116 research outputs found
New magnetic phase in metallic V_{2-y}O_3 close to the metal insulator transition
We have observed two spin density wave (SDW) phases in hole doped metallic
V_{2-y}O_3, one evolves from the other as a function of doping, pressure or
temperature. They differ in their response to an external magnetic field, which
can also induce a transition between them. The phase boundary between these two
states in the temperature-, doping-, and pressure-dependent phase diagram has
been determined by magnetization and magnetotransport measurements. One phase
exists at high doping level and has already been described in the literature.
The second phase is found in a small parameter range close to the boundary to
the antiferromagnetic insulating phase (AFI). The quantum phase transitions
between these states as a function of pressure and doping and the respective
metamagnetic behavior observed in these phases are discussed in the light of
structurally induced changes of the band structure.Comment: REVTeX, 8 pages, 12 EPS figures, submitted to PR
Trimer Formation and Metal-Insulator Transition in Orbital Degenerate Systems on a Triangular Lattice
As a prototypical self-organization in the system with orbital degeneracy, we
theoretically investigate trimer formation on a triangular lattice, as observed
in LiVO2. From the analysis of an effective spin-orbital coupled model in the
strong correlation limit, we show that the previously-proposed orbital-ordered
trimer state is not the lowest-energy state for a finite Hund's-rule coupling.
Instead, exploring the ground state in a wide range of parameters for a
multiorbital Hubbard model, we find an instability toward a different
orbital-ordered trimer state in the intermediately correlated regime in the
presence of trigonal crystal field. The trimer phase appears in the competing
region among a paramagnetic metal, band insulator, and Mott insulator. The
underlying mechanism is nesting instability of the Fermi surface by a
synergetic effect of Coulomb interactions and trigonal-field splitting. The
results are compared with experiments in triangularlattice compounds, LiVX2
(X=O, S, Se) and NaVO2.Comment: 4 pages, 4 figures, accepted for publication in J. Phys. Soc. Jp
Electronic structure of Co_xTiSe_2 and Cr_xTiSe_2
The results of investigations of intercalated compounds Cr_xTiSe_2 and
Co_xTiSe_2 by X-ray photoelectron spectroscopy (XPS) and X-ray emission
spectroscopy (XES) are presented. The data obtained are compared with
theoretical results of spin-polarized band structure calculations. A good
agreement between theoretical and experimental data for the electronic
structure of the investigated materials has been observed. The interplay
between the M3d--Ti3d hybridization (M=Cr, Co) and the magnetic moment at the M
site is discussed. A 0.9 eV large splitting of the core Cr2p{3/2} level was
observed, which reveals a strong exchange magnetic interaction of 3d-2p
electrons of Cr. In the case of a strong localization of the Cr3d electrons
(for x<0.25), the broadening of the CrL spectra into the region of the states
above the nominal Fermi level was observed and attributed to X-ray re-emission.
The measured kinetic properties are in good accordance with spectral
investigations and band calculation results.Comment: 14 pages, 11 figures, submitted to Phys.Rev.
Correlation effects in the ground state charge density of Mott-insulating NiO: a comparison of ab-initio calculations and high-energy electron diffraction measurements
Accurate high-energy electron diffraction measurements of structure factors
of NiO have been carried out to investigate how strong correlations in the Ni
3d shell affect electron charge density in the interior area of nickel ions and
whether the new ab-initio approaches to the electronic structure of strongly
correlated metal oxides are in accord with experimental observations. The
generalized gradient approximation (GGA) and the local spin density
approximation corrected by the Hubbard U term (LSDA+U) are found to provide the
closest match to experimental measurements. The comparison of calculated and
observed electron charge densities shows that correlations in the Ni 3d shell
suppress covalent bonding between the oxygen and nickel sublattices.Comment: 6 pages, LaTeX and 5 figures in the postscript forma
Ab initio calculation of resonant X-ray scattering in Manganites
We study the origin of the resonant x-ray signal in manganites and generalize
the resonant cross-section to the band structure framework. With {\it ab
initio} LSDA and LSDA+U calculations we determine the resonant x-ray spectrum
of LaMnO. The calculated spectrum and azimuthal angle dependence at the Mn
-edge reproduce the measured data without adjustable parameters. The
intensity of this signal is directly related to the orthorhombicity of the
lattice. We also predict a resonant x-ray signal at the La -edge, caused by
the tilting of the MnO octahedra. This shows that the resonant x-ray signal
in the hard x-ray regime can be understood in terms of the band structure of a
material and is sensitive to the fine details of crystal structure.Comment: 4 pages, 4 figures, accepted for publication in Phys. Rev.
Rationality in Differential Algebraic Geometry
Parametric Cartan theory of exterior differential systems, and explicit
cohomology of projective manifolds reveal united rationality features of
differential algebraic geometry.Comment: Abel Symposium 201
Finite temperature numerical renormalization group study of the Mott-transition
Wilson's numerical renormalization group (NRG) method for the calculation of
dynamic properties of impurity models is generalized to investigate the
effective impurity model of the dynamical mean field theory at finite
temperatures. We calculate the spectral function and self-energy for the
Hubbard model on a Bethe lattice with infinite coordination number directly on
the real frequency axis and investigate the phase diagram for the Mott-Hubbard
metal-insulator transition. While for T<T_c approx 0.02W (W: bandwidth) we find
hysteresis with first-order transitions both at U_c1 (defining the insulator to
metal transition) and at U_c2 (defining the metal to insulator transition), at
T>T_c there is a smooth crossover from metallic-like to insulating-like
solutions.Comment: 10 pages, 9 eps-figure
Electronic Structure of CoxTiSe2 and CrxTiSe2
The results of investigations of intercalated compounds CrxTiSe2 and CoxTiSe2 by x-ray photoelectron spectroscopy and x-ray emission spectroscopy are presented. The data obtained are compared with theoretical results of spin-polarized band-structure calculations. A good agreement between theoretical and experimental data for the electronic structure of the investigated materials has been observed. The interplay between the M 3d−Ti3d hybridization (M=Cr, Co) and the magnetic moment at the M site is discussed. A 0.9-eV large splitting of the core Cr2p3/2 level was observed, which reveals a strong exchange magnetic interaction of 3d−2p electrons of Cr. In the case of a strong localization of the Cr 3d electrons (for x<0.25), the broadening of the Cr L spectra into the region of the states above the nominal Fermi level was observed and attributed to x-ray reemission. The measured kinetic properties are in good accordance with spectral investigations and band calculation results. © 2001 The American Physical Society.This work was supported by the Russian Science Foundation for Fundamental Research (Projects No. 99-03-32503 and No. 00-15-96575), a NATO Linkage Grant (No. HTECH.LG 971222), and a DFG-RFFI Project. Financial support from the Deutsche Forschungsgemeinschaft is greatly acknowledged
Familial hypercholesterolemia and elevated lipoprotein(a) : double heritable risk and new therapeutic opportunities
Vuorio A, Watts GF, Schneider WJ, Tsimikas S, Kovanen PT (Mehilainen Airport Health Centre, Vantaa; University of Helsinki, Helsinki, Finland; University of Western Australia, Perth, Australia; Royal Perth Hospital, Perth, Australia; Medical University of Vienna, Vienna, Austria; University of California San Diego, La Jolla, CA, USA; Wihuri Research Institute, Helsinki, Finland). Familial hypercholesterolemia and elevated lipoprotein(a): double heritable risk and new therapeutic opportunities (Review). J Intern Med 2020; 287: 2-18. There is compelling evidence that the elevated plasma lipoprotein(a) [Lp(a)] levels increase the risk of atherosclerotic cardiovascular disease (ASCVD) in the general population. Like low-density lipoprotein (LDL) particles, Lp(a) particles contain cholesterol and promote atherosclerosis. In addition, Lp(a) particles contain strongly proinflammatory oxidized phospholipids and a unique apoprotein, apo(a), which promotes the growth of an arterial thrombus. At least one in 250 individuals worldwide suffer from the heterozygous form of familial hypercholesterolemia (HeFH), a condition in which LDL-cholesterol (LDL-C) is significantly elevated since birth. FH-causing mutations in the LDL receptor gene demonstrate a clear gene-dosage effect on Lp(a) plasma concentrations and elevated Lp(a) levels are present in 30-50% of patients with HeFH. The cumulative burden of two genetically determined pro-atherogenic lipoproteins, LDL and Lp(a), is a potent driver of ASCVD in HeFH patients. Statins are the cornerstone of treatment of HeFH, but they do not lower the plasma concentrations of Lp(a). Emerging therapies effectively lower Lp(a) by as much as 90% using RNA-based approaches that target the transcriptional product of the LPA gene. We are now approaching the dawn of an era, in which permanent and significant lowering of the high cholesterol burden of HeFH patients can be achieved. If outcome trials of novel Lp(a)-lowering therapies prove to be safe and cost-effective, they will provide additional risk reduction needed to effectively treat HeFH and potentially lower the CVD risk in these high-risk patients even more than currently achieved with LDL-C lowering alone.Peer reviewe
- …