Gibbs-Preserving Maps outperform Thermal Operations in the quantum regime

In this brief note, we compare two frameworks for characterizing possible operations in quantum thermodynamics. One framework considers Thermal Operations---unitaries which conserve energy. The other framework considers all maps which preserve the Gibbs state at a given temperature. Thermal Operations preserve the Gibbs state; hence a natural question which arises is whether the two frameworks are equivalent. Classically, this is true---Gibbs-Preserving Maps are no more powerful than Thermal Operations. Here, we show that this no longer holds in the quantum regime: a Gibbs-Preserving Map can generate coherent superpositions of energy levels while Thermal Operations cannot. This gap has an impact on clarifying a mathematical framework for quantum thermodynamics.Comment: 4 pages, 1 figur

Quantum Coarse-Graining: An Information-Theoretic Approach to Thermodynamics

We investigate fundamental connections between thermodynamics and quantum information theory. First, we show that the operational framework of thermal operations is nonequivalent to the framework of Gibbs-preserving maps, and we comment on this gap. We then introduce a fully information-theoretic framework generalizing the above by making further abstraction of physical quantities such as energy. It is technically convenient to work with and reproduces known results for finite-size quantum thermodynamics. With our framework we may determine the minimal work cost of implementing any logical process. In the case of information processing on memory registers with a degenerate Hamiltonian, the answer is given by the max-entropy, a measure of information known from quantum information theory. In the general case, we obtain a new information measure, the "coherent relative entropy", which generalizes both the conditional entropy and the relative entropy. It satisfies a collection of properties which justifies its interpretation as an entropy measure and which connects it to known quantities. We then present how, from our framework, macroscopic thermodynamics emerges by typicality, after singling out an appropriate class of thermodynamic states possessing some suitable reversibility property. A natural thermodynamic potential emerges, dictating possible state transformations, and whose differential describes the physics of the system. The textbook thermodynamics of a gas is recovered as well as the form of the second law relating thermodynamic entropy and heat exchange. Finally, noting that quantum states are relative to the observer, we see that the procedure above gives rise to a natural form of coarse-graining in quantum mechanics: Each observer can consistently apply the formalism of quantum information according to their own fundamental unit of information.Comment: Ph. D. thesis, ETH Zurich (301 pages). Chaps. 1-3,9 are introductory and/or reviews; Chaps. 4,6 discuss previously published results (reproduces content from arXiv:1406.3618, New J. Phys. 2015 and from arXiv:1211.1037, Nat. Comm. 2015); Chaps. 5,7,8,10 are as of yet unpublished (introducing our information-theoretic framework, the coherent relative entropy, and quantum coarse-graining

Microcanonical and resource-theoretic derivations of the thermal state of a quantum system with noncommuting charges

The grand canonical ensemble lies at the core of quantum and classical statistical mechanics. A small system thermalizes to this ensemble while exchanging heat and particles with a bath. A quantum system may exchange quantities represented by operators that fail to commute. Whether such a system thermalizes and what form the thermal state has are questions about truly quantum thermodynamics. Here we investigate this thermal state from three perspectives. First, we introduce an approximate microcanonical ensemble. If this ensemble characterizes the system-and-bath composite, tracing out the bath yields the system's thermal state. This state is expected to be the equilibrium point, we argue, of typical dynamics. Finally, we define a resource-theory model for thermodynamic exchanges of noncommuting observables. Complete passivity---the inability to extract work from equilibrium states---implies the thermal state's form, too. Our work opens new avenues into equilibrium in the presence of quantum noncommutation.Comment: Published version. 7 pages (2 figures) + appendices. The leading author's surname is "Yunger Halpern.

Fundamental work cost of quantum processes

Information-theoretic approaches provide a promising avenue for extending the laws of thermodynamics to the nanoscale. Here, we provide a general fundamental lower limit, valid for systems with an arbitrary Hamiltonian and in contact with any thermodynamic bath, on the work cost for the implementation of any logical process. This limit is given by a new information measure—the coherent relative entropy—which accounts for the Gibbs weight of each microstate. The coherent relative entropy enjoys a collection of natural properties justifying its interpretation as a measure of information and can be understood as a generalization of a quantum relative entropy difference. As an application, we show that the standard first and second laws of thermodynamics emerge from our microscopic picture in the macroscopic limit. Finally, our results have an impact on understanding the role of the observer in thermodynamics: Our approach may be applied at any level of knowledge—for instance, at the microscopic, mesoscopic, or macroscopic scales—thus providing a formulation of thermodynamics that is inherently relative to the observer. We obtain a precise criterion for when the laws of thermodynamics can be applied, thus making a step forward in determining the exact extent of the universality of thermodynamics and enabling a systematic treatment of Maxwell-demon-like situations

