Precise and accurate isotope fractionation factors (α17O, α18O and αD) for water and CaSO4·2H2O (gypsum)

Gypsum (CaSO4·2H2O) is a hydrated mineral containing crystallization water, also known as gypsum hydration water (GHW). We determined isotope fractionation factors (α17O, α18O and αD) between GHW and free water of the mother solution in the temperature range from 3 °C to 55 °C at different salinities and precipitation rates. The hydrogen isotope fractionation factor (αDgypsum-water) increases by 0.0001 units per °C between 3 °C and 55 °C and salinities <150 g/L of NaCl. The αDgypsum-water is 0.9812 ± 0.0007 at 20 °C, which is in good agreement with previous estimates of 0.981 ± 0.001 at the same temperature. The α18Ogypsum-water slightly decreases with temperature by 0.00001 per °C, which is not significant over much of the temperature range considered for paleoclimate applications. Between 3 °C and 55 °C, α18Ogypsum-water averages 1.0035 ± 0.0002. This value is more precise than that reported previously (e.g. 1.0041 ± 0.0004 at 25 °C) and lower than the commonly accepted value of 1.004. We found that NaCl concentrations below 150 g/L do not significantly affect α18Ogypsum-water, but αDgypsum-water increases linearly with NaCl concentrations even at relatively low salinities, suggesting a salt correction is necessary for gypsum formed from brines. Unlike oxygen isotopes, the αDgypsum-water is affected by kinetic effects that increase with gypsum precipitation rate. As expected, the relationship of the fractionation factors for 17O and 18O follows the theoretical mass-dependent fractionation on Earth (θ = 0.529 ± 0.001). We provide specific examples of the importance of using the revised fractionation factors when calculating the isotopic composition of the fluids

Generalizing the N=2 supersymmetric RG flow solution of IIB supergravity

We explicitly construct the supersymmetry transformations for the N=2 supersymmetric RG flow solution of chiral IIB supergravity. We show that the metric, dilaton/axion, five-index tensor and half of the three index tensor are determined algebraically in terms of the Killing spinor of the unbroken supersymmetry. The algebraic nature of the solution allows us to generalize this construction to a new class of N=2 supersymmetric solutions of IIB supergravity. Each solution in this class is algebraically determined by supersymmetry and is parametrized by a single function of two variables that satisfies a non-linear equation akin to the Laplace equation on the space transverse to the brane.Comment: 27 pages; harvmac; tex twic

A Class of N=1 Supersymmetric RG Flows from Five-dimensional N = 8 Supergravity

We consider the holographic dual of a general class of N=1* flows in which all three chiral multiplets have independent masses, and in which the corresponding Yang-Mills scalars can develop particular supersymmetry-preserving vevs. We also allow the gaugino to develop a vev. This leads to a six parameter subspace of the supergravity scalar action, and we show that this is a consistent truncation, and obtain a superpotential that governs the N=1* flows on this subspace. We analyse some of the structure of the superpotential, and check consistency with the asymptotic behaviour near the UV fixed point. We show that the dimensions of the six couplings obey a sum rule all along the N=1* flows. We also show how our superpotential describes part of the Coulomb branch of the non-trivial N=1 fixed point theory.Comment: 14 pages; harvmac. New version has only minor correction

What Shall We Call God? An Exploration of Metaphors Coded From Descriptions of God From A Large U.S. Undergraduate Sample

People use numerous metaphors to describe God. God is seen as a bearded man, light, and love. Based on metaphor theories, the metaphors people use to refer to God reflect how people think about God and could, in turn, reflect their worldview. However, little work has explored the common metaphors for God. This was the purpose of the current investigation. Four trained raters coded open-ended responses from predominantly Christian U.S. undergraduates (N = 2,923) describing God for the presence or absence of numerous metaphoric categories. We then assessed the frequency of each of the metaphor categories. We identified 16 metaphor categories that were present in more than 1% of the responses. The top categories were “GOD IS POWER,” “GOD IS HUMAN,” and “GOD IS MALE.” These findings were similar across religious affiliations. We attempted to support our coding analysis using top-down and bottom-up automated language analysis. Results from these analyses provided added confidence to our conclusions. We discuss the implications of our findings and the potential for future studies investigating important psychological and behavioral outcomes of using different metaphors for God

