A Simple, Quick, and Precise Procedure for the Determination of Water in Organic Solvents

A procedure for the UV/VIS-spectroscopic determination of water by the use of a solvatochromic pyridiniumphenolate betaine is given. The water content of organic solvents is calculated by a two parameter equation from λmax of the dye. A typical, detection limit is of the order of 1 mg in 1 ml solvent for routine spectrometers. The parameters for the determination of water are given for a number of commonly used solvents

The existence of time

Of those gauge theories of gravity known to be equivalent to general relativity, only the biconformal gauging introduces new structures - the quotient of the conformal group of any pseudo-Euclidean space by its Weyl subgroup always has natural symplectic and metric structures. Using this metric and symplectic form, we show that there exist canonically conjugate, orthogonal, metric submanifolds if and only if the original gauged space is Euclidean or signature 0. In the Euclidean cases, the resultant configuration space must be Lorentzian. Therefore, in this context, time may be viewed as a derived property of general relativity.Comment: 21 pages (Reduced to clarify and focus on central argument; some calculations condensed; typos corrected

The effect of bedrest on various parameters of physiological function. part xiv- effect of bedrest on plasma levels and urinary excretion of 17-hydroxycorticosteroids

Bed rest effect on plasma levels and urinary excretion of hydroxycorticosteroid

Stress-driven instability in growing multilayer films

We investigate the stress-driven morphological instability of epitaxially growing multilayer films, which are coherent and dislocation-free. We construct a direct elastic analysis, from which we determine the elastic state of the system recursively in terms of that of the old states of the buried layers. In turn, we use the result for the elastic state to derive the morphological evolution equation of surface profile to first order of perturbations, with the solution explicitly expressed by the growth conditions and material parameters of all the deposited layers. We apply these results to two kinds of multilayer structures. One is the alternating tensile/compressive multilayer structure, for which we determine the effective stability properties, including the effect of varying surface mobility in different layers, its interplay with the global misfit of the multilayer film, and the influence of asymmetric structure of compressive and tensile layers on the system stability. The nature of the asymmetry properties found in stability diagrams is in agreement with experimental observations. The other multilayer structure that we study is one composed of stacked strained/spacer layers. We also calculate the kinetic critical thickness for the onset of morphological instability and obtain its reduction and saturation as number of deposited layers increases, which is consistent with recent experimental results. Compared to the single-layer film growth, the behavior of kinetic critical thickness shows deviations for upper strained layers.Comment: 27 pages, 11 figures; Phys. Rev. B, in pres

Epitaxial growth in dislocation-free strained alloy films: Morphological and compositional instabilities

The mechanisms of stability or instability in the strained alloy film growth are of intense current interest to both theorists and experimentalists. We consider dislocation-free, coherent, growing alloy films which could exhibit a morphological instability without nucleation. We investigate such strained films by developing a nonequilibrium, continuum model and by performing a linear stability analysis. The couplings of film-substrate misfit strain, compositional stress, deposition rate, and growth temperature determine the stability of film morphology as well as the surface spinodal decomposition. We consider some realistic factors of epitaxial growth, in particular the composition dependence of elastic moduli and the coupling between top surface and underlying bulk of the film. The interplay of these factors leads to new stability results. In addition to the stability diagrams both above and below the coherent spinodal temperature, we also calculate the kinetic critical thickness for the onset of instability as well as its scaling behavior with respect to misfit strain and deposition rate. We apply our results to some real growth systems and discuss the implications related to some recent experimental observations.Comment: 26 pages, 13 eps figure

The USNO/NRL Green Bank interferometer program

Application of the connected-element radio interferometer of the National Radio Astronomy Observation in Green Bank, West Virginia to the determination of improved source coordinates, astronomical constants, and variations in Earth rotation parameters is discussed. It is concluded that because of the brevity and discontinuity of the data so far no reliable conclusions regarding the accuracy of the data can be drawn