Macroscopic thermodynamic reversibility in quantum many-body systems

The resource theory of thermal operations, an established model for small-scale thermodynamics, provides an extension of equilibrium thermodynamics to nonequilibrium situations. On a lattice of any dimension with any translation-invariant local Hamiltonian, we identify a large set of translation-invariant states that can be reversibly converted to and from the thermal state with thermal operations and a small amount of coherence. These are the spatially ergodic states, i.e., states that have sharp statistics for any translation-invariant observable, and mixtures of such states with the same thermodynamic potential. As an intermediate result, we show for a general state that if the gap between the min- and the max-relative entropies to the thermal state is small, then the state can be approximately reversibly converted to and from the thermal state with thermal operations and a small source of coherence. Our proof provides a quantum version of the Shannon-McMillan-Breiman theorem for the relative entropy and a quantum Stein’s lemma for ergodic states and local Gibbs states. Our results provide a strong link between the abstract resource theory of thermodynamics and more realistic physical systems as we achieve a robust and operational characterization of the emergence of a thermodynamic potential in translation-invariant lattice systems

Quantum thermodynamics with multiple conserved quantities

In this chapter we address the topic of quantum thermodynamics in the presence of additional observables beyond the energy of the system. In particular we discuss the special role that the generalized Gibbs ensemble plays in this theory, and derive this state from the perspectives of a micro-canonical ensemble, dynamical typicality and a resource-theory formulation. A notable obstacle occurs when some of the observables do not commute, and so it is impossible for the observables to simultaneously take on sharp microscopic values. We show how this can be circumvented, discuss information-theoretic aspects of the setting, and explain how thermodynamic costs can be traded between the different observables. Finally, we discuss open problems and future directions for the topic.Comment: 18 pages, 3 figures; Chapter for the book "Thermodynamics in the Quantum Regime - Recent Progress and Outlook", eds. F. Binder, L. A. Correa, C. Gogolin, J. Anders and G. Adess

Smooth entropy in axiomatic thermodynamics

Thermodynamics can be formulated in either of two approaches, the phenomenological approach, which refers to the macroscopic properties of systems, and the statistical approach, which describes systems in terms of their microscopic constituents. We establish a connection between these two approaches by means of a new axiomatic framework that can take errors and imprecisions into account. This link extends to systems of arbitrary sizes including microscopic systems, for which the treatment of imprecisions is pertinent to any realistic situation. Based on this, we identify the quantities that characterise whether certain thermodynamic processes are possible with entropy measures from information theory. In the error-tolerant case, these entropies are so-called smooth min and max entropies. Our considerations further show that in an appropriate macroscopic limit there is a single entropy measure that characterises which state transformations are possible. In the case of many independent copies of a system (the so-called i.i.d. regime), the relevant quantity is the von Neumann entropy.Comment: 18 pages, 1 figure; book chapter in "Thermodynamics in the Quantum Regime - Recent Progress and Outlook", eds. F. Binder, L. A. Correa, C. Gogolin, J. Anders and G. Adesso; the chapter relies on results reported in MW's PhD thesis, arXiv:1807.0634

Fundamental work cost of quantum processes

Information-theoretic approaches provide a promising avenue for extending the laws of thermodynamics to the nanoscale. Here, we provide a general fundamental lower limit, valid for systems with an arbitrary Hamiltonian and in contact with any thermodynamic bath, on the work cost for the implementation of any logical process. This limit is given by a new information measure—the coherent relative entropy—which accounts for the Gibbs weight of each microstate. The coherent relative entropy enjoys a collection of natural properties justifying its interpretation as a measure of information and can be understood as a generalization of a quantum relative entropy difference. As an application, we show that the standard first and second laws of thermodynamics emerge from our microscopic picture in the macroscopic limit. Finally, our results have an impact on understanding the role of the observer in thermodynamics: Our approach may be applied at any level of knowledge—for instance, at the microscopic, mesoscopic, or macroscopic scales—thus providing a formulation of thermodynamics that is inherently relative to the observer. We obtain a precise criterion for when the laws of thermodynamics can be applied, thus making a step forward in determining the exact extent of the universality of thermodynamics and enabling a systematic treatment of Maxwell-demon-like situations