Angular dependence of core hole screening in LiCoO2: A DFT+U calculation of the oxygen and cobalt K-edge x-ray absorption spectra

Angular dependent core-hole screening effects have been found in the cobalt K-edge x-ray absorption spectrum of LiCoO2, using high-resolution data and parameter-free GGA+U calculations. The Co 1s core-hole on the absorber causes strong local attraction. The core-hole screening on the nearest neighbours cobalt induces a 2 eV shift in the density of states with respect to the on-site 1s-3d transitions, as detected in the Co K pre-edge spectrum. Our DFT+U calculations reveal that the off-site screening is different in the out-of-plane direction, where a 3 eV shift is visible in both calculations and experiment. The detailed analysis of the inclusion of the core-hole potential and the Hubbard parameter U shows that the core-hole is essential for the off-site screening, while U improves the description of the angular dependent screening effects. In the case of oxygen K-edge, both the core-hole potential and the Hubbard parameter improve the relative positions of the spectral features

Covariant statistical mechanics and the stress-energy tensor

After recapitulating the covariant formalism of equilibrium statistical mechanics in special relativity and extending it to the case of a non-vanishing spin tensor, we show that the relativistic stress-energy tensor at thermodynamical equilibrium can be obtained from a functional derivative of the partition function with respect to the inverse temperature four-vector \beta. For usual thermodynamical equilibrium, the stress-energy tensor turns out to be the derivative of the relativistic thermodynamic potential current with respect to the four-vector \beta, i.e. T^{\mu \nu} = - \partial \Phi^\mu/\partial \beta_\nu. This formula establishes a relation between stress-energy tensor and entropy current at equilibrium possibly extendable to non-equilibrium hydrodynamics.Comment: 4 pages. Final version accepted for publication in Phys. Rev. Let

Poster: Resource Allocation with Conflict Resolution for Vehicular Sidelink Broadcast Communications

In this paper we present a graph-based resource allocation scheme for sidelink broadcast V2V communications. Harnessing available information on geographical position of vehicles and spectrum resources utilization, eNodeBs are capable of allotting the same set of sidelink resources to different vehicles distributed among several communications clusters. Within a communications cluster, it is crucial to prevent time-domain allocation conflicts since vehicles cannot transmit and receive simultaneously, i.e., they must transmit in orthogonal time resources. In this research, we present a solution based on a bipartite graph, where vehicles and spectrum resources are represented by vertices whereas the edges represent the achievable rate in each resource based on the SINR that each vehicle perceives. The aforementioned time orthogonality constraint can be approached by aggregating conflicting vertices into macro-vertices which, in addition, reduces the search complexity. We show mathematically and through simulations that the proposed approach yields an optimal solution. In addition, we provide simulations showing that the proposed method outperforms other competing approaches, specially in scenarios with high vehicular density.Comment: arXiv admin note: substantial text overlap with arXiv:1805.0655

The impact of industrial sites on residential property values

Industrial sites cause several negative externalities, such as traffic noise disturbance, congestion, and obstruction of view. In order to quantify the negative effects stemming from industrial sites, we estimate – using a hedonic pricing model – the impact of distance to industrial sites on residential property values. We use data on houses sold in the Randstad region and the province of Noord-Brabant (both located in the Netherlands) in the year 2005, together with data on characteristics of a substantial number of industrial sites in the same regions and period. The results reveal that the distance to an industrial site has a statistically significant negative effect on the value of residential properties. However, the effect is largely localized within a relatively short distance from the nearest industrial site. Furthermore, we obtain statistical evidence for substantial localized price differentials, which vary according to the size of an industrial site

Theory of Resonant Inelastic X-ray Scattering by Collective Magnetic Excitations

I present a tractable theory for the Resonant Inelastic X-ray Scattering (RIXS) spectral function of magnons. The low-energy transition operator is written as a product of local spin operators times fundamental x-ray absorption spectra. This leads to simple selection rules for the magnetic cross section. The scattering cross section linear (quadratic) in spin operators is proportional to the magnetic circular (linear) dichroic absorption. RIXS is a novel tool to measure magnetic quasi particles (magnons) and the incoherent spectral weight, as well as multiple magnons up to very high energy losses, in small samples, thin films and multilayers, complementary to Neutron scattering

Network-Assisted Resource Allocation with Quality and Conflict Constraints for V2V Communications

The 3rd Generation Partnership Project (3GPP) has recently established in Rel. 14 a network-assisted resource allocation scheme for vehicular broadcast communications. Such novel paradigm is known as vehicle--to--vehicle (V2V) \textit{mode-3} and consists in eNodeBs engaging only in the distribution of sidelink subchannels among vehicles in coverage. Thereupon, without further intervention of the former, vehicles will broadcast their respective signals directly to their counterparts. Because the allotment of subchannels takes place intermittently to reduce signaling, it must primarily be conflict-free in order not to jeopardize the reception of signals. We have identified four pivotal types of allocation requirements that must be guaranteed: one quality of service (QoS) requirement and three conflict conditions which must be precluded in order to preserve reception reliability. The underlying problem is formulated as a maximization of the system sum-capacity with four types of constraints that must be enforced. In addition, we propose a three-stage suboptimal approach that is cast as multiple independent knapsack problems (MIKPs). We compare the two approaches through simulations and show that the latter formulation can attain acceptable performance at lesser complexity