Explosive Percolation in the Human Protein Homology Network

We study the explosive character of the percolation transition in a real-world network. We show that the emergence of a spanning cluster in the Human Protein Homology Network (H-PHN) exhibits similar features to an Achlioptas-type process and is markedly different from regular random percolation. The underlying mechanism of this transition can be described by slow-growing clusters that remain isolated until the later stages of the process, when the addition of a small number of links leads to the rapid interconnection of these modules into a giant cluster. Our results indicate that the evolutionary-based process that shapes the topology of the H-PHN through duplication-divergence events may occur in sudden steps, similarly to what is seen in first-order phase transitions.Comment: 13 pages, 6 figure

System-level Noise Performance of Coherent Imaging Systems

We provide an in-depth analysis of noise considerations in coherent imaging, accounting for speckle and scintillation in addition to “conventional” image noise. Specifically, we formulate closed-form expressions for total effective noise in the presence of speckle only, scintillation only, and speckle combined with scintillation. We find analytically that photon shot noise is uncorrelated with both speckle and weak-to-moderate scintillation, despite their shared dependence on the mean signal. Furthermore, unmitigated speckle and scintillation noise tends to dominate coherent-imaging performance due to a squared mean-signal dependence. Strong coupling occurs between speckle and scintillation when both are present, and we characterize this behavior by fitting a scale factor capable of generating variances in closed form. We verify each of these claims through a series of wave-optics simulations, and we see strong agreement in general between numerical results and theoretical predictions. Our findings allow us to confidently gauge signal-to-noise ratio (SNR) expectations when active illumination produces coherent noise

Impact of the Manchester Glaucoma Enhanced Referral Scheme on NHS costs

Objectives: Glaucoma filtering schemes such as the Manchester Glaucoma Enhanced Referral Scheme (GERS) aim to reduce the number of false positive cases referred to Hospital Eye Services. Such schemes can also have wider system benefits, as they may reduce waiting times for other patients. However, previous studies of the cost consequences and wider system benefits of glaucoma filtering schemes are inconclusive. We investigate the cost consequences of the Manchester GERS. Design: Observational study. Methods: A cost analysis from the perspective of the National Health Service (NHS) was conducted using audit data from the Manchester GERS. Results: 2405 patients passed through the Manchester GERS from April 2013 to November 2016. 53.3% were not referred on to Manchester Royal Eye Hospital (MREH). Assuming an average of 2.3 outpatient visits to MREH were avoided for each filtered patient, the scheme saved the NHS approximately £2.76 per patient passing through the scheme. Conclusion: Our results indicate that glaucoma filtering schemes have the potential to reduce false positive referrals and costs to the NHS

Small-Scale Magnetic Fields are Critical to Shaping Solar Gamma-Ray Emission

The Sun is a bright gamma-ray source due to hadronic cosmic-ray interactions with solar gas. While it is known that incoming cosmic rays must generally first be reflected by solar magnetic fields to produce outgoing gamma rays, theoretical models have yet to reproduce the observed spectra. We introduce a simplified model of the solar magnetic fields that captures the main elements relevant to gamma-ray production. These are a flux tube, representing the network elements, and a flux sheet, representing the intergranule sheets. Both the tube and sheet have a horizontal size of order $100~{\rm km}$ and serve as sites where cosmic rays are reflected and gamma rays are produced. Despite having no tuning to match gamma-ray data, our model produces a gamma-ray spectrum that reasonably matches both the hard spectrum seen by Fermi-LAT data at $\text{1--200}~{\rm GeV}$ and the considerably softer spectrum seen by HAWC at near $10^3~{\rm GeV}$. We show that lower-energy ($\lesssim 10~{\rm GeV}$) gamma rays are primarily produced in the network elements and higher-energy ($\gtrsim {\rm few} \times 10~{\rm GeV}$) gamma rays in the intergranule sheets. Notably, the spectrum softening observed by HAWC results from the limited effectiveness of capturing and reflecting $\sim 10^4~{\rm GeV}$ cosmic rays by the finite-sized intergranule sheets. Our study is important for understanding cosmic-ray transport in the solar atmosphere and will lead to insights about small-scale magnetic fields in the quiet photosphere.Comment: 22 pages, 12 figure