spin fluctuation contribution to the intra-grain pairing interaction is strongly reduced opening the way for BCS superconductivity. We are thus able to explain the superconducting and magnetic properties recently observed in granular Pt as due to scattering effects in single small grains.Comment: 9 pages 3 figures, accepted for publication in Phys. Rev. Letter

Biodiversity and Ecosystem Health of the Aldabra Group, Southern Seychelles: Scientific Report to the Government of Seychelles.

National Geographic's Pristine Seas project, in collaboration with the government of the Seychelles, the Island Conservation Society (ICS), the Seychelles Islands Foundation (SIF), and the Waitt Foundation, conducted an expedition to explore the poorly known marine environment around these islands. The goals were to assess the biodiversity of the nearshore marine environment and to survey the largely unknown deep sea realm. The data collected contribute to the marine spatial planning of the Seychelles, in particular the creation of large marine reserves

Shot noise and conductivity at high bias in bilayer graphene: Signatures of electron-optical phonon coupling

We have studied electronic conductivity and shot noise of bilayer graphene (BLG) sheets at high bias voltages and low bath temperature $T_0=4.2$ K. As a function of bias, we find initially an increase of the differential conductivity, which we attribute to self-heating. At higher bias, the conductivity saturates and even decreases due to backscattering from optical phonons. The electron-phonon interactions are also responsible for the decay of the Fano factor at bias voltages $V>0.1$ V. The high bias electronic temperature has been calculated from shot noise measurements, and it goes up to $\sim1200$ K at $V=0.75$ V. Using the theoretical temperature dependence of BLG conductivity, we extract an effective electron-optical phonon scattering time $\tau_{e-op}$. In a 230 nm long BLG sample of mobility $\mu=3600$ cm$^2$V$^{-1}$s$^{-1}$, we find that $\tau_{e-op}$ decreases with increasing voltage and is close to the charged impurity scattering time $\tau_{imp}=60$ fs at $V=0.6$ V.Comment: 7 pages, 7 figures. Extended version of the high bias part of version 1. The low bias part is discussed in arXiv:1102.065

Slowly and non-digestible tissues in Elytrigia scabrifolia y E. Scabriglumis

The estimation of the percentages of slowly and non-digestible tissues allows the prediction 01the nutritive value of forages. In this study, the percentages of tissues in sheaths and blades of two species natives of the Salado Basin and abundant in the Pampas range pastures (Elytrigia scabrifolia y E. scabriglumis) were determined as a primary evaluation of their forage qualily. The estimations were done in the vegetative and reproductive stages. A split-plots design in space and time, with species as main plot, plant part (sheath or blade) as secondary plots, and three replications was used. Percentages of all leaf tissues were estimated by microscopic analysis of cross section and were grouped in rapidly and slowly plus non-digestible tissues. The variation of all leaf tissues between species, plant parts and growth stage, and the percentages variation of slowly and non-digestible tissues were analysed by principal components and by ANOVA, respectively. In all cases, the percentages of sclerenchyma were lower than 10% and those of slowly plus non-digestible tissues were lower than 45%. The percentages of slowly and non-digestible tissues did not differ (P<0.05) either between species (P<0.05) or plant parts, but increased 34% with the advancement of growth from the vegetativa to the reproductive stage. Although the percentage of slowly and nondigestible tissues suggest that both species have an acceptable nutritive value, this rating could be altered by the degree of forage lignification.Resúmenes de Trabajos presentados en otras publicaciones (por docentes de la UNLPam.) Publicado en Archivos latinoamericanos de producción animal, 5(Supl. 1): 118-121, 1997

Slowly and non-digestible tissues in Elytrigia scabrifolia y E. Scabriglumis

The estimation of the percentages of slowly and non-digestible tissues allows the prediction 01the nutritive value of forages. In this study, the percentages of tissues in sheaths and blades of two species natives of the Salado Basin and abundant in the Pampas range pastures (Elytrigia scabrifolia y E. scabriglumis) were determined as a primary evaluation of their forage qualily. The estimations were done in the vegetative and reproductive stages. A split-plots design in space and time, with species as main plot, plant part (sheath or blade) as secondary plots, and three replications was used. Percentages of all leaf tissues were estimated by microscopic analysis of cross section and were grouped in rapidly and slowly plus non-digestible tissues. The variation of all leaf tissues between species, plant parts and growth stage, and the percentages variation of slowly and non-digestible tissues were analysed by principal components and by ANOVA, respectively. In all cases, the percentages of sclerenchyma were lower than 10% and those of slowly plus non-digestible tissues were lower than 45%. The percentages of slowly and non-digestible tissues did not differ (P<0.05) either between species (P<0.05) or plant parts, but increased 34% with the advancement of growth from the vegetativa to the reproductive stage. Although the percentage of slowly and nondigestible tissues suggest that both species have an acceptable nutritive value, this rating could be altered by the degree of forage lignification.Resúmenes de Trabajos presentados en otras publicaciones (por docentes de la UNLPam.) Publicado en Archivos latinoamericanos de producción animal, 5(Supl. 1): 118-121, 1997