Magnetization profile for impurities in graphene nanoribbons

The magnetic properties of graphene-related materials and in particular the spin-polarised edge states predicted for pristine graphene nanoribbons (GNRs) with certain edge geometries have received much attention recently due to a range of possible technological applications. However, the magnetic properties of pristine GNRs are not predicted to be particularly robust in the presence of edge disorder. In this work, we examine the magnetic properties of GNRs doped with transition-metal atoms using a combination of mean-field Hubbard and Density Functional Theory techniques. The effect of impurity location on the magnetic moment of such dopants in GNRs is investigated for the two principal GNR edge geometries - armchair and zigzag. Moment profiles are calculated across the width of the ribbon for both substitutional and adsorbed impurities and regular features are observed for zigzag-edged GNRs in particular. Unlike the case of edge-state induced magnetisation, the moments of magnetic impurities embedded in GNRs are found to be particularly stable in the presence of edge disorder. Our results suggest that the magnetic properties of transition-metal doped GNRs are far more robust than those with moments arising intrinsically due to edge geometry.Comment: submitte

Impurity segregation in graphene nanoribbons

The electronic properties of low-dimensional materials can be engineered by doping, but in the case of graphene nanoribbons (GNR) the proximity of two symmetry-breaking edges introduces an additional dependence on the location of an impurity across the width of the ribbon. This introduces energetically favorable locations for impurities, leading to a degree of spatial segregation in the impurity concentration. We develop a simple model to calculate the change in energy of a GNR system with an arbitrary impurity as that impurity is moved across the ribbon and validate its findings by comparison with ab initio calculations. Although our results agree with previous works predicting the dominance of edge disorder in GNR, we argue that the distribution of adsorbed impurities across a ribbon may be controllable by external factors, namely an applied electric field. We propose that this control over impurity segregation may allow manipulation and fine-tuning of the magnetic and transport properties of GNRs.Comment: 5 pages, 4 figures, submitte

Analytical results for long time behavior in anomalous diffusion

We investigate through a Generalized Langevin formalism the phenomenon of anomalous diffusion for asymptotic times, and we generalized the concept of the diffusion exponent. A method is proposed to obtain the diffusion coefficient analytically through the introduction of a time scaling factor $\lambda$. We obtain as well an exact expression for $\lambda$ for all kinds of diffusion. Moreover, we show that $\lambda$ is a universal parameter determined by the diffusion exponent. The results are then compared with numerical calculations and very good agreement is observed. The method is general and may be applied to many types of stochastic problem

Thermal inactivation of Byssochlamys nivea in pineapple nectar combined with preliminary high pressure treatments

Byssochlamys nivea is a thermal resistant filamentous fungi and potential micotoxin producer. Recent studies have verified the presence of ascospores of such microorganism in samples of pineapple nectars. Although the majority of filamentous fungi have limited heat resistance and are easily destroyed by heat, Byssochlamys nivea ascospores have shown high thermal resistance. The aim of this work was to evaluate the application of linear and Weibull models on thermal inactivation (70, 80 and 90ºC) of Byssochlamys nivea ascospores in pineapple nectar after pretreatment with high pressure (550MPa or 650MPa during 15min). Following the treatments, survival curves were built up for each processing temperature and adjusted for both models. It was observed that survival curves at 90°C after high pressure pretreatment at 550 MPa/15 min did not fit well to linear and Weibull models. For all the other treatments, the Weibull model presented a better fit. At 90ºC without pressure treatment, the Weibull model also showed a better adjustment, having a larger R2 and a smaller RMSE. Regarding the process effectiveness, a 5-log reduction (t5), as recommended for pasteurization, was only achieved for Byssochlamys nivea ascospores presented in pineapple nectar at 90ºC/10.7 min with previous high pressure treatment of 650 MPa for 15 min. Considering the high intensity and energy demanding process with possibly product damage, other preventive and alternative treatments are being investigated

Avaliação da intensidade da queima-das-folhas em cultivares de coqueiro.

