1,175 research outputs found

    Fall-Off from Extrapolated Values of All Chemical Reactions at Very High Temperatures

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    Cooperative Jahn-Teller Distortion in PrO2

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    We report neutron diffraction data on single crystal PrO2 which reveal a cooperative Jahn-Teller distortion at TD = 120 +/- 2 K. Below this temperature an internal distortion of the oxygen sublattice causes the unit cell of the crystallographic structure to become doubled along one crystal axis. We discuss several possible models for this structure. The antiferromagnetic structure below TN = 13.5 K is found to consist of two components, one of which shares the same doubled unit cell as the distorted crystallographic structure. We also present measurements of the magnetic susceptibility, the specific heat capacity and the electrical conductivity of PrO2. The susceptibility data show an anomaly at a temperature close to TD. From the specific heat capacity data we deduce that the ground state is doubly degenerate, consistent with a distortion of the cubic local symmetry. We discuss possible mechanisms for this. The conductivity shows an activated behaviour with an activation energy Ea = 0.262 +/- 0.003 eV.Comment: 12 pages, 14 figures, 2 tables. Additional suggested structure in v

    On the equation of state of a dense columnar liquid crystal

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    An accurate description of a columnar liquid crystal of hard disks at high packing fractions is presented using an improved free-volume theory. It is shown that the orientational entropy of the disks in the one-dimensional fluid direction leads to a different high-density scaling pressure compared to the prediction from traditional cell theory. Excellent quantitative agreement is found with recent Monte-Carlo simulation results for various thermodynamic and structural properties of the columnar state.Comment: 4 pages, 2 figures, to appear in Phys. Rev. Let

    Raman and Infra-red properties and layer dependence of the phonon dispersions in multi-layered graphene

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    The symmetry group analysis is applied to classify the phonon modes of NN-stacked graphene layers (NSGL's) with AB- and AA-stacking, particularly their infra-red and Raman properties. The dispersions of various phonon modes are calculated in a multi-layer vibrational model, which is generalized from the lattice vibrational potentials of graphene to including the inter-layer interactions in NSGL's. The experimentally reported red shift phenomena in the layer number dependence of the intra-layer optical C-C stretching mode frequencies are interpreted. An interesting low frequency inter-layer optical mode is revealed to be Raman or Infra-red active in even or odd NSGL's respectively. Its frequency shift is sensitive to the layer number and saturated at about 10 layers.Comment: enlarged versio

    Perceived Benefits of Technology Enhanced Language Learning in Beginning Language Classes

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    This paper examines the perceptions of benefit of Technology EnhancedLanguage Learning (TELL) on students’ language learning, comfort &enjoyment, and increased confidence using technology at a large SouthernCalifornia University during one university term. Through a surveyadministered to 345 beginning language students, 11 tutors and 12instructors, and through selective interviews and classroom observations,several questions were examined: 1.) Perceived confidence, benefits, andcomfort/enjoyment with TELL for instructors, tutors, and students at thebeginning and end of the semester; 2.) Students’ perceived impact ofTELL between pre and post survey measures on second language skills,learning culture, student motivation to learn a language, and preparingstudents for class tests and quizzes; 3.) Whether or not target languageorthography, exposure to TELL, student gender, and instructors’ ortutors’ previous confidence in using TELL, impacted perception of benefitby students; 4.) Positive and negative aspects of incorporating a TELLcomponent in the language classroom for instructors and tutors. Theresults showed that incorporating TELL in a new, but limited, way in allbeginning level classes at one university was a positive experience formany participants, especially in the areas of comfort/enjoyment, andincreased confidence in using technology. However, unless tasks wereclearly tied to learning objectives, students did not recognize theirinstructional value
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