Collision of Polymers in a Vacuum

In a number of experimental situations, single polymer molecules can be suspended in a vacuum. Here collisions between such molecules are considered. The limit of high collision velocity is investigated numerically for a variety of conditions. The distribution of contact times, scattering angles, and final velocities are analyzed. In this limit, self avoiding chains are found to become highly stretched as they collide with each other, and have a distribution of scattering times that depends on the scattering angle. The velocity of the molecules after the collisions is similar to predictions of a model assuming thermal equilibration of molecules during the collision. The most important difference is a significant subset of molecules that inelastically scatter but do not substantially change direction.Comment: 7 pages, 6 figure

Phase diagram for the asymmetric nuclear matter in the multifragmentation model

We assume that, in equilibrium, nuclear matter at reduced density and moderate finite temperature, breaks up into many fragments. A strong support to this assumption is provided by date accumulated from intermediate energy heavy ion collisions. The break-up of hot and expanded nuclear matter according to rules of equilibrium statistical mechanics is the multifragmentation model. The model gives a first order phase transition. This is studied in detail here. Phase-equilibrium lines for different degrees of asymmetry are computed.Comment: 22 pages, 10 figure

A Model for Phase Transition based on Statistical Disassembly of Nuclei at Intermediate Energies

Consider a model of particles (nucleons) which has a two-body interaction which leads to bound composites with saturation properties. These properties are : all composites have the same density and the ground state energies of composites with k nucleons are given by -kW+\sigma k^{2/3} where W and \sigma are positive constants. W represents a volume term and \sigma a surface tension term. These values are taken from nuclear physics. We show that in the large N limit where N is the number of particles such an assembly in a large enclosure at finite temperature shows properties of liquid-gas phase transition. We do not use the two-body interaction but the gross properties of the composites only. We show that (a) the p-\rho isotherms show a region where pressure does not change as $\rho$ changes just as in Maxwell construction of a Van der Waals gas, (b) in this region the chemical potential does not change and (c) the model obeys the celebrated Clausius-Clapeyron relations. A scaling law for the yields of composites emerges. For a finite number of particles N (upto some thousands) the problem can be easily solved on a computer. This allows us to study finite particle number effects which modify phase transition effects. The model is calculationally simple. Monte-Carlo simulations are not needed.Comment: RevTex file, 21 pages, 5 figure

Quasi-Particle Degrees of Freedom versus the Perfect Fluid as Descriptors of the Quark-Gluon Plasma

The hot nuclear matter created at the Relativistic Heavy Ion Collider (RHIC) has been characterized by near-perfect fluid behavior. We demonstrate that this stands in contradiction to the identification of QCD quasi-particles with the thermodynamic degrees of freedom in the early (fluid) stage of heavy ion collisions. The empirical observation of constituent quark ``$n_q$'' scaling of elliptic flow is juxtaposed with the lack of such scaling behavior in hydrodynamic fluid calculations followed by Cooper-Frye freeze-out to hadrons. A ``quasi-particle transport'' time stage after viscous effects break down the hydrodynamic fluid stage, but prior to hadronization, is proposed to reconcile these apparent contradictions. However, without a detailed understanding of the transitions between these stages, the ``$n_q$'' scaling is not a necessary consequence of this prescription. Also, if the duration of this stage is too short, it may not support well defined quasi-particles. By comparing and contrasting the coalescence of quarks into hadrons with the similar process of producing light nuclei from nucleons, it is shown that the observation of ``$n_{q}$'' scaling in the final state does not necessarily imply that the constituent degrees of freedom were the relevant ones in the initial state.Comment: 9 pages, 7 figures, Updated text and figure

A Paradox of State-Dependent Diffusion and How to Resolve It

Consider a particle diffusing in a confined volume which is divided into two equal regions. In one region the diffusion coefficient is twice the value of the diffusion coefficient in the other region. Will the particle spend equal proportions of time in the two regions in the long term? Statistical mechanics would suggest yes, since the number of accessible states in each region is presumably the same. However, another line of reasoning suggests that the particle should spend less time in the region with faster diffusion, since it will exit that region more quickly. We demonstrate with a simple microscopic model system that both predictions are consistent with the information given. Thus, specifying the diffusion rate as a function of position is not enough to characterize the behaviour of a system, even assuming the absence of external forces. We propose an alternative framework for modelling diffusive dynamics in which both the diffusion rate and equilibrium probability density for the position of the particle are specified by the modeller. We introduce a numerical method for simulating dynamics in our framework that samples from the equilibrium probability density exactly and is suitable for discontinuous diffusion coefficients.Comment: 21 pages, 6 figures. Second round of revisions. This is the version that will appear in Proc Roy So

