30 research outputs found
p-Type semiconducting properties in lithium-doped MgO single crystals
The phenomenally large enhancement in conductivity observed when Li-doped MgO
crystals are oxidized at elevated temperatures was investigated by dc and ac
electrical measurements in the temperature interval 250-673 K. The
concentration of ([Li]^{0}) centers (Li^{+} ions each with a trapped hole)
resulting from oxidation was monitored by optical absorption measurements.
Both dc and ac experiments provide consistent values for the bulk resistance.
The electricalconductivity of oxidized MgO:Li crystals increases linearly with
the concentration of ([Li]^{0}) centers. The conductivity is thermally
activated with an activation energy of (0.70 +/- 0.01) eV, which is independent
of the ([Li]^{0}) content. The \textit{standard semiconducting} mechanism
satisfactorily explains these results. Free holes are the main contribution to
band conduction as they are trapped at or released from the ([Li]^{0})-acceptor
centers.
In as-grown MgO:Li crystals, electrical current increases dramatically with
time due to the formation of ([Li]^{0}) centers. The activation energy values
between 1.3 and 0.7 eV are likely a combination of the activation energy for
the creation of ([Li]^{0}) centers and the activation energy of ionization of
these centers. Destruction of ([Li]^{0}) centers can be induced in oxidized
crystals by application of an electric field due to Joule heating up to
temperatures at which ([Li]^{0}) centers are not stable.Comment: LaTeX, 20 pages, 9 Encapsulated Postscript Format Figures, use the
version 4.0 of REVTEX 4 macro packag
History of Stepped Channels and Spillways: a Rediscovery of the 'Wheel'
Recently, spillways with a stepped profile have regained interest and favor among design engineers to pass flood waters over the dams. The stepped geometry enhances the energy dissipation above the spillway and reduces the size of a downstream stilling basin. In this paper, the author shows that the technique of stepped channels has been developed since Antiquity. Spillways and irrigation channels with stepped profiles were developed by several civilisations around the Mediterranean sea and in America. The main characteristics of the stepped spillways along the ages suggest a regular evolution rather than a revolution. Present stepped spillways are designed to pass similar discharges as two hundred years ago