Transport of Water and Gases through EVA/PVC blend films – Permeation and DSC investigations.

The transport of water vapor and gases (oxygen and carbon dioxide) through poly(ethylene-co-vinyl acetate) (EVA) films of different VA content, poly(vinylchloride) (PVC) and EVA/PVC blend films, was analysed from permeation measurements. A plasticization effect of water on the material was observed for EVA films with more than 19% wt. of VA content and for the EVA/PVC blends, while for gas permeation practically all the experimental curves are characterized by a constant diffusion coefficient, whatever the VA content of the copolymer used. The increase in water absorption with the VA content leads to a steady increase in the water permeability of the EVA copolymers. By mixing the glassy PVC polymer with the EVA copolymer (in a rubbery state) reduced water and gas permeability is observed, resulting mainly from the decrease of the diffusivity due to the low segment mobility of the dense PVC material able to create hydrogen bonds between the hydrogen atoms and the Cl-substituted carbon of PVC with VA carbonyls. Compared to EVA copolymers, the EVA/PVC blends with equivalent VA contents are better in terms of selectivity

Real time noise and wavelength correlations in octave-spanning supercontinuum generation

We use dispersive Fourier transformation to measure shot-to-shot spectral instabilities in femtosecond supercontinuum generation. We study both the onset phase of supercontinuum generation with distinct dispersive wave generation, as well as a highly-unstable supercontinuum regime spanning an octave in bandwidth. Wavelength correlation maps allow interactions between separated spectral components to be identified, even when such interactions are not apparent in shot-to-shot or average measurements. Experimental results are interpreted using numerical simulations. Our results show the clear advantages of dispersive Fourier transformation for studying spectral noise during supercontinuum generation.Comment: 14 pages, 5 figure

SmartEx: a case study on user profiling and adaptation in exhibition booths

An investigation into user profiling and adaptation with exhibition booth as a case study is reported. First a review of the field of exhibitions and trade fairs and a summary introduction to adaptation and profiling are given. We then introduce three criteria for the evaluation of exhibition booth: effectiveness, efficiency and affect. Effectiveness is related the amount of information collected, efficiency is a measurement of the time taken to collect the information, and affect is the perception of the experience and the mood booth visitors have during and after their visit. We have selected these criteria to assess adaptive and profiled exhibition booths, we call smart exhibition (SmartEx). The assessment is performed with an experiment with three test conditions (non-profiled/non adaptive, profiled/non-adaptive and profiled adaptive presentations). Results of the experiment are presented along discussion. While there is significant improvements of effectiveness and efficiency between the two-first test conditions, the improvement is not significant for the last test condition, for reasons explained. As for the affect, the results show that it has an under-estimated importance in people minds and that it should be addressed more carefully

The Dababiya corehole, Upper Nile Valley, Egypt : preliminary results

Author Posting. © Austrian Geological Society, 2012. This article is posted here by permission of Austrian Geological Society for personal use, not for redistribution. The definitive version was published in Austrian Journal of Earth Sciences 105, no. 1 (2012): 161-168.The Dababiya corehole was drilled in the Dababiya Quarry (Upper Nile Valley, Egypt), adjacent to the GSSP for the Paleocene/ Eocene boundary, to a total depth of 140 m and bottomed in the lower Maastrichtian Globotruncana aegyptiaca Zone of the Dakhla Shale Formation. Preliminary integrated studies on calcareous plankton (foraminifera, nannoplankton), benthic foraminifera, dinoflagellates, ammonites, geochemistry, clay mineralogy and geophysical logging indicate that: 1) The K/P boundary lies between 80.4 and 80.2 m, the Danian/Selandian boundary between ~ 41 and 43 m, the Selandian/Thanetian boundary at ~ 30 m (within the mid-part of the Tarawan Chalk) and the Paleocene/Eocene boundary at 11.75 m (base [planktonic foraminifera] Zone E1 and [calcareous nannoplankton] Zone NP9b); 2) the Dababiya Quarry Member (=Paleocene/Eocene Thermal Maximum interval) extends from 11.75 to 9.5 m, which is ~1 m less than in the adjacent GSSP outcrop.; 3) the Late Cretaceous (Maastrichtian) depositional environment was nearshore, tropical-sub tropical and nutrient rich; the latest Maastrichtian somewhat more restricted (coastal); and the early Danian cooler, low(er) salinity with increasing warmth and depth of water (i.e., more open water); 4) the Paleocene is further characterized by outer shelf (~ 200 m), warm water environments as supported by foraminifera P/B ratios > 85% (~79-28 m), whereas benthic foraminifera dominate (>70%) from ~27-12 m (Tarawan Chalk and Hanadi Member) due, perhaps, in part to increased dissolution (as observed in nearby outcrop samples over this interval); 5) during the PETM, enhanced hydrodynamic conditions are inferred to have occurred on the sea-floor with increased river discharge (in agreement with sedimentologic evidence), itself a likely cause for very high enhanced biological productivity on the epicontinental shelf of Egypt; 6) correlation of in situ measured geophysical logs of Natural Gamma Ray (GR), Single-Point Resistance (PR), Self-Potential (SP), magnetic susceptibility (MS), and Resistivity, and Short Normal (SN) and Long Normal (LN) showed correspondence to the lithologic units. The Dababiya Quarry Member, in particular, is characterized by very high Gamma Ray and Resistivity Short Normal values.The Dababiya corehole was made possible by the financial support of the National Geographic Society