A thermal behavior of low-substituted hydroxyethyl cellulose and cellulose solutions in NaOH-water

The articles belonging to the special issue are open access, all published articles are freely available online.International audienceHydroxyethyl cellulose (HEC) with low molar substitution has better solubility in 8%NaOH-water solution than pure cellulose. The thermal behavior of ternary HEC/NaOH/water mixtures was investigated by DSC, and the results are compared with those of cellulose/NaOH/water solutions, aiming at providing better understanding about cellulose dissolution mechanism in NaOH-water. At low polymer concentrations and below 0°C, HEC and cellulose solutions exhibit a similar thermal behavior with ice, eutectic and/or melting and recrystallization peaks, showing that the overall interactions between NaOH, water and cellulose or HEC are identical. However, when the concentration increases above 2%, the eutectic peak of HEC solutions disappeared, leaving only the ice peak, which is different from previous results for cellulose where the disappearance of the eutectic peak was related to the maximum solubility of cellulose (around 8 wt%). This implies that the dissolution behavior of HEC in NaOH solution is changed due to possible changes of chain flexibility and/or increased attractions to water caused by the hydrophilic hydroxyethyl groups. The melting and recrystallization peaks visible only at low concentrations of HEC or cellulose in solution also support the conclusion that dissolution of cellulose and HEC at low concentrations bears features which are not yet understood

Joint Exposure to Ambient Air Pollutants Might Elevate the Risk of Small for Gestational Age (SGA) Infants in Wuhan: Evidence From a Cross-Sectional Study

Objective: To investigate the effect of exposure to multiple ambient air pollutants during pregnancy on the risk of children being born small for gestational age (SGA).Methods: An Air Pollution Score (APS) was constructed to assess the effects of being exposed to six air pollutants simultaneously, PM2.5, PM10, SO2, NO2, CO, and O3 (referred to as joint exposure). A logistic regression model was applied to estimate the associations of APS and SGA.Results: The adjusted odds ratios (ORs) of SGA per 10 ug/m3 increased in APS during the first and second trimesters and the entire pregnancy were 1.003 [95% confidence intervals (CIs): 1.000, 1.007], 1.018 (1.012, 1.025), and 1.020 (1.009, 1.031), respectively. The ORs of SGA for each 10 μg/m3 elevated in APS during the whole pregnancy were 1.025 (1.005, 1.046) for mothers aged over 35 years old vs. 1.018 (1.005, 1.031) for mothers aged under 35 years old. Women who were pregnant for the first time were more vulnerable to joint ambient air pollution.Conclusion: In summary, the results of the present study suggested that joint exposure to ambient air pollutants was associated with the increment in the risks of SGA

Electromagnetic design and performance analysis of coreless superconducting machine

With the development of offshore wind power generation, there is an urgent demand for high-power wind turbines. Superconducting machines with high power density and efficiency are one of the solutions for wind turbines of 10 MW and above. This paper summarizes the existing superconducting synchronous generators in several structural forms and features, and considers that the coreless machine can avoid the impact of core oversaturation on the power density increase of the machine, which is the development direction of the superconducting machine. In this paper, the structural topology of a coreless superconducting machine is established and the similarities and differences between its structure and that of a conventional one are analyzed. Since the conventional magnetic circuit method is no longer applicable, a designing model based on the analytical method is established for the designing of coreless machines, which considers the effects of slotless armature, the superconducting excitation winding thickness and the nonlinearity of the ferromagnetic material. Based on this method, the magnetic field distribution is solved and verified with the finite element method. Further, the effect of the superconducting excitation winding opening angle on the magnetic field in the air gap of the machine is investigated, and the machine structure is optimized based on this. The steady-state and transient performance analysis of the machine is carried out to illustrate the operating characteristics of the coreless superconducting machine. The design method and analysis results of this paper can provide a reference for building higher power density coreless superconducting wind turbines

Structure and properties of novel cellulose-based fibers spun from aqueous NaOH solvent under various drawing conditions

International audienceHydroxyethyl cellulose (HEC) fibers with low degree of substitution were prepared by wet spinning of solutions in 8 wt% aqueous NaOH solvent. The spinning solution had a classical shear-thinning behavior and a good stability towards gelation according to its rheological behavior. The influence of drawing conditions on the structural characteristics and tensile properties of the resultant HEC fibers was investigated using synchrotron X-ray measurements, scanning electron microscope and tensile tests. HEC fibers exhibited circular cross-sections with soft and deformable surface layer as well as relatively uniform and dense inner structure. Regardless of the different jet stretch or post-drawing conditions, most of the structural features and the tensile properties of HEC fibers were improved as the drawing ratio increased. Post-drawing was confirmed to be the key factor in controlling the fiber structure and tensile properties due to plastic deformation. Excellent tensile properties were found for HEC fibers prepared at relatively low jet ratio associated with high post-drawing ratio

