Tracing the cosmological evolution of stars and cold gas with CMB spectral surveys

A full account of galaxy evolution in the context of LCDM cosmology requires measurements of the average star-formation rate (SFR) and cold gas abundance across cosmic time. Emission from the CO ladder traces cold gas, and [CII] fine structure emission at 158 um traces the SFR. Intensity mapping surveys the cumulative surface brightness of emitting lines as a function of redshift, rather than individual galaxies. CMB spectral distortion instruments are sensitive to both the mean and anisotropy of the intensity of redshifted CO and [CII] emission. Large-scale anisotropy is proportional to the product of the mean surface brightness and the line luminosity-weighted bias. The bias provides a connection between galaxy evolution and its cosmological context, and is a unique asset of intensity mapping. Cross-correlation with galaxy redshift surveys allows unambiguous measurements of redshifted line brightness despite residual continuum contamination and interlopers. Measurement of line brightness through cross-correlation also evades cosmic variance and suggests new observation strategies. Galactic foreground emission is $\sim 10^3$ times larger than the expected signals, and this places stringent requirements on instrument calibration and stability. Under a range of assumptions, a linear combination of bands cleans continuum contamination sufficiently that residuals produce a modest penalty over the instrumental noise. For PIXIE, the $2 \sigma$ sensitivity to CO and [CII] emission scales from $\sim 5 \times 10^{-2}$ kJy/sr at low redshift to ~2 kJy/sr by reionization.Comment: 11 pages, 9 figures, accepted in Ap

Ionizing radiation from hydrogen recombination strongly suppresses the lithium scattering signature in the CMB

It has been suggested that secondary CMB anisotropies generated by neutral lithium could open a new observational window into the universe around the redshift z~400, and permit a determination of the primordial lithium abundance. The effect is due to resonant scattering in the allowed Li i doublet (2s2S1/2-2p2P1/2,3/2), so its observability depends on the formation history of neutral lithium. Here we show that the ultraviolet photons produced during hydrogen recombination are sufficient to keep lithium in the Li ii ionization stage in the relevant redshift range and suppress the neutral fraction by ~3 orders of magnitude from previous calculations, making the lithium signature unobservable

Theoretical Framework of Exchange Coupled Tripartite Spin Systems with Magnetic Anisotropy and Predictions of Spin and Electronic Transport Properties for Their Use in Quantum Architectures

There has been significant interest in spin systems involving two or more coupled spins as a single logical qubit, particularly for scalable quantum computing architectures. Recent realizations include the so-called singlet-triplet qubits and coupled magnetic molecules. An important class of coupled-spin systems, the three-spin paradigm for spin greater than 1/2, has not yet been fully realized in scalable qubit architectures. In this thesis, I develop the theoretical framework to investigate a class of tripartite spin models for realistic systems. First, I model a spin 1/2 particle (e.g., an electron) and two spin 1 particles (in a dimer arrangement) coupled with an exchange interaction. I find that if the two spin particles possess zero-field magnetic anisotropy, there exists resonance conditions that enable read, manipulate, and write operations on the representative qubit using the electron. Next, I generalize this result for any spin S, and describe how the resonance conditions change based on the type of exchange coupling, magnetic anisotropy, and magnitude of applied magnetic fields. The rest of the thesis is dedicated to utilizing the tools described in the framework to uncover the properties of potential scalable quantum architectures. To guide the correspondence between experiment and model Hamiltonians of effective tripartite spin systems connected to leads, I investigate the transport properties of a three-terminal quantum dot coupled to a magnetic molecular dimer using the generalized master equation. I then model both steady state and transient phenomena using equilibrium and non-equilibrium Green\u27s functions (NEGF), and comment on the applicability of a newly-developed NEGF-derived quantum master equation. Finally, I characterize two examples of novel quantum systems: the spin qubit candidate h-BN VB- and the thin film FeBipy spin-crossover molecule

Intensity mapping from the sky: synergizing the joint potential of [OIII] and [CII] surveys at reionization

We forecast the ability of future-generation experiments to detect the fine-structure lines of the carbon and oxygen ions, [CII] and [OIII] in intensity mapping (IM) from the Epoch of Reionization ($z \sim 6-8$). Combining the latest empirically derived constraints relating the luminosity of the [OIII] line to the ambient star-formation rate, and using them in conjunction with previously derived estimates for the abundance of [CII] in haloes, we predict the expected auto-correlation IM signal to be observed using new experiments based on the Fred Young Submillimetre Telescope (FYST) and the balloon-borne facility, Experiment for Cryogenic Large-Aperture Intensity Mapping (EXCLAIM) over $z \sim 5.3 - 7$. We describe how improvements to both the ground-based and balloon-based surveys in the future will enable a cross-correlation signal to be detected at $\sim$ 10-30 $\sigma$ over $z \sim 5.3 - 7$. Finally, we propose a space-based mission targeting the [OIII] 88 and 52 $\mu$m lines along with the [CII] 158 $\mu$m line, configured to enhance the signal-to-noise ratio of cross-correlation measurements. We find that such a configuration can achieve a high-significance detection (hundreds of $\sigma$) in both auto- and cross-correlation modes.Comment: 11 pages, 7 figures, 2 tables; accepted for publication in MNRA

Epitaxial Electrodeposition of Hole Transport CuSCN Nanorods on Au(111) at the Wafer Scale and Lift-Off to Produce Flexible and Transparent Foils

The wide bandgap p-type metal pseudohalide semiconductor copper(I) thiocyanate (CuSCN) can serve as a transparent hole transport layer in various opto-electronic applications such as perovsksite and organic solar cells and light-emitting diodes. The material deposits as one-dimensional CuSCN nanorod arrays, which are advantageous due to their high surface area and good charge transport properties. However, the growth of high-quality epitaxial CuSCN nanorods has remained a challