LA-MC-ICPMS and SHRIMP U-Pb dating of complex zircons from Quarternary tephras from the French Massif Central: Magma residence time and geochemical implications

Analyses of zircon grains from the Queureuilh Quaternary tephras (pumice) provide new information about their pre-eruptive history. U-Pb dating was performed in situ using two methods: SHRIMP and LA-MC-ICPMS equipped with a multi-ion counting system. Both methods provided reliable 207Pb/206Pb and 206Pb/238U ratios as well as U and Th abundances required for U-Pb Concordia intercept age determination, after initial 230Th disequilibrium correction. The new LA-MC-ICPMS method was validated by dating a reference zircon (61.308B) and zircons from a phonolitic lava dated independently with the two techniques. A time resolution of about 20 kyr for 1 Ma zircon crystals was achieved for both methods. The clear euhedral zircon population from Queureuilh tephras is quite complex from several points of view: (1) some grains are reddish or yellowish while others are colorless; (2) the U and Th composition changes by more than an order of magnitude and Th/U is generally high (∼1-2); (3) there are three discrete ages recorded at 2.35 ± 0.04, 1.017 ± 0.008 and 0.640 ± 0.010 Ma. From the previously determined 40Ar/39Ar age at 0.571 ± 0.060 Ma [Duffell H. (1999) Contribution géochronologique à la stratigraphie volcanique du Massif des Monts Dore par la méthode 40Ar/39Ar. D.E.A. Univ. Clermont-Ferrand, 56 p.], the discontinuous zircon age populations, the color of the grains and their composition, we favor the following model as explanation: The oldest, less numerous group of reddish zircons represents xenocrystic grains resulting from assimilation of the local material during magma ascent. A primitive magma chamber, perhaps deep in crustal level, was formed at 1.0 Ma. The related magma, previously characterized by high Th/U ratio (2.2 ± 1.1), underwent rejuvenation during ascent to a new chamber at shallow depth and/or during injection of more mafic magmas. During this stage, at 0.64 Ma, the colorless zircon grains of lower Th/U ratio (1.3 ± 0.5) crystallized. This last stage defined the magma residence time of 70 kyr prior to eruption dated by the 40Ar/39Ar method. However, if the primitive magma is considered, the magma residence time as a whole from this first stage reached 446 kyr. In the light of the complex history of such magmas, which commonly involves recycling of zircon grains that precipitated tens to hundreds of kyr earlier than eruptions, the use of Zr concentration in geochemical modeling of whole rock compositional data can be problematic

Dating the Triassic continental rift in the southern Andes : The Potrerillos Formation, Cuyo Basin, Argentina

The Triassic successions of western Argentina commonly show thin pyroclastic levels intercalated within thick fluvial and lacustrine terrigenous deposits. The Potrerillos Formation is the thickest Triassic unit in the Cuyo Basin. It is composed of alternating cycles of gravelly- sandy- and muddy-dominated intervals, in which several laterally-continuous tuff horizons occur. U-Pb SHRIMP ages were determined on zircon grains from three tuff levels located between the lowermost and the middle sections of the Potrerillos Formation. The ages for the time of deposition of the tuffs are 239.2 ± 4.5 Ma, 239.7 ± 2.2 Ma and 230.3 ± 2.3 Ma (Middle Triassic). Chemical data indicate that these acid to intermediate volcaniclastic rocks are derived from coeval basic magmas displaying tholeiitic to slightly alkaline signatures. They are associated with the rift stage that followed the extensive post-orogenic volcanism of the Choiyoi Group, that in turn has been ascribed to slab break-off in neighbouring areas. Two of the studied samples also record a subpopulation of inherited zircon grains with crystallisation ages of 260-270 Ma. The latter are considered to be an indirect measurement for the age of the Choiyoi Group in the Cuyo basin. The rift-related Triassic event represents the culmination of the Gondwanian magmatic cycle, and is interpreted as the result of subduction cessation and anomalous heating of the upper mantle previous to the western Gondwana break-up.Centro de Investigaciones Geológica

Dating the Triassic continental rift in the southern Andes : The Potrerillos Formation, Cuyo Basin, Argentina

The Triassic successions of western Argentina commonly show thin pyroclastic levels intercalated within thick fluvial and lacustrine terrigenous deposits. The Potrerillos Formation is the thickest Triassic unit in the Cuyo Basin. It is composed of alternating cycles of gravelly- sandy- and muddy-dominated intervals, in which several laterally-continuous tuff horizons occur. U-Pb SHRIMP ages were determined on zircon grains from three tuff levels located between the lowermost and the middle sections of the Potrerillos Formation. The ages for the time of deposition of the tuffs are 239.2 ± 4.5 Ma, 239.7 ± 2.2 Ma and 230.3 ± 2.3 Ma (Middle Triassic). Chemical data indicate that these acid to intermediate volcaniclastic rocks are derived from coeval basic magmas displaying tholeiitic to slightly alkaline signatures. They are associated with the rift stage that followed the extensive post-orogenic volcanism of the Choiyoi Group, that in turn has been ascribed to slab break-off in neighbouring areas. Two of the studied samples also record a subpopulation of inherited zircon grains with crystallisation ages of 260-270 Ma. The latter are considered to be an indirect measurement for the age of the Choiyoi Group in the Cuyo basin. The rift-related Triassic event represents the culmination of the Gondwanian magmatic cycle, and is interpreted as the result of subduction cessation and anomalous heating of the upper mantle previous to the western Gondwana break-up.Centro de Investigaciones Geológica

Proterozoic crustal evolution of central East Antarctica: Age and isotopic evidence from glacial igneous clasts, and links with Australia and Laurentia

Rock clasts entrained in glacial deposits sourced from the continental interior of Antarctica provide an innovative means to determine the age and composition of ice-covered crust. Zircon U-Pb ages from a suite of granitoid clasts collected in glacial catchments draining central East Antarctica through the Transantarctic Mountains show that crust in this region was formed by a series of magmatic events at ∼2.01, 1.88–1.85, ∼1.79, ∼1.57, 1.50–1.41, and 1.20–1.06 Ga. The dominant granitoid populations are ca. 1.85, 1.45 and 1.20–1.06 Ga. None of these igneous ages are known from limited outcrop in the region. In addition to defining a previously unrecognized geologic history, zircon O and Hf isotopic compositions from this suite have: (1) mantle-like δ18O signatures (4.0–4.5‰) and near-chondritic Hf-isotope compositions (εHf ∼ +1.5) for granitoids of ∼2.0 Ga age; (2) mostly crustal δ18O (6.0–8.5‰) and variable Hf-isotope compositions (εHf = −6 to +5) in rocks with ages of ∼1.88–1.85, ∼1.79 and ∼1.57 Ga, in which the ∼1.88–1.79 Ga granitoids require involvement of older crust; (3) mostly juvenile isotopic signatures with low, mantle-like δ18O (∼4–5‰) and radiogenic Hf-isotope signatures (εHf = +6 to +10) in rocks of 1.50–1.41 Ga age, with some showing crustal sources or evidence of alteration; and (4) mixed crustal and mantle δ18O signatures (6.0–7.5‰) and radiogenic Hf isotopes (εHf = +3 to +4) in rocks of ∼1.2 Ga age. Together, these age and isotopic data indicate the presence in cratonic East Antarctica of a large, composite igneous province that formed through a punctuated sequence of relatively juvenile Proterozoic magmatic events. Further, they provide direct support for geological correlation of crust in East Antarctica with both the Gawler Craton of present-day Australia and Proterozoic provinces in western Laurentia. Prominent clast ages of ∼2.0, 1.85, 1.57 and 1.45 Ga, together with sediment source linkages, provide evidence for the temporal and spatial association of these cratonic elements in the Columbia supercontinent. Abundant ∼1.2–1.1 Ga igneous and metamorphic clasts may sample crust underlying the Gamburtsev Subglacial Mountains, indicating the presence of a Mesoproterozoic orogenic belt in the interior of East Antarctica that formed during final assembly of Rodinia.Field and analytical portions of this project were supported by the National Science Foundation (award 0944645)

Timing of extension in the Pioneer metamorphic core complex with implications for the spatial-temporal pattern of Cenozoic extension and exhumation in the northern U.S. Cordillera

The Pioneer core complex (PCC) in central Idaho lies along a transition between Early Eocene and ca. 40 Ma core complexes to the north and south, respectively. Thus, the age of extensional development of the PCC is important in understanding the spatial-temporal patterns of core-complex development in the North American Cordillera. New results, including structural observations and U-Pb zircon (SHRIMP and ICPMS) geochronology, constrain the early extensional history of the footwall for the first time. High-temperature strain with a top-WNW shear-sense is pervasive throughout metamorphic rocks of the northwestern footwall. An isoclinally folded dike yields a crystallization age of ∼48-47 Ma, whereas a crosscutting dike yielded an age of 46 Ma. Metamorphic rocks are also intruded by the ∼50-48 Ma Pioneer intrusive suite (PIS), a W-dipping granodiorite sheet displaying a magmatic fabric. Northwest-trending lineations are locally visible and also defined by anisotropy of magnetic susceptibility, indicating that during emplacement, the PIS was undergoing similarly oriented extensional strain as the enclosing metamorphic rocks. Therefore, WNW-directed extension spanning this structural section occurred between ∼50 and 46 Ma. Following emplacement of crosscutting 46 Ma dikes, deformation was partitioned into the WNW-directed Wildhorse detachment. Motion on the detachment occurred between ∼38 and 33 Ma, as documented by previous 40Ar/ 39Ar thermochronology. It is not clear, however, whether extension was continuous through the interval between these two time periods. Although Early Eocene extension in the PCC was synchronous with extension in core complexes to the north, rates of footwall exhumation in central Idaho were much lower. This southward slowing is compatible with N-S differences in inferred subduction zone geometry/kinematics and in the internal character of the orogenic wedge

First magmatism in the New England Batholith, Australia: Forearc and arc-back-arc components in the Bakers Creek Suite gabbros

The New England Orogen, eastern Australia, was established as an outboard extension of the Lachlan Orogen through the migration of magmatism into forearc basin and accretionary prism sediments. Widespread S-type granitic rocks of the Hillgrove and Bundarra supersuites represent the first pulse of magmatism, followed by I-A nd A-types typical of circum-Pacific extensional accretionary orogens. Associated with the former are a number of small tholeiite-gabbroic to intermediate bodies of the Bakers Creek Suite, which sample the heat source for production of granitic magmas and are potential tectonic markers indicating why magmatism moved into the forearc and accretionary complexes rather than rifting the old Lachlan Orogen arc. The Bakers Creek Suite gabbros capture an early (∼305Ma) forearc basalt-like component with low Th/Nb and with high Y/Zr and Ba/La, recording melting in the mantle wedge with little involvement of a slab flux and indicating forearc rifting. Subsequently, arc-back-arc like gabbroic magmas (305-304Ma) were emplaced, followed by compositionally diverse magmatism leading up to the main S-type granitic intrusion (∼290Ma). This trend in magmatic evolution implicates forearc and other mantle wedge melts in the heating and melting of fertile accretion complex sediments and relatively long (∼10Myr) timescales for such meltingThis research was partially supported by an Australian National University PhD Research Scholarship to Seann J. McKibbin, who is currently a postdoctoral fellow of the Research Foundation – Flanders (Fonds Wetenschapplijke Onderszoek; FWO

U-Pb zircon ages of the Wildhorse gneiss, Pioneer Mountains, south-central Idaho, and tectonic implications

The gneiss complex of Wildhorse Creek (Wildhorse gneiss) forms the central component of the lowest structural plate in the Pioneer metamorphic core complex of south-central Idaho. The oldest rock in the complex is a felsic ortho-gneiss, with Neoarchean U-Pb magmatic zircon ages of 2.60-2.67 Ga. The ortho-gneiss overlaps in age and is interpreted to be part of the Grouse Creek block of the Albion Mountains to the south. This Archean metagranitoid is structurally interleaved with paragneiss containing quartzite and calc-silicate rock. Structurally below the orthogneiss, some quartzites have multiple concordant populations of detrital-zircon grains as young as ca. 1700 Ma, while others have no zircon grains younger than ca. 2500 Ma. Structurally above the Archean gneiss is a heterogeneous paragneiss that contains calc-silicate and quartzitic rocks with detrital zircons as young as ca. 1460 Ma. Amphibolite in this unit contains zircons dated at ca. 1850 Ma, indicating that this rock can be no older than that and implying considerable structural complexity. The upper part of the Wildhorse gneiss contains metaquartzites bearing zircons as young as ca. 1400 Ma. The protolith of this paragneiss is interpreted as the southernmost exposures of the Lemhi subbasin of the Mesoproterozoic Belt Supergroup. The upper Wildhorse gneiss includes ca. 695 Ma intrusive orthogneiss that is coeval with Neoproterozoic rift-related volcanic or intrusive rocks near Pocatello, House Mountain, and Edwardsburg, Idaho. This Cryogenian meta-intrusive rock is the likely source of the 650-710 Ma detrital-zircon population in the Big Lost River that drains the core complex. Initial eHf values from 675 Ma zircons are between 3.4 and -2.4, suggesting the granitoids had a mixed source in both continental crust and juvenile mantle.This research was supported by National Science Foundation grants EAR 05-10980 and 08-38425 and U.S. Geological Survey grant G14AC00136. Logistical support was provided by the Idaho State University Geology field camp at Lost River Field Station

Geochemistry and geochronology of the shallow-level La Esperanza magmatic system (Permian-Triassic), Northern Patagonia

The La Esperanza plutonic-volcanic complex is the largest Late Paleozoic-Early Triassic composite magmatic system of northern Patagonia. This paper reports new SHRIMP U-Pb zircon ages and K-Ar muscovite dating as well as whole-rock geochemical data for selected units. In addition, we present some new and reprocessed whole-rock Sr isotopic compositions. On the basis of the new and published data, three compositionally and isotopically distinct high-K magnesian calc-alkaline series were distinguished. Two of these are characterized by high Ba-Sr: (i) biotite and muscovite bearing rhyolites and granites (265 ± 2 Ma; 260 ± 2 Ma) and (ii) metaluminous amphibole-biotite bearing granodiorites (273 ± 2 Ma), monzogranites (255 ± 2 Ma), dacites (253 ± 2 Ma), and slightly peraluminous granites (dated herein as 251 ± 2 Ma). There is also a low Ba-Sr series of high-silica metaluminous rocks (granites and acid dike swarms; 250 ± 2 Ma and ≈244 ± 2 Ma). Geochemistry coupled with geochronology revealed a pulsatory multi-sourced open magmatic system with mafic magma replenishment and reactivation of crystal mushes that occurred before upward migration to upper crustal levels. Mafic magmas alternated with crust-derived magmas incrementally assembled in subvolcanic levels over 30 Ma. Zircon crystallization and mica cooling ages in the granite units allowed detection of two magmatic lulls, between 270 and 265 Ma and between 260 and 255 Ma. Both episodes coincide with a period of exhumation in upper crustal levels. The new temporal and geochemical constraints allow correlation of the La Esperanza plutonic-volcanic complex with the Los Menucos Group (258-248 Ma), encompassing a volume of magmatism comparable to a moderately sized large igneous silicic province. These mid-to-late Permian to Middle Triassic rocks record the transition between subduction-related magmatism (>273 Ma) and post-orogenic extensional magmatism (<250 Ma) in the Gondwana margin. Even though this magmatism would be coeval with the proposed collision of the Patagonia terrane, no expected syn-collisional magmatism or associated deformation were found in upper crustal levels. However, the different nature and melting conditions of the inferred sources of the magmas that crystallized before 270 Ma, between 265 and 260 Ma, and from 255 to 245 Ma, suggest that the La Esperanza plutonic-volcanic complex was assembled during a 30 Ma period of major plate reorganization.Fil: Martínez Dopico, Carmen Irene. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotópica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; ArgentinaFil: Lopez, Monica Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotópica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; ArgentinaFil: Rapalini, Augusto Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires; ArgentinaFil: Fanning, Christopher Mark. The Australian National University; AustraliaFil: Antonio, Paul Yves Jean. Universidade de Sao Paulo; Brasi