Anais do 1º Simpósio da Rede de Recursos Genéticos Vegetais do Nordeste (I RGVNE), Cruz das Almas, nov. 2013

Is it really possible to grow isotropic on-lattice diffusion-limited aggregates?

In a recent paper (Bogoyavlenskiy V A 2002 \JPA \textbf{35} 2533), an algorithm aiming to generate isotropic clusters of the on-lattice diffusion-limited aggregation (DLA) model was proposed. The procedure consists of aggregation probabilities proportional to the squared number of occupied sites ($k^2$). In the present work, we analyzed this algorithm using the noise reduced version of the DLA model and large scale simulations. In the noiseless limit, instead of isotropic patterns, a $45^\circ$ ($30^\circ$) rotation in the anisotropy directions of the clusters grown on square (triangular) lattices was observed. A generalized algorithm, in which the aggregation probability is proportional to $k^\nu$, was proposed. The exponent $\nu$ has a nonuniversal critical value $\nu_c$, for which the patterns generated in the noiseless limit exhibit the original (axial) anisotropy for $\nu<\nu_c$ and the rotated one (diagonal) for $\nu>\nu_c$. The values $\nu_c = 1.395\pm0.005$ and $\nu_c = 0.82\pm 0.01$ were found for square and triangular lattices, respectively. Moreover, large scale simulations show that there are a nontrivial relation between noise reduction and anisotropy direction. The case $\nu=2$ (\bogo's rule) is an example where the patterns exhibit the axial anisotropy for small and the diagonal one for large noise reduction.Comment: 12 pages, 8 figure

Light scattering by a medium with a spatially modulated optical conductivity: the case of graphene

We describe light scattering from a graphene sheet having a modulated optical conductivity. We show that such modulation enables the excitation of surface plasmon-polaritons by an electromagnetic wave impinging at normal incidence. The resulting surface plasmon-polaritons are responsible for a substantial increase of electromagnetic radiation absorption by the graphene sheet. The origin of the modulation can be due either to a periodic strain field or to adatoms (or absorbed molecules) with a modulated adsorption profile.Comment: http://iopscience.iop.org/0953-8984/24/24/24530

AN ATTEMPT TO LINK THE BRAZILIAN HEIGHT SYSTEM TO A WORLD HEIGHT SYSTEM

This paper deals with the geopotential approach to investigate the present BrazilianHeight System (BHS). Geopotential numbers are derived from Global PositioningSystem (GPS) satellite surveying and disturbing potential on selected benchmarks.A model for the disturbing potential can be obtained by an existing set of sphericalharmonic coefficients such as the Earth Gravity Model 2008 (EGM08). Theapproach provides absolute evaluation of local normal geopotential numbers (akaspheropotential numbers) related to a so-called World Height System (WHS). Totest the validity of the proposed methodology, a numerical experiment was carriedout related to a test region in Southern Brazil. The accuracy of the derivedgeopotential numbers was tested versus local normal geopotential numbers based on262 GPS/leveling points. The root mean square error (RMSE) value for metricoffset of BHS derived from geopotential numbers and the disturbing potentialmodeling in the test area was estimated to be near 0.224 meters in the absolute view.Therefore, since these spheropotential numbers are referred to a local datum, theseresults of comparisons may be an indicator of the mean bias of local network due tothe effect of local Sea Surface Topography (SSTop) and possible offset between theunknown reference for the BHS and the quasigeoid model in the region

Exponential behavior of the interlayer exchange coupling across non-magnetic metallic superlattices

It is shown that the coupling between magnetic layers separated by non-magnetic metallic superlattices can decay exponentially as a function of the spacer thickness $N$, as opposed to the usual $N^{-2}$ decay. This effect is due to the lack of constructive contributions to the coupling from extended states across the spacer. The exponential behavior is obtained by properly choosing the distinct metals and the superlattice unit cell composition.Comment: To appear in Phys. Rev.