114 research outputs found
Simple model for 1/f noise
We present a simple stochastic mechanism which generates pulse trains
exhibiting a power law distribution of the pulse intervals and a
power spectrum over several decades at low frequencies with close to
one. The essential ingredient of our model is a fluctuating threshold which
performs a Brownian motion. Whenever an increasing potential hits the
threshold, is reset to the origin and a pulse is emitted. We show that
if increases linearly in time, the pulse intervals can be approximated
by a random walk with multiplicative noise. Our model agrees with recent
experiments in neurobiology and explains the high interpulse interval
variability and the occurrence of noise observed in cortical
neurons and earthquake data.Comment: 4 pages, 4 figure
Interface to high-performance periodic coupled-cluster theory calculations with atom-centered, localized basis functions
Coupled cluster (CC) theory is often considered the gold standard of quantum-chemistry. For solids, however, the available software is scarce. We present CC-aims, which can interface ab initio codes with localized atomic orbitals and the CC for solids (CC4S) code by the group of A. Gr\"uneis. CC4S features a continuously growing selection of wave function-based methods including perturbation and CC theory. The CC-aims interface was developed for the FHI-aims code (https://fhi-aims.org) but is implemented such that other codes may use it as a starting point for corresponding interfaces. As CC4S offers treatment of both molecular and periodic systems, the CC-aims interface is a valuable tool, where DFT is either too inaccurate or too unreliable, in theoretical chemistry and materials science alike
Phonon surface mapping of graphite: disentangling quasi--degenerate phonon dispersions
The two-dimensional mapping of the phonon dispersions around the point of
graphite by inelastic x-ray scattering is provided. The present work resolves
the longstanding issue related to the correct assignment of transverse and
longitudinal phonon branches at . We observe an almost degeneracy of the
three TO, LA and LO derived phonon branches and a strong phonon trigonal
warping. Correlation effects renormalize the Kohn anomaly of the TO mode, which
exhibits a trigonal warping effect opposite to that of the electronic band
structure. We determined the electron--phonon coupling constant to be
166 in excellent agreement to calculations. These results
are fundamental for understanding angle-resolved photoemission,
double--resonance Raman and transport measurements of graphene based systems
The effect of sublattice symmetry breaking on the electronic properties of a doped graphene
Motivated by a number of recent experimental studies, we have carried out the
microscopic calculation of the quasiparticle self-energy and spectral function
in a doped graphene when a symmetry breaking of the sublattices is occurred.
Our systematic study is based on the many-body GW approach that is
established on the random phase approximation and on graphene's massive Dirac
equation continuum model. We report extensive calculations of both the real and
imaginary parts of the quasiparticle self-energy in the presence of a gap
opening. We also present results for spectral function, renormalized Fermi
velocity and band gap renormalization of massive Dirac Fermions over a broad
range of electron densities. We further show that the mass generating in
graphene washes out the plasmaron peak in spectral weight.Comment: 22 Pages, 10 Figure
Assessment of correlation energies based on the random-phase approximation
The random-phase approximation to the ground state correlation energy (RPA)
in combination with exact exchange (EX) has brought Kohn-Sham (KS) density
functional theory one step closer towards a universal, "general purpose first
principles method". In an effort to systematically assess the influence of
several correlation energy contributions beyond RPA, this work presents
dissociation energies of small molecules and solids, activation energies for
hydrogen transfer and non-hydrogen transfer reactions, as well as reaction
energies for a number of common test sets. We benchmark EX+RPA and several
flavors of energy functionals going beyond it: second-order screened exchange
(SOSEX), single excitation (SE) corrections, renormalized single excitation
(rSE) corrections, as well as their combinations. Both the single excitation
correction as well as the SOSEX contribution to the correlation energy
significantly improve upon the notorious tendency of EX+RPA to underbind.