Sub-milliKelvin spatial thermometry of a single Doppler cooled ion in a Paul trap

We report on observations of thermal motion of a single, Doppler-cooled ion along the axis of a linear radio-frequency quadrupole trap. We show that for a harmonic potential the thermal occupation of energy levels leads to Gaussian distribution of the ion's axial position. The dependence of the spatial thermal spread on the trap potential is used for precise calibration of our imaging system's point spread function and sub-milliKelvin thermometry. We employ this technique to investigate the laser detuning dependence of the Doppler temperature.Comment: 5 pages, 4 figure

Dynamic roughening and fluctuations of dipolar chains

Nonmagnetic particles in a carrier ferrofluid acquire an effective dipolar moment when placed in an external magnetic field. This fact leads them to form chains that will roughen due to Brownian motion when the magnetic field is decreased. We study this process through experiments, theory and simulations, three methods that agree on the scaling behavior over 5 orders of magnitude. The RMS width goes initially as $t^{1/2}$, then as $t^{1/4}$ before it saturates. We show how these results complement existing results on polymer chains, and how the chain dynamics may be described by a recent non-Markovian formulation of anomalous diffusion.Comment: 4 pages, 3 figures, submitted to Phys. Rev. Let

Relaxation paths for single modes of vibrations in isolated molecules

A numerical simulation of vibrational excitation of molecules was devised, and used to excite computational models of common molecules into a prescribed, pure, normal vibration mode in the ground electronic state, with varying, controlable energy content. The redistribution of this energy (either non-chaotic or irreversible IVR) within the isolated, free molecule is then followed in time with a view to determining the coupling strength between modes. This work was triggered by the need to predict the general characters of the infrared spectra to be expected from molecules in interstellar space, after being excited by photon absorption or reaction with a radical. It is found that IVR from a pure normal mode is very "restricted" indeed at energy contents of one mode quantum or so. However, as this is increased, or when the excitation is localized, our approach allows us to isolate, describe and quantify a number of interesting phenomena, known to chemists and in non-linear mechanics, but difficult to demonstrate experimentally: frequency dragging, mode locking or quenching or, still, instability near a potential surface crossing, the first step to generalized chaos as the energy content per mode is increased.Comment: 25 pages, 15 figures; accepted by J. Atom. Phys.

Fcc-bcc transition for Yukawa interactions determined by applied strain deformation

Calculations of the work required to transform between bcc and fcc phases yield a high-precision bcc-fcc transition line for monodisperse point Yukawa (screened-Couloumb) systems. Our results agree qualitatively but not quantitatively with previously published simulations and phenomenological criteria for the bcc-fcc transition. In particular, the bcc-fcc-fluid triple point lies at a higher inverse screening length than previously reported.Comment: RevTex4, 9 pages, 6 figures. Discussion of phase coexistence extended, a few other minor clarifications added, referencing improved. Accepted for publication by Physical Review

Nonzero orbital angular momentum superfluidity in ultracold Fermi gases

We analyze the evolution of superfluidity for nonzero orbital angular momentum channels from the Bardeen-Cooper-Schrieffer (BCS) to the Bose-Einstein condensation (BEC) limit in three dimensions. First, we analyze the low energy scattering properties of finite range interactions for all possible angular momentum channels. Second, we discuss ground state ($T = 0$) superfluid properties including the order parameter, chemical potential, quasiparticle excitation spectrum, momentum distribution, atomic compressibility, ground state energy and low energy collective excitations. We show that a quantum phase transition occurs for nonzero angular momentum pairing, unlike the s-wave case where the BCS to BEC evolution is just a crossover. Third, we present a gaussian fluctuation theory near the critical temperature ($T = T_{\rm c}$), and we analyze the number of bound, scattering and unbound fermions as well as the chemical potential. Finally, we derive the time-dependent Ginzburg-Landau functional near $T_{\rm c}$, and compare the Ginzburg-Landau coherence length with the zero temperature average Cooper pair size.Comment: 28 pages and 24 figure