6 research outputs found
Physics case for an LHCb Upgrade II - Opportunities in flavour physics, and beyond, in the HL-LHC era
The LHCb Upgrade II will fully exploit the flavour-physics opportunities of the HL-LHC, and study additional physics topics that take advantage of the forward acceptance of the LHCb spectrometer. The LHCb Upgrade I will begin operation in 2020. Consolidation will occur, and modest enhancements of the Upgrade I detector will be installed, in Long Shutdown 3 of the LHC (2025) and these are discussed here. The main Upgrade II detector will be installed in long shutdown 4 of the LHC (2030) and will build on the strengths of the current LHCb experiment and the Upgrade I. It will operate at a luminosity up to 2Ă1034
cmâ2sâ1, ten times that of the Upgrade I detector. New detector components will improve the intrinsic performance of the experiment in certain key areas. An Expression Of Interest proposing Upgrade II was submitted in February 2017. The physics case for the Upgrade II is presented here in more depth. CP-violating phases will be measured with precisions unattainable at any other envisaged facility. The experiment will probe b â sl+lâand b â dl+lâ transitions in both muon and electron decays in modes not accessible at Upgrade I. Minimal flavour violation will be tested with a precision measurement of the ratio of B(B0 â ÎŒ+ÎŒâ)/B(Bs â ÎŒ+ÎŒâ). Probing charm CP violation at the 10â5 level may result in its long sought discovery. Major advances in hadron spectroscopy will be possible, which will be powerful probes of low energy QCD. Upgrade II potentially will have the highest sensitivity of all the LHC experiments on the Higgs to charm-quark couplings. Generically, the new physics mass scale probed, for fixed couplings, will almost double compared with the pre-HL-LHC era; this extended reach for flavour physics is similar to that which would be achieved by the HE-LHC proposal for the energy frontier
LHCb upgrade software and computing : technical design report
This document reports the Research and Development activities that are carried out in the software and computing domains in view of the upgrade of the LHCb experiment. The implementation of a full software trigger implies major changes in the core software framework, in the event data model, and in the reconstruction algorithms. The increase of the data volumes for both real and simulated datasets requires a corresponding scaling of the distributed computing infrastructure. An implementation plan in both domains is presented, together with a risk assessment analysis
Syntheses of Heteroleptic Amidinate Strontium Complexes Using a Superbulky Ligand
Strontium
complexes are presented with two different bulky amidinate
ligands (Am): <i>t</i>BuCÂ(N<i>-</i>DIPP)<sub>2</sub> (DIPP = 2,6-diisopropylphenyl), abbreviated here as <i>t</i>BuAm<sup>DIPP</sup>, and (<i>p</i>-tolyl)ÂCÂ(N-Ar<sup>âĄ</sup>)<sub>2</sub> (Ar<sup>âĄ</sup> = 2,6-Ph<sub>2</sub>CH-4-<i>i</i>Pr-phenyl) abbreviated here as <i>p</i>TolAm<sup>ArâĄ</sup>. The amidine <i>t</i>BuAm<sup>DIPP</sup>-H was deprotonated by SrÂ[NÂ(SiMe<sub>3</sub>)<sub>2</sub>]<sub>2</sub> in benzene at 60 °C. Although the product, <i>t</i>BuAm<sup>DIPP</sup>SrNÂ(SiMe<sub>3</sub>)<sub>2</sub>, could be characterized
by NMR, attempts to isolate it led to ligand scrambling via a Schlenk
equilibrium. Reaction of in situ prepared <i>t</i>BuAm<sup>DIPP</sup>SrNÂ(SiMe<sub>3</sub>)<sub>2</sub> with PhSiH<sub>3</sub> gave PhH<sub>2</sub>SiNÂ(SiMe<sub>3</sub>)<sub>2</sub> and presumably
the intermediate <i>t</i>BuAm<sup>DIPP</sup>SrH, but the
latter is not stable and the homoleptic complex (<i>t</i>BuAm<sup>DIPP</sup>)<sub>2</sub>Sr was isolated and structurally
characterized. Deprotonation of the bulkier amidine <i>p</i>TolAm<sup>ArâĄ</sup>-H with SrÂ[NÂ(SiMe<sub>3</sub>)<sub>2</sub>]<sub>2</sub> needed forcing conditions, inevitably giving rise to
deprotonation of the Ph<sub>2</sub>CH substituent as well. Reaction
of <i>p</i>TolAm<sup>ArâĄ</sup>-H with the less bulky
and less basic SrÂ[NÂ(SiHMe<sub>2</sub>)<sub>2</sub>]<sub>2</sub>, however,
gave the heteroleptic product <i>p</i>TolAm<sup>ArâĄ</sup>SrNÂ(SiHMe<sub>2</sub>)<sub>2</sub>, which has been structurally characterized.
The latter was also at 60 °C stable toward ligand scrambling.