Surprisingly, activation energies obtained using EX+RPA based on a KS reference
alone are remarkably accurate. RPA+SOSEX+rSE provides an equal level of
accuracy for reaction as well as activation energies and overall gives the most
balanced performance, which makes it applicable to a wide range of systems and
chemical reactions.Comment: 14 pages, 5 figures, full articl
Pairing symmetry of superconducting graphene
The possibility of intrinsic superconductivity in alkali-coated graphene
monolayers has been recently suggested theoretically. Here, we derive the
possible pairing symmetries of a carbon honeycomb lattice and discuss their
phase diagram. We also evaluate the superconducting local density of states
(LDOS) around an isolated impurity. This is directly related to scanning
tunneling microscopy experiments, and may evidence the occurrence of
unconventional superconductivity in graphene.Comment: Eur. Phys. J. B, to appea
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Tunneling current modulation in atomically precise graphene nanoribbon heterojunctions
Lateral heterojunctions of atomically precise graphene nanoribbons (GNRs) hold promise for applications in nanotechnology, yet their charge transport and most of the spectroscopic properties have not been investigated. Here, we synthesize a monolayer of multiple aligned heterojunctions consisting of quasi-metallic and wide-bandgap GNRs, and report characterization by scanning tunneling microscopy, angle-resolved photoemission, Raman spectroscopy, and charge transport. Comprehensive transport measurements as a function of bias and gate voltages, channel length, and temperature reveal that charge transport is dictated by tunneling through the potential barriers formed by wide-bandgap GNR segments. The current-voltage characteristics are in agreement with calculations of tunneling conductance through asymmetric barriers. We fabricate a GNR heterojunctions based sensor and demonstrate greatly improved sensitivity to adsorbates compared to graphene based sensors. This is achieved via modulation of the GNR heterojunction tunneling barriers by adsorbates
Magneto-optical Selection Rules in Bilayer Bernal Graphene
The low-frequency magneto-optical properties of bilayer Bernal graphene are
studied by the tight-binding model with four most important interlayer
interactions taken into account. Since the main features of the wave functions
are well depicted, the Landau levels can be divided into two groups based on
the characteristics of the wave functions. These Landau levels lead to four
categories of absorption peaks in the optical absorption spectra. Such
absorption peaks own complex optical selection rules and these rules can be
reasonably explained by the characteristics of the wave functions. In addition,
twin-peak structures, regular frequency-dependent absorption rates and complex
field-dependent frequencies are also obtained in this work. The main features
of the absorption peaks are very different from those in monolayer graphene and
have their origin in the interlayer interactions
Random-phase approximation and its applications in computational chemistry and materials science
The random-phase approximation (RPA) as an approach for computing the
electronic correlation energy is reviewed. After a brief account of its basic
concept and historical development, the paper is devoted to the theoretical
formulations of RPA, and its applications to realistic systems. With several
illustrating applications, we discuss the implications of RPA for computational
chemistry and materials science. The computational cost of RPA is also
addressed which is critical for its widespread use in future applications. In
addition, current correction schemes going beyond RPA and directions of further
development will be discussed.Comment: 25 pages, 11 figures, published online in J. Mater. Sci. (2012
Quantum magneto-optics of graphite family
The optical conductivity of graphene, bilayer graphene, and graphite in
quantizing magnetic fields is studied. Both dynamical conductivities,
longitudinal and Hall's, are analytically evaluated. The conductivity peaks are
explained in terms of electron transitions. We have shown that trigonal warping
can be considered within the perturbation theory for strong magnetic fields
larger than 1 T and in the semiclassical approach for weak fields when the
Fermi energy is much larger than the cyclotron frequency. The main optical
transitions obey the selection rule with \Deltan = 1 for the Landau number n,
however the \Deltan = 2 transitions due to the trigonal warping are also
possible. The Faraday/Kerr rotation and light transmission/reflection in the
quantizing magnetic fields are calculated. Parameters of the
Slonczewski-Weiss-McClure model are used in the fit taking into account the
previous dHvA measurements and correcting some of them for the case of strong
magnetic fields.Comment: 28 pages, 12 figures. arXiv admin note: text overlap with
arXiv:1106.340
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