Revealing the hydrological history of Mars

The study of the history and present availability of water on Mars is critical to understanding geological processes and life on Mars, and to preparing for human exploration of Mars. NASA set forth the theme of Following the Water for the Mars exploration program. Following the theme, I presents this dissertation on 1) the origin of sulfates in the equatorial region of western Mars, 2) the water signature of gully-exposed sites on Mars, and 3) a characterization of the Phoenix landing site in an attempt to better understand the hydrologic history of early Mars, and the availability of water on Mars in recent geologic time and the present day. A new hypothesis for the origin and redistribution of sulfates in the equatorial region of western Mars was proposed in terms of the observed distribution occurrence of sulfates and the physiographic processes (volcanic, tectonic and sedimentary) affecting the Martian surface. This hypothesis integrates logically 1) the fate of sulfates in Valles Marineris and the source of sulfates in Meridiani Planum, and 2) the formation of sulfates in the equatorial region of western Mars, the Tharsis rise and Valles Marineris. This research implies that there was a dynamic Martian surface in early Martian history and liquid water was active at least until the Hesperian epoch. Investigation of water signatures at gully-exposed sites on Mars by hyperspectral image analysis finds that the depths of the water-related absorption bands are greater at the four selected gully-exposed sites than in surrounding areas. The stronger signature of water at the gully-exposed sites than their surrounding areas indicates more water (water-ice, isolated water molecules and hydroxyl) is likely contained in the surface materials at the gully-exposed sites and implies that the formation of gullies on Mars might have involved processes associated with liquid water. One interpretation might be that liquid water has been active in recent geological time, even to the present. Characterization of the Phoenix landing site indicates that it is in a plain composed of the soils or regolith of weathered basaltic andesite on the surface and water-ice or icy soil (permafrost) within centimetres or tens of centimetres below the surface. The landing site is an ideal site for investigating water and water-ice, and its potential as a habitat for life on Mars

Controls of Phosphorus Loading and Transport in the Cuyahoga River of Northeastern Ohio, USA

An urban stream differs from a natural stream in that it commonly contains anthropogenic nutrients from a variety of diffuse and point sources (e.g., urban runoff, industrial and municipal effluents). The Cuyahoga River as one of such stream systems receives on average 30% of water from over a dozen wastewater treatment plants (WWTPs) and exports over 300 Mg/yr of total phosphorus (TP) into Lake Erie. Municipal effluents account for at least two thirds of the TP loading and 90% of the effluent TP is in the form of soluble reactive phosphorus (SRP), i.e., the highly bioavailable form in aquatic ecosystems. Owing to its dominance of the effluent P, the Cuyahoga River may pose a disproportionately greater ecological risk to Lake Erie. Here we report results of TP and SRP as measured on water samples collected from 12 locations along the Cuyahoga River and its major tributary – Tinkers Creek under three different flow conditions in July 2007 through May 2008. Our results show that the loadings of SRP and TP increased progressively with the effluent inputs increasing from the upper basin downstream. We found the loadings of SRP and TP are not only affected by the amount of effluent P input but also regulated by stream flow regimes. Effluent P is more likely to be transformed during storm runoff events, whereas TP is more likely to be retained under low flow conditions. As a result, most of the TP loading was exported during the storm and intermediate flow conditions, whereas most of the SRP loading was delivered during the low and intermediate flow conditions. These results suggest that stream hydrology has played an important role in the loading and transport of P across the Cuyahoga River as it dictated the amount, form, and timing of P exported to Lake Erie

Controls of Phosphorus Loading and Transport in the Cuyahoga River of Northeastern Ohio, USA

