415 research outputs found
Optical-phonon resonances with saddle-point excitons in twisted-bilayer graphene
Twisted-bilayer graphene (tBLG) exhibits van Hove singularities in the
density of states that can be tuned by changing the twisting angle . A
-defined tBLG has been produced and characterized with optical
reflectivity and resonance Raman scattering. The -engineered optical
response is shown to be consistent with persistent saddle-point excitons.
Separate resonances with Stokes and anti-Stokes Raman scattering components can
be achieved due to the sharpness of the two-dimensional saddle-point excitons,
similar to what has been previously observed for one-dimensional carbon
nanotubes. The excitation power dependence for the Stokes and anti-Stokes
emissions indicate that the two processes are correlated and that they share
the same phonon.Comment: 5 pages, 6 figure
Interaction between concentric Tubes in DWCNTs
A detailed investigation of the Raman response of the inner tube radial
breathing modes (RBMs) in double-wall carbon nanotubes is reported. It revealed
that the number of observed RBMs is two to three times larger than the number
of possible tubes in the studied frequency range. This unexpected increase in
Raman lines is attributed to a splitting of the inner tube response. It is
shown to originate from the possibility that one type of inner tube may form in
different types of outer tubes and the fact that the inner tube RBM frequency
depends on the diameter of the enclosing tube. Finally, a comparison of the
inner tube RBMs and the RBMs of tubes in bundles gave clear evidence that the
interaction in a bundle is stronger than the interaction between inner and
outer tubes.Comment: 6 pages, 7 figures, submitted to Eur. Phys. J.
How does the substrate affect the Raman and excited state spectra of a carbon nanotube?
We study the optical properties of a single, semiconducting single-walled
carbon nanotube (CNT) that is partially suspended across a trench and partially
supported by a SiO2-substrate. By tuning the laser excitation energy across the
E33 excitonic resonance of the suspended CNT segment, the scattering
intensities of the principal Raman transitions, the radial breathing mode
(RBM), the G-mode and the D-mode show strong resonance enhancement of up to
three orders of magnitude. In the supported part of the CNT, despite a loss of
Raman scattering intensity of up to two orders of magnitude, we recover the E33
excitonic resonance suffering a substrate-induced red shift of 50 meV. The peak
intensity ratio between G-band and D-band is highly sensitive to the presence
of the substrate and varies by one order of magnitude, demonstrating the much
higher defect density in the supported CNT segments. By comparing the E33
resonance spectra measured by Raman excitation spectroscopy and
photoluminescence (PL) excitation spectroscopy in the suspended CNT segment, we
observe that the peak energy in the PL excitation spectrum is red-shifted by 40
meV. This shift is associated with the energy difference between the localized
exciton dominating the PL excitation spectrum and the free exciton giving rise
to the Raman excitation spectrum. High-resolution Raman spectra reveal
substrate-induced symmetry breaking, as evidenced by the appearance of
additional peaks in the strongly broadened Raman G band. Laser-induced line
shifts of RBM and G band measured on the suspended CNT segment are both linear
as a function of the laser excitation power. Stokes/anti-Stokes measurements,
however, reveal an increase of the G phonon population while the RBM phonon
population is rather independent of the laser excitation power.Comment: Revised manuscript, 20 pages, 8 figure
Thermodynamics of the incommensurate state in Rb_2WO_4: on the Lifshitz point in A`A``BX_4 compounds
We consider the evolution of the phase transition from the parent hexagonal
phase to the orthorhombic phase that occurs in several
compounds of family as a function of the hcp lattice parameter
. For compounds of type with larger than the threshold
value 1.26 the direct first-order transition is characterized
by the large entropy jump . For compounds , ,
with this transition occurs via an intermediate
incommensurate phase. DSC measurements were performed in
to characterize the thermodynamics of the transitions. It
was found that both transitions are again of the first order with entropy jumps
0.3Rln2c/a ~ 1.26A'A''BX_{4}BX_{4}$ tetrahedra
orientation as a possible source of the transitions discontinuity.Comment: 13 pages,1 Postscript figure. Submitted as Brief Report to Phys. Rev.
B, this paper reports a new work in Theory and Experiment, directed to
Structural Phase Transition
Raman Spectroscopy Study of Rotated Double-Layer Graphene: Misorientation-Angle Dependence of Electronic Structure
We present a systematic Raman study of unconventionally stacked double-layer graphene, and find that the spectrum strongly depends on the relative rotation angle between layers. Rotation-dependent trends in the position, width and intensity of graphene 2D and G peaks are experimentally established and accounted for theoretically. Our theoretical analysis reveals that changes in electronic band structure due to the interlayer interaction, such as rotational-angle dependent Van Hove singularities, are responsible for the observed spectral features. Our combined experimental and theoretical study provides a deeper understanding of the electronic band structure of rotated double-layer graphene, and leads to a practical way to identify and analyze rotation angles of misoriented double-layer graphene.open1048
Factors associated with thrombocytopenia in severe leptospirosis (Weil's disease)
OBJECTIVE: This study was conducted to investigate factors associated with thrombocytopenia in a large cohort of patients with leptospirosis in an endemic area. METHODS: This retrospective study included 374 consecutive patients with leptospirosis who were admitted to tertiary hospitals in Fortaleza, Brazil. All patients had a diagnosis of severe leptospirosis (Weil's disease). Acute kidney injury was defined according to the RIFLE criteria. Thrombocytopenia was defined as a platelet coun
Phonon-assisted exciton relaxation dynamics for a (6,5)-enriched DNA-wrapped single-walled carbon nanotube sample
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