1,668 research outputs found
Raman scattering investigation across the magnetic and MI transition in rare earth nickelate RNiO3 (R = Sm, Nd) thin films
We report a temperature-dependent Raman scattering investigation of thin film
rare earth nickelates SmNiO3, NdNiO3 and Sm0.60Nd0.40NiO3, which present a
metal-to-insulator (MI) transition at TMI and an antiferromagnetic-paramagnetic
Neel transition at TN. Our results provide evidence that all investigated
samples present a structural phase transition at TMI but the Raman signature
across TMI is significantly different for NdNiO3 (TMI = TN) compared to SmNiO3
and Sm0.60Nd0.40NiO3 (TMI =/ TN). It is namely observed that the
paramagnetic-insulator phase (TN < T < TMI) in SmNiO3 and Sm0.60Nd0.40NiO3 is
characterized by a pronounced softening of one particular phonon band around
420 cm-1. This signature is unusual and points to an important and continuous
change in the distortion of NiO6 octahedra (thus the Ni-O bonding) which
stabilizes upon cooling at the magnetic transition. The observed behaviour
might well be a general feature for all rare earth nickelates with TMI =/ TN
and illustrates intriguing coupling mechanism in the TMI > T > TN regime.Comment: Revised & published versio
Random local strain effects in homovalent-substituted relaxor ferroelectrics: a first-principles study of BaTi0.74Zr0.26O3
We present first-principles supercell calculations on BaTi0.74Zr0.26O3, a
prototype material for relaxors with a homovalent substitution. From a
statistical analysis of relaxed structures, we give evidence for four types of
Ti-atom polar displacements: along the , , or
directions of the cubic unit cell, or almost cancelled. The type of a Ti
displacement is entirely determined by the Ti/Zr distribution in the adjacent
unit cells. The underlying mechanism involves local strain effects that ensue
from the difference in size between the Ti4+ and Zr4+ cations. These results
shed light on the structural mechanisms that lead to disordered Ti
displacements in BaTi(1-x)Zr(x)O3 relaxors, and probably in other BaTiO3-based
relaxors with homovalent substitution.Comment: 5 pages, 4 figure
Strain analysis of multiferroic BiFeO3-CoFe2O4 nanostructures by Raman scattering
We report a Raman scattering investigation of columnar BiFeO3-CoFe2O4
(BFO-CFO) epitaxial thin film nanostructures, where BFO pillars are embedded in
a CFO matrix. The feasibility of a strain analysis is illustrated through an
investigation of two nanostructures with different BFO-CFO ratios. We show that
the CFO matrix presents the same strain state in both nanostructures, while the
strain state of the BFO pillars depends on the BFO/CFO ratio with an increasing
tensile strain along the out-of-plane direction with decreasing BFO content.
Our results demonstrate that Raman scattering allows monitoring strain states
in complex 3D multiferroic pillar/matrix composites.Comment: revised version submitted to Appl. Phys. Let
SmNiO3/NdNiO3 thin film multilayers
Rare earth nickelates RENiO3 which attract interest due to their sharp
metal-insulator phase transition, are instable in bulk form due to the
necessity of an important oxygen pressure to stabilize Ni in its 3+ state of
oxidation. Here, we report the stabilization of rare earth nickelates in
[(SmNiO3)t/(NdNiO3)t]n thin film multilayers, t being the thickness of layers
alternated n times. Both bilayers and multilayers have been deposited by
Metal-Organic Chemical Vapour Deposition. The multilayer structure and the
presence of the metastable phases SmNiO3 and NdNiO3 are evidenced from by X-ray
and Raman scattering. Electric measurements of a bilayer structure further
support the structural quality of the embedded rare earth nickelate layers.Comment: Appl. Phys. Lett. (2011), accepte
Colossal Spin-Phonon Anomalies and the Ferroelectric Phase Transition in the Model Multiferroic Bifeo3
We report a temperature-dependent Raman and neutron scattering investigation
of the multiferroic material bismuth ferrite BiFeO3 (BFO).Comment: submitted to PRL (July 2005
Magentically-Induced Lattice Distortions and Ferroelectricity in Magnetoelectric GdMnO3
In this work we investigate the magnetic field dependence of Ag octahedra
rotation (tilt) and B2g symmetric stretching modes frequency at different
temperatures. Our field-dependent Raman investigation at 10K is interpreted by
an ionic displacive nature of the magnetically induced ferroelectric phase
transition. The frequency change of the Ag tilt is in agreement with the
stabilization of the Mn-Gd spin arrangement, yielding the necessary conditions
for the onset of ferroelectricity on the basis of the inverse
Dzyaloshinskii-Moriya interaction. The role of the Jahn-Teller cooperative
interaction is also evidenced by the change of the B2g mode frequency at the
ferroelectric phase transition. This frequency change allows estimating the
shift of the oxygen position at the ferroelectric phase transition and the
corresponding spontaneous polarization of 480 {\mu}C/m2, which agrees with
earlier reported values in single crystals. Our study also confirms the
existence of a large magnetic hysteresis at the lowest temperatures, which is a
manifestation of magnetrostiction.Comment: 5 pages, 3 figure
An algorithmic approach to the existence of ideal objects in commutative algebra
The existence of ideal objects, such as maximal ideals in nonzero rings,
plays a crucial role in commutative algebra. These are typically justified
using Zorn's lemma, and thus pose a challenge from a computational point of
view. Giving a constructive meaning to ideal objects is a problem which dates
back to Hilbert's program, and today is still a central theme in the area of
dynamical algebra, which focuses on the elimination of ideal objects via
syntactic methods. In this paper, we take an alternative approach based on
Kreisel's no counterexample interpretation and sequential algorithms. We first
give a computational interpretation to an abstract maximality principle in the
countable setting via an intuitive, state based algorithm. We then carry out a
concrete case study, in which we give an algorithmic account of the result that
in any commutative ring, the intersection of all prime ideals is contained in
its nilradical
Existential witness extraction in classical realizability and via a negative translation
We show how to extract existential witnesses from classical proofs using
Krivine's classical realizability---where classical proofs are interpreted as
lambda-terms with the call/cc control operator. We first recall the basic
framework of classical realizability (in classical second-order arithmetic) and
show how to extend it with primitive numerals for faster computations. Then we
show how to perform witness extraction in this framework, by discussing several
techniques depending on the shape of the existential formula. In particular, we
show that in the Sigma01-case, Krivine's witness extraction method reduces to
Friedman's through a well-suited negative translation to intuitionistic
second-order arithmetic. Finally we discuss the advantages of using call/cc
rather than a negative translation, especially from the point of view of an
implementation.Comment: 52 pages. Accepted in Logical Methods for Computer Science (LMCS),
201
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