An urban stream differs from a natural stream in that it commonly contains anthropogenic nutrients from a variety of diffuse and point sources (e.g., urban runoff, industrial and municipal effluents). The Cuyahoga River as one of such stream systems receives on average 30% of water from over a dozen wastewater treatment plants (WWTPs) and exports over 300 Mg/yr of total phosphorus (TP) into Lake Erie. Municipal effluents account for at least two thirds of the TP loading and 90% of the effluent TP is in the form of soluble reactive phosphorus (SRP), i.e., the highly bioavailable form in aquatic ecosystems. Owing to its dominance of the effluent P, the Cuyahoga River may pose a disproportionately greater ecological risk to Lake Erie. Here we report results of TP and SRP as measured on water samples collected from 12 locations along the Cuyahoga River and its major tributary – Tinkers Creek under three different flow conditions in July 2007 through May 2008. Our results show that the loadings of SRP and TP increased progressively with the effluent inputs increasing from the upper basin downstream. We found the loadings of SRP and TP are not only affected by the amount of effluent P input but also regulated by stream flow regimes. Effluent P is more likely to be transformed during storm runoff events, whereas TP is more likely to be retained under low flow conditions. As a result, most of the TP loading was exported during the storm and intermediate flow conditions, whereas most of the SRP loading was delivered during the low and intermediate flow conditions. These results suggest that stream hydrology has played an important role in the loading and transport of P across the Cuyahoga River as it dictated the amount, form, and timing of P exported to Lake Erie

Cylindrical nano-indentation on metal film/elastic substrate system with discrete dislocation plasticity analysis: A simple model for nano-indentation size effect

AbstractThe cylindrical nano-indentation on metal film/elastic substrate is computationally studied using two-dimensional discrete dislocation plasticity combined with the commercial software ANSYS®, with a focus on the storage volume for geometrically necessary dislocations (GNDs) inside the films and the nano-indentation size effect (NISE). Our calculations show that almost all GNDs are stored in a rectangular area determined by the film thickness and the actual contact width. The variations of indentation contact width with indentation depth for various film thicknesses and indenter radii are fitted by an exponential relation, and then the GND density underneath the indenter is estimated. Based on the Taylor dislocation model and Tabor formula, a simple model for the dependence of the nano-indentation hardness of the film/substrate system on the indentation depth, the indenter radius and the film thickness is established, showing a good agreement with the present numerical results

DFPENet-geology: A Deep Learning Framework for High Precision Recognition and Segmentation of Co-seismic Landslides

The following lists two main reasons for withdrawal for the public. 1. There are some problems in the method and results, and there is a lot of room for improvement. In terms of method, "Pre-trained Datasets (PD)" represents selecting a small amount from the online test set, which easily causes the model to overfit the online test set and could not obtain robust performance. More importantly, the proposed DFPENet has a high redundancy by combining the Attention Gate Mechanism and Gate Convolution Networks, and we need to revisit the section of geological feature fusion, in terms of results, we need to further improve and refine. 2. arXiv is an open-access repository of electronic preprints without peer reviews. However, for our own research, we need experts to provide comments on my work whether negative or positive. I then would use their comments to significantly improve this manuscript. Therefore, we finally decided to withdraw this manuscript in arXiv, and we will update to arXiv with the final accepted manuscript to facilitate more researchers to use our proposed comprehensive and general scheme to recognize and segment seismic landslides more efficiently.Comment: 1. There are some problems in the method and results, and there is a lot of room for improvement. Overall, the proposed DFPENet has a high redundancy by combining the Attention Gate Mechanism and Gate Convolution Networks, and we need to further improve and refine the results. 2. For our own research, we need experts to provide comments on my work whether negative or positiv

Evaporative Enrichment of Oxygen-18 and Deuterium in Lake Waters on the Tibetan Plateau

Stable isotopes (δ18O and δD) are useful tracers for investigating hydrologic and climatic variability on a variety of temporal and spatial scales. Since the early isotopic studies on mountainous glaciers in the late 1960s, a great deal of information has been generated on the isotopic composition of rainfall, snow, ice, surface waters, and lake carbonate sediments across the Tibetan Plateau. However, measurements of δ18O and δD values of lake water are scarce. Here we present a new dataset of δ18O and δD values of lake waters collected from 27 lakes across the plateau during a reconnaissance survey in summer 2009. δ18O and δD values of lake water range from −19.9 to 6.6‰ and from −153 to −16‰, respectively. The average values of δ18O and δD are −6.4 and −72‰, considerably greater than those of precipitation observed in this region. The derived Tibetan lake water line, δD = 5.2δ18O − 38.9, is significantly different from the global meteoric water line. Most of the lakes, including some freshwater lakes, contain water with negative values of d-excess (d). There is a negative correlation between d and total dissolved solids (TDS). Each of these findings indicates that evaporation-induced isotopic enrichment prevails in Tibetan lakes. Moreover, we develop an isotope modeling scheme to calculate E/P ratios for Tibetan lakes, using a combination of existing isotopic fractionation equations and the Rayleigh distillation model. We use the intersection of the local evaporation line and GMWL as a first approximation of δ18O and δD values of lake water inputs to infer an E/P ratio for each lake. Our modeling calculations reveal that although variable from lake to lake, the water budget across the plateau is positive, with an average E/P of 0.52. This is in good agreement with other observational and model data that show varying degrees of increases in lake size from satellite imagery and significant decreases in lake salinity in many lakes on the plateau over the last several decades. Together with the new isotopic dataset, the proposed modeling framework can be used to examine and quantify past changes in a lake’s hydrologic balance from the isotopic record of downcore carbonate sediments in the region

Identifying post-earthquake debris flow hazard using Massflow

Catastrophic debris flows are common after large earthquakes and pose a significant risk for recovering communities. The depositional volume of these large debris flows is often much greater than the initiation volume, suggesting that bulking of the flow plays an important role in determining their volume, speed, and runout distance. Observations from recent earthquakes have driven progress in understanding the relationship between triggering rainfall events and the timing of post-earthquake debris flows. However, we lack an adequate mechanism for quantifying bulking and applying it within a hazard context. Here we apply a 2D dynamic debris flow model (Massflow) that incorporates a process-based expression of basal entrainment to understand how debris flow bulking may occur within post-earthquake catchments and develop hazard maps. Focussing on catchments in the epicentral area of the 2008 Mw 7.9 Wenchuan Earthquake, we first parameterised the model based on a large debris flow that occurred within the Hongchun catchment, before applying the calibrated model to adjoining catchments. A model sensitivity analysis identified three main controls on debris flow bulking; the saturation level of entrainable material along the flow pathway, and the size and position of initial mass failures. The model demonstrates that the difference between small and very large debris flows occur across a narrow range of pore-water ratios (λ). Below λ = 0.65 flows falter at the base of hillslopes and come to rest in the valley bottom, above λ = 0.70 they build sufficient mass and momentum to sustain channelised flow and transport large volumes of material beyond the valley confines. Finally, we applied the model across different catchments to develop hazard maps that demonstrate the utility of Massflow in post-earthquake planning within the Wenchuan epicentral region

Black porous silicon as a photothermal agent and immunoadjuvant for efficient antitumor immunotherapy

Photothermal therapy (PTT) in combination with other treatment modalities has shown great potential to activate immunotherapy against tumor metastasis. However, the nanoparticles (NPs) that generate PTT have served as the photothermal agent only. Moreover, researchers have widely utilized highly immuno-genic tumor models to evaluate the immune response of these NPs thus giving over-optimistic results. In the present study black porous silicon (BPSi) NPs were developed to serve as both the photothermal agent and the adjuvant for PTT-based antitumor immunotherapy. We found that the poorly immunogenic tumor models such as B16 are more valid to evaluate NP-based immunotherapy than the widely used im-munogenic models such as CT26. Based on the B16 cancer model, a cocktail regimen was developed that combined BPSi-based PTT with doxorubicin (DOX) and cytosine-phosphate-guanosine (CpG). BPSi-based PTT was an important trigger to activate the specific immunotherapy to inhibit tumor growth by featuring the selective upregulation of TNF-alpha. Either by adding a low dose DOX or by prolonging the laser heating time, a similar efficacy of immunotherapy was evoked to inhibit tumor growth. Moreover, BPSi acted as a co-adjuvant for CpG to significantly boost the immunotherapy. The present study demonstrates that the BPSi-based regimen is a potent and safe antitumor immunotherapy modality. Moreover, our study high-lighted that tuning the laser heating parameters of PTT is an alternative to the toxic cytostatic to evoke immunotherapy, paving the way to optimize the PTT-based combination therapy for enhanced efficacy and decreased side effects.Peer reviewe

Energy evolution mechanism during rockburst development in structures of surrounding rocks of deep rockburst-prone roadways in coal mines

Influenced by the deep high-stress environment, geological structures, and mining disturbance in coal mines, the frequency of rockburst disasters in roadways is increasing. This research analyzed energy evolution characteristics during rockburst development in the elastic bearing zone and energy conversion in the plastic failure zone. The critical energy criteria for structural instability of roadway surrounding rocks were deduced. Numerical software was also applied to simulate the energy evolution during rockburst development in surrounding rocks of rockburst-prone roadways under conditions of different mining depths and coal pillar widths. The occurrence mechanism of rockburst deep in coal mines was analyzed from the perspective of energy in structures of deep roadway surrounding rock in coal mines. The research results show that the critical energy criteria are closely related to the elastic strain energy stored in deep roadway surrounding rocks and the energy absorbed by support systems. The impact energy in roadways is directly proportional to the square of the stress concentration factor k. Moreover, as the mining depth increases, the location of the peak point of maximum energy density gradually shifts to coal ahead of the working face. The larger the mining depth is, the more significantly the energy density is influenced by advanced abutment pressure of the working face and the wider the affected area is. With the increment of the coal pillar width, the distance from the peak point of energy density to the roadway boundary enlarges abruptly at first and then slowly, and the critical coal pillar width for gentle change in the distance is 30 m. Changes in the peak elastic energy density in coal pillars with the coal pillar width can be divided into four stages: the slow increase stage, abrupt increase stage, abrupt decrease stage, and slow decrease stage. The elastic energy density is distributed asymmetrically in deep roadway surrounding rocks in coal mines. Under the action of structures of roadway surrounding rocks, energy evolution in these structures differs greatly during rockburst development under conditions of different coal pillar widths. This research provides an important theoretical basis for the support of rockburst-prone roadways during deep coal mining

Fatty acid metabolites of Dendrobium nobile were positively correlated with representative endophytic fungi at altitude

IntroductionAltitude, as a comprehensive ecological factor, regulates the growth and development of plants and microbial distribution. Dendrobium nobile (D. nobile) planted in habitats at different elevations in Chishui city, also shows metabolic differences and endophytes diversity. What is the triangular relationship between altitude, endophytes, and metabolites?MethodsIn this study, the diversity and species of endophytic fungi were tested by ITS sequencing and metabolic differences in plants were tested by UPLC–ESI–MS/MS. Elevation regulated the colonization of plant endophytic fungal species and fatty acid metabolites in D. nobile.ResultsThe results indicate that and high altitude was better for the accumulation of fatty acid metabolites. Therefore, the high-altitude characteristic endophytic floras were screened, and the correlation with fatty acid metabolites of plants was built. The colonization of T. rubrigenum, P. Incertae sedis unclassified, Phoma. cf. nebulosa JZG 2008 and Basidiomycota unclassified showed a significantly positive correlation with fatty acid metabolites, especially 18-carbon-chain fatty acids, such as (6Z,9Z,12Z)-octadeca-6,9,12-trienoic acid, 3,7,11,15-tetramethyl-12-oxohexadeca-2,4-dienoic acid and Octadec-9-en-12-ynoic acid. What is more fascinating is these fatty acids are the essential substrates of plant hormones.DiscussionConsequently, it was speculated that the D. nobile- colonizing endophytic fungi stimulated or upregulated the synthesis of fatty acid metabolites and even some plant hormones, thus affecting the metabolism and development of D. nobile