Continuous-variable quantum key distribution field-test with true local oscillator

Continuous-variable quantum key distribution (CV-QKD) using a true local (located at the receiver) oscillator (LO) has been proposed to remove any possibility of side-channel attacks associated with transmission of the LO as well as reduce the cross-pulse contamination. Here we report an implementation of true LO CV-QKD using "off-the-shelf" components and conduct QKD experiments using the fiber optical network at Oak Ridge National Laboratory. A phase reference and quantum signal are time multiplexed and then wavelength division multiplexed with the classical communications which "coexist" with each other on a single optical network fiber. This is the first demonstration of CV-QKD with a receiver-based true LO over a deployed fiber network, a crucial step for its application in real-world situations

Identifying Social Transformations and Crisis during the Pre-Monastic to Post-Viking era on Iona : New Insights from a Palynological and Palaeoentomological Perspective

Acknowledgements: Special acknowledgements go to Audrey Innes for her laboratory support, to Historic Environment Scotland and to the Leverhulme Trust who have helped fund this project and to the University of Glasgow who have helped support this work.Peer reviewedPostprin

Coupled measurements of δ18O and δD of hydration water and salinity of fluid inclusions in gypsum from the Messinian Yesares Member, Sorbas Basin (SE Spain)

Financial support was provided by Clare College Geological Research Fund to N.P. Evans. The research leading to these results has received funding from the European Research Council under the European Union's Seventh Framework Programme (FP/2007–2013)/ERC Grant Agreement n. 339694 (Water Isotopes of Hydrated Minerals) to D.A. Hodell.We studied one cycle (Cycle 6) of gypsum-marl deposition from the Messinian Yesares Member in Sorbas Basin, Spain. The objective was to reconstruct the changing environment of deposition and its relation to astronomically-forced climate change. The δ18O and δD of gypsum hydration water (CaSO4 • 2H2O) and salinity of fluid inclusions were measured in the same samples to test if they record the composition of the mother fluid from which gypsum was precipitated. Water isotopes are highly correlated with fluid inclusion salinity suggesting the hydration water has not exchanged after formation. The relatively low water isotope values and fluid inclusion salinities indicate a significant influence of meteoric water, whereas δ34S, δ18OSO4 and 87Sr/86Sr support a dominant marine origin for the gypsum deposits. The discrepancy between water and elemental isotope signatures can be reconciled if meteoric water dissolved previously deposited marine sulfates supplying calcium and sulfate ions to the basin which maintained gypsum saturation. This recycling process accounts for the marine δ34S, δ18OSO4 and 87Sr/86Sr signatures, whereas the low δ18O and δD values of gypsum hydration water and fluid inclusion salinities reflect the influence of freshwater. The cyclic deposition of gypsum and marl in the Yesares Member has previously been interpreted to reflect changing climate related to Earth's precession cycle. We demonstrate that the δ18O, δD and salinity of the parent brine increased from low values at the base of the cycle to a maximum in the massive gypsum palisade, and decreased again to lower values in the supercones at the top of the cycle. This pattern, together with changes in mineralogy (calcite-dolomite-gypsum), is consistent with a precession-driven change in climate with wettest conditions (summer insolation maxima) associated with the base of the calcium carbonate marls and driest conditions (summer insolation minima) during formation of the gypsum palisade.Publisher PDFPeer reviewe

Flowing with Eight Supersymmetries in M-Theory and F-theory

We consider holographic RG flow solutions with eight supersymmetries and study the geometry transverse to the brane. For both M2-branes and for D3-branes in F-theory this leads to an eight-manifold with only a four-form flux. In both settings there is a natural four-dimensional hyper-Kahler slice that appears on the Coulomb branch. In the IIB theory this hyper-Kahler manifold encodes the Seiberg-Witten coupling over the Coulomb branch of a U(1) probe theory. We focus primarily upon a new flow solution in M-theory. This solution is first obtained using gauged supergravity and then lifted to eleven dimensions. In this new solution, the brane probes have an Eguchi-Hanson moduli space with the M2-branes spread over the non-trivial 2-sphere. It is also shown that the new solution is valid for a class of orbifold theories. We discuss how the hyper-Kahler structure on the slice extends to some form of G-structure in the eight-manifold, and describe how this can be computed.Comment: 29 pages, 1 figure, harvma