Reaction with PhSiH<sub>3</sub> did give hydride exchange, but the
product <i>p</i>TolAm<sup>ArâĄ</sup>SrH decomposed
even at â30 °C. Instead, an amidinate complex with a deprotonated
Ph<sub>2</sub>CH substituent was isolated and structurally characterized
(<b>7</b>). The latter catalyzed the intramolecular alkene hydroamination
Reactions of [RuCl<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub>] with Nitron and with the âEnders Carbeneâ: Access to Ruthenium(III) NHC Complexes
The reactions of [RuCl<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub>] with the âEnders carbeneâ
1,3,4-triphenyl-1,2,4-triazol-5-ylidene
(<b>1</b>) and the âinstant carbeneâ Nitron (<b>2</b>) respectively afforded the Ru<sup>II</sup> chelates [RuClÂ(<b>3</b>)Â(PPh<sub>3</sub>)<sub>2</sub>] (<b>3</b> = 3,4-diphenyl-1-<i>o</i>-phenylene-1,2,4-triazol-5-ylidene) and [RuClÂ(<b>4</b>)Â(PPh<sub>3</sub>)<sub>2</sub>] (<b>4</b> = 4-phenyl-3-phenylamino-1-<i>o</i>-phenylene-1,2,4-triazol-5-ylidene) in a process involving
the ortho metalation of the 1-Ph group of the respective carbene ligand.
It proved possible to synthesize [RuClÂ(<b>3</b>)Â(PPh<sub>3</sub>)<sub>2</sub>] more conveniently in higher yield by using the stable
carbene precursor 5-methoxy-1,3,4-triphenyl-4,5-dihydro-1<i>H</i>-1,2,4-triazole (MeO-<b>1</b>-H) instead of the free carbene <b>1</b> in the presence of triethylamine to trap the HCl generated
by the ortho metalation. Aerobic oxidation of the Ru<sup>II</sup> chelates
in the presence of chloride ions furnished [RuCl<sub>2</sub>(<b>3</b>)Â(PPh<sub>3</sub>)<sub>2</sub>] and [RuCl<sub>2</sub>(<b>4</b>)Â(PPh<sub>3</sub>)<sub>2</sub>], which are rare examples
of Ru<sup>III</sup> NHC complexes. The crystal structures of all four
complexes were determined by single-crystal X-ray diffraction studies.
In addition, the crystal structure of the hydrochloride of Nitron
was also determined. In the Ru<sup>II</sup> chelates, the pentacoordinate
metal center is in a distorted-square-pyramidal environment with the
carbon atom of the ortho-metalated 1-Ph group occupying the apical
position. The coordination sphere of the Ru<sup>III</sup> chelates
is complemented by a second chlorido ligand, which is positioned <i>trans</i> to this carbon atom
Stabilization of Calcium Hydride Complexes by Fine Tuning of Amidinate Ligands
A range
of symmetric amidinate ligands RAm<sup>Ar</sup> (R is backbone
substituent, Ar is N substituent) have been investigated for their
ability to stabilize calcium hydride complexes of the type RAm<sup>Ar</sup>CaH. It was found that the precursors of the type RAm<sup>Ar</sup>CaNÂ(SiMe<sub>3</sub>)<sub>2</sub> are only stable toward
ligand exchange for Ar = DIPP (2,6-diisopropylphenyl). The size of
the backbone substituent R determines aggregation and solvation. The
following complexes could be obtained: [RAm<sup>DIPP</sup>CaNÂ(SiMe<sub>3</sub>)<sub>2</sub>]<sub>2</sub> (R = Me, <i>p</i>-Tol),
RAm<sup>DIPP</sup>CaNÂ(SiMe<sub>3</sub>)<sub>2</sub>·Et<sub>2</sub>O (R = Np, <i>t</i>Bu), AdAm<sup>DIPP</sup>CaNÂ(SiMe<sub>3</sub>)<sub>2</sub>·THF, and AdAm<sup>DIPP</sup>CaNÂ(SiMe<sub>3</sub>)<sub>2</sub>. Reaction of these heteroleptic calcium amide
complexes with PhSiH<sub>3</sub> gave only for larger backbone substituents
(R = <i>t</i>Bu, Ad) access to the dimeric calcium hydride
complexes (RAm<sup>Ar</sup>CaH)<sub>2</sub>. (N,aryl)-coordination
of the amidinate ligand seems crucial for the stability of these complexes,
and the aryl···Ca interaction is found to be strong
(17 kcal/mol). Addition of polar solvents led to a new type of trimeric
calcium hydride complex exemplified by the crystal structures of (<i>t</i>BuAm<sup>DIPP</sup>CaH)<sub>3</sub>·2Et<sub>2</sub>O and (AdAm<sup>DIPP</sup>CaH)<sub>3</sub>·2THF. The overall
conclusion of this work is that minor changes in sterics (<i>t</i>Bu vs Ad) or coordinated solvent (THF vs Et<sub>2</sub>O) can have large consequences for product formation and stability
Observation of decays and precision measurements of the masses
International audienceThe first observation of the decays B(s)0âJ/ÏppÂŻ is reported, using proton-proton collision data corresponding to an integrated luminosity of 5.2ââfb-1, collected with the LHCb detector. These decays are suppressed due to limited available phase space, as well as due to Okubo-Zweig-Iizuka or Cabibbo suppression. The measured branching fractions are B(B0âJ/ÏppÂŻ)=[4.51±0.40(stat)±0.44(syst)]Ă10-7, B(Bs0âJ/ÏppÂŻ)=[3.58±0.19(stat)±0.39(syst)]Ă10-6. For the Bs0 meson, the result is much higher than the expected value of O(10-9). The small available phase space in these decays also allows for the most precise single measurement of both the B0 mass as 5279.74±0.30(stat)±0.10(syst)ââMeV and the Bs0 mass as 5366.85±0.19(stat)±0.13(syst)ââMeV