Levels of Organochlorine Pesticides and Heavy Metals in Surface Waters of Konya Closed Basin, Turkey

The concentrations of organochlorine pesticides (OCPs), including α-, β-, γ-, and δ-hexachlorocyclohexane (HCH), heptachlor, heptachlor epoxide, dieldrin, aldrin, endrin, endrin aldehyde, endrin ketone, endosulfan I, endosulfan II, endosulfan sulfate, p,p′-DDE, p,p′-DDD, p,p′-DDT, methoxychlor, chlordane I, chlordane II, and heavy metals, such as As, Cr, Cu, Fe, Mn, and Ni in surface water samples from the Konya closed basin were determined to evaluate the level of contamination. Among all HCH isomers, β-HCH is the main isomer with a concentration range of 0.015–0.065 μg/L. DDE, DDD, and DDT were almost determined in all samples, in which DDE isomer had the highest concentration ranged from not detected to 0.037 μg/L. In all studied OCPs, aldrin showed the highest concentration at 0.220 μg/L. The concentrations of heavy metals in water samples were observed with order: Mn < Cu < Ni < As < Cr < Fe. In some samples, As, Fe, and Cr concentrations exceeded the drinking water quality recommended by EU, US EPA, WHO, and Turkish Regulation, while Cu, Ni, and Mn concentrations are below the guideline values. The levels of both OCPs and heavy metals were also compared with other previously published data

Analysis of diclofenac in water samples using in situ derivatization-vortex-assisted liquid-liquid microextraction with gas chromatography-mass spectrometry

A novel micro-extraction technique for a rapid and sensitive analysis of diclofenac (DCF) in water samples has been developed. DCF was derivatized and extracted simultaneously using vortex-assisted liquid-liquid micro-extraction (VALLME) prior to gas chromatography with mass spectrometry detection. The effects of extraction solvent volume, extraction and derivatization time and ionic strength of the sample were studied using 23 factorial experimental design. The optimum extraction conditions were as follows: 200 µL of chloroform, 25 µL of N-methyl-N-trimethylsilyl-trifluoroacetamide (MSTFA) derivatization reagent, vortex extraction and derivatization time 5 min at 3000 rpm. The extraction recovery for different fortification levels was 98 %. Also, the proposed micro-extraction method exhibited results comparable with the solid phase extraction of real water samples. The proposed one-step VALLME and derivatization method is simpler and faster than the conventional extraction and derivatization methods used for the determination of DCF in real water samples

Analysis of diclofenac in water samples using in situ derivatization-vortex-assisted liquid-liquid microextraction with gas chromatography-mass spectrometry

A novel micro-extraction technique for a rapid and sensitive analysis of diclofenac (DCF) in water samples has been developed. DCF was derivatized and extracted simultaneously using vortex-assisted liquid-liquid micro-extraction (VALLME) prior to gas chromatography with mass spectrometry detection. The effects of extraction solvent volume, extraction and derivatization time and ionic strength of the sample were studied using 23 factorial experimental design. The optimum extraction conditions were as follows: 200 μL of chloroform, 25 μL of N-methyl-N-trimethylsilyl-trifluoroacetamide (MSTFA) derivatization reagent, vortex extraction and derivatization time 5 min at 3000 rpm. The extraction recovery for different fortification levels was 98 %. Also, the proposed micro-extraction method exhibited results comparable with the solid phase extraction of real water samples. The proposed one-step VALLME and derivatization method is simpler and faster than the conventional extraction and derivatization methods used for the determination of DCF in real water samples