Hyaluronic Acid and Polyethylene Glycol Hybrid Hydrogel Encapsulating Nanogel with Hemostasis and Sustainable Antibacterial Property for Wound Healing

Immediate hemorrhage control and anti-infection play important roles in the wound management. Besides, a moist environment is also beneficial for wound healing. Hydrogels are promising materials in urgent hemostasis and drug release. However, hydrogels have the disadvantage of rapid release profiles, leading to the exposure to high drug concentrations. In this study, we constructed hybrid hydrogels with rapid hemostasis and sustainable antibacterial property combining aminoethyl methacrylate hyaluronic acid (HA-AEMA) and methacrylated methoxy polyethylene glycol (mPEG-MA) hybrid hydrogels and chlorhexidine diacetate (CHX)-loaded nanogels. The CHX-loaded nanogels (CLNs) were prepared by the enzyme degradation of CHX-loaded lysine-based hydrogels. The HA-AEMA and mPEG-MA hybrid hydrogel loaded with CLNs (labeled as Gel@CLN) displayed a three-dimensional microporous structure and exhibited excellent swelling, mechanical property, and low cytotoxicity. The Gel@CLN hydrogel showed a prolonged release period of CHX over 240 h and the antibacterial property over 10 days. The hemostasis and wound-healing properties were evaluated in vivo using a mouse model. The results showed that hydrogel had the rapid hemostasis capacity and accelerated wound healing. In summary, CLN-loaded hydrogels may be excellent candidates as hemostasis and anti-infection materials for the wound dressing application

A Composite Fabric with Dual Functions for High-Performance Water Purification

The dilemma of diminishing freshwater resources caused by water pollution has always impacted human life. Solar-driven interfacial evaporation technology has the potential for freshwater production via solar-driven distillation. However, in solar-driven interfacial evaporation technology, it is difficult to overcome the problem of wastewater containing various contaminants. In this work, we propose a bifunctional fabric created by depositing titanium dioxide@carbon black nanoparticles onto cotton fabric (TiO2@CB/CF). The TiO2@CB/CF has a coupling effect that includes the photothermal effect of CB and photocatalysis of TiO2, and it can not only generate clean water but can also purify contaminated water. The resulting bifunctional fabric can achieve an outstanding water evaporation rate of 1.42 kg m−2 h−1 and a conversion efficiency of 90.4% in methylene blue (MB) solution under one-sun irradiation. Simultaneously, the TiO2@CB/CF demonstrates a high photocatalytic degradation of 57% for MB solution after 2 h with light irradiation. It still shows a good photocatalysis effect, even when reused in an MB solution for eight cycles. Furthermore, the TiO2@CB/CF delivers excellent performance for actual industrial textile dyeing wastewater. This bifunctional fabric has a good application prospect and will provide a novel way to resolve the issue of freshwater scarcity

Air pollution weaken your muscle? Evidence from a cross-sectional study on sarcopenia in central China

Background: As the world experiences a demographic shift towards aging populations, there will be a significant surge in the number of sarcopenia patients, along with an unprecedented expansion in the associated economic burden. The multitudinous risk factors for sarcopenia have been reported, but evidence for air pollution remains rare. Methods: This cross-sectional study employed multi-stage random sampling to select 1592 participants over 40 years of age from Hubei Province. Daily mean concentrations of air pollutants were collected ChinaHighAirPollutants dataset. Unconditional logistic regression models were utilized to investigate the associations between air pollution and sarcopenia. Results: For each 1 μg/m3 increase in PM2.5, PM10, SO2 and O3, there were corresponding elevations of 11.1% [95% confidence interval (CI): 4.9, 17.7], 4.3% (95% CI: 1.4, 7.2), 22.6% (95% CI: 7.2, 40.1) and 9.3% (95% CI: 0.7, 18.7) in the risk of sarcopenia, respectively. The associations of PM2.5/PM10/O3-sarcopenia were more pronounced in females, with corresponding odds ratios (ORs) and 95% CIs of 1.179 (1.062, 1.310), 1.079 (1.027, 1.135) and 1.180 (1.026, 1.358), separately. Additionally, individuals residing in rural areas were more susceptible to the effects of PM2.5 and PM10. Current/ever smokers or drinkers were also at higher risk of developing sarcopenia caused by PM2.5, PM10 and O3 exposure. Mixture analyses show a surge of 48.4% (95% CI: 3.6%, 112.5%) in the likelihood of suffering from sarcopenia, and the joint impacts of the air pollution were mainly driven by PM2.5. Conclusions: Our results produced evidence for a relationship between air pollution exposure and the increased prevalence of sarcopenia in China. Public health and relevant departments should make efforts to prevent sarcopenia, particularly in China experiencing rapid demographic aging