The O2 A-band in fluxes and polarization of starlight reflected by Earth-like exoplanets

Earth-like, potentially habitable exoplanets are prime targets in the search for extraterrestrial life. Information about their atmosphere and surface can be derived by analyzing light of the parent star reflected by the planet. We investigate the influence of the surface albedo $A_{\rm s}$, the optical thickness $b_{\rm cloud}$ and altitude of water clouds, and the mixing ratio $\eta$ of biosignature O$_2$ on the strength of the O$_2$ A-band (around 760 nm) in flux and polarization spectra of starlight reflected by Earth-like exoplanets. Our computations for horizontally homogeneous planets show that small mixing ratios ($\eta$ < 0.4) will yield moderately deep bands in flux and moderate to small band strengths in polarization, and that clouds will usually decrease the band depth in flux and the band strength in polarization. However, cloud influence will be strongly dependent on their properties such as optical thickness, top altitude, particle phase, coverage fraction, horizontal distribution. Depending on the surface albedo, and cloud properties, different O$_2$ mixing ratios $\eta$ can give similar absorption band depths in flux and band strengths in polarization, in particular if the clouds have moderate to high optical thicknesses. Measuring both the flux and the polarization is essential to reduce the degeneracies, although it will not solve them, in particular not for horizontally inhomogeneous planets. Observations at a wide range of phase angles and with a high temporal resolution could help to derive cloud properties and, once those are known, the mixing ratio of O$_2$ or any other absorbing gas.Comment: 21 pages, 20 figures, accepted for publication in Ap

Utilisation de la grille pour la simulation de température de brillance dans une atmosphère nuageuse composée de cirrus

Utilisation de la grille pour la simulation de température de brillance dans une atmosphère nuageuse composée de cirru

Scale dependence of cirrus heterogeneity effects. Part II: MODIS NIR and SWIR channels

In a context of global climate change, the understanding of the radiative role of clouds is crucial. On average, ice clouds such as cirrus have a significant positive radiative effect, but under some conditions the effect may be negative. However, many uncertainties remain regarding the role of ice clouds on Earth's radiative budget and in a changing climate. Global satellite observations are particularly well suited to monitoring clouds, retrieving their characteristics and inferring their radiative impact. To retrieve ice cloud properties (optical thickness and ice crystal effective size), current operational algorithms assume that each pixel of the observed scene is plane-parallel and homogeneous, and that there is no radiative connection between neighboring pixels. Yet these retrieval assumptions are far from accurate, as real radiative transfer is 3-D. This leads to the plane-parallel and homogeneous bias (PPHB) plus the independent pixel approximation bias (IPAB), which impacts both the estimation of top-of-the-atmosphere (TOA) radiation and the retrievals. An important factor that determines the impact of these assumptions is the sensor spatial resolution. High-spatial-resolution pixels can better represent cloud variability (low PPHB), but the radiative path through the cloud can involve many pixels (high IPAB). In contrast, low-spatial-resolution pixels poorly represent the cloud variability (high PPHB), but the radiation is better contained within the pixel field of view (low IPAB). In addition, the solar and viewing geometry (as well as cloud optical properties) can modulate the magnitude of the PPHB and IPAB. In this, Part II of our study, we simulate TOA 0.86 and 2.13 µm solar reflectances over a cirrus uncinus scene produced by the 3DCLOUD model. Then, 3-D radiative transfer simulations are performed with the 3DMCPOL code at spatial resolutions ranging from 50&thinsp;m to 10&thinsp;km, for 12 viewing geometries and nine solar geometries. It is found that, for simulated nadir observations taken at resolution higher than 2.5&thinsp;km, horizontal radiation transport (HRT) dominates biases between 3-D and 1-D reflectance calculations, but these biases are mitigated by the side illumination and shadowing effects for off-zenith solar geometries. At resolutions coarser than 2.5&thinsp;km, PPHB dominates. For off-nadir observations at resolutions higher than 2.5&thinsp;km, the effect that we call THEAB (tilted and homogeneous extinction approximation bias) due to the oblique line of sight passing through many cloud columns contributes to a large increase of the reflectances, but 3-D radiative effects such as shadowing and side illumination for oblique Sun are also important. At resolutions coarser than 2.5&thinsp;km, the PPHB is again the dominant effect. The magnitude and resolution dependence of PPHB and IPAB is very different for visible, near-infrared and shortwave infrared channels compared with the thermal infrared channels discussed in Part I of this study. The contrast of 3-D radiative effects between solar and thermal infrared channels may be a significant issue for retrieval techniques that simultaneously use radiative measurements across a wide range of solar reflectance and infrared wavelengths.</p

The Prospect of Detecting Volcanic Signatures on an ExoEarth Using Direct Imaging

The James Webb Space Telescope (JWST) has provided the first opportunity to study the atmospheres of terrestrial exoplanets and estimate their surface conditions. Earth-sized planets around Sun-like stars are currently inaccessible with JWST however, and will have to be observed using the next generation of telescopes with direct imaging capabilities. Detecting active volcanism on an Earth-like planet would be particularly valuable as it would provide insight into its interior, and provide context for the commonality of the interior states of Earth and Venus. In this work we used a climate model to simulate four exoEarths over eight years with ongoing large igneous province eruptions with outputs ranging from 1.8-60 Gt of sulfur dioxide. The atmospheric data from the simulations were used to model direct imaging observations between 0.2-2.0 $\mu$m, producing reflectance spectra for every month of each exoEarth simulation. We calculated the amount of observation time required to detect each of the major absorption features in the spectra, and identified the most prominent effects that volcanism had on the reflectance spectra. These effects include changes in the size of the O$_3$, O$_2$, and H$_2$O absorption features, and changes in the slope of the spectrum. Of these changes, we conclude that the most detectable and least ambiguous evidence of volcanism are changes in both O$_3$ absorption and the slope of the spectrum.Comment: 13 pages, 5 figures, 4 tables, Accepted for publication in AJ (September 26, 2023

Sensitive Probing of Exoplanetary Oxygen via Mid Infrared Collisional Absorption

The collision-induced fundamental vibration-rotation band at 6.4 um is the most significant absorption feature from O2 in the infrared (Timofeyev and Tonkov, 1978; Rinslandet al., 1982, 1989), yet it has not been previously incorporated into exoplanet spectral analyses for several reasons. Either CIAs were not included or incomplete/obsolete CIA databases were used. Also, the current version of HITRAN does not include CIAs at 6.4 um with other collision partners (O2-X). We include O2-X CIA features in our transmission spectroscopy simulations by parameterizing the 6.4 um O2-N2 CIA based on Rinsland et al.(1989) and the O2-CO2 CIA based on Baranov et al. (2004). Here we report that the O2-X CIA may be the most detectable O2 feature for transit observations. For a potentialTRAPPIST-1e analogue system within 5 pc of the Sun, it could be the only O2 detectable signature with JWST (using MIRI LRS) for a modern Earth-like cloudy atmosphere with biological quantities of O2. Also, we show that the 6.4 um O2-X CIA would be prominent for O2-rich desiccated atmospheres (Luger and Barnes, 2015) and could be detectable with JWST in just a few transits. For systems beyond 5 pc, this feature could therefore be a powerful discriminator of uninhabited planets with non-biological "false positive" O2 in their atmospheres - as they would only be detectable at those higher O2 pressures.Comment: Published in Nature Astronom

Evaluating the Plausible Range of N2O Biosignatures on Exo-Earths: An Integrated Biogeochemical, Photochemical, and Spectral Modeling Approach

Nitrous oxide (N2O) -- a product of microbial nitrogen metabolism -- is a compelling exoplanet biosignature gas with distinctive spectral features in the near- and mid-infrared, and only minor abiotic sources on Earth. Previous investigations of N2O as a biosignature have examined scenarios using Earthlike N2O mixing ratios or surface fluxes, or those inferred from Earth's geologic record. However, biological fluxes of N2O could be substantially higher, due to a lack of metal catalysts or if the last step of the denitrification metabolism that yields N2 from N2O had never evolved. Here, we use a global biogeochemical model coupled with photochemical and spectral models to systematically quantify the limits of plausible N2O abundances and spectral detectability for Earth analogs orbiting main-sequence (FGKM) stars. We examine N2O buildup over a range of oxygen conditions (1%-100% present atmospheric level) and N2O fluxes (0.01-100 teramole per year; Tmol = 10^12 mole) that are compatible with Earth's history. We find that N2O fluxes of 10 [100] Tmol yr$^{-1}$ would lead to maximum N2O abundances of ~5 [50] ppm for Earth-Sun analogs, 90 [1600] ppm for Earths around late K dwarfs, and 30 [300] ppm for an Earthlike TRAPPIST-1e. We simulate emission and transmission spectra for intermediate and maximum N2O concentrations that are relevant to current and future space-based telescopes. We calculate the detectability of N2O spectral features for high-flux scenarios for TRAPPIST-1e with JWST. We review potential false positives, including chemodenitrification and abiotic production via stellar activity, and identify key spectral and contextual discriminants to confirm or refute the biogenicity of the observed N2O.Comment: 22 pages, 17 figures; ApJ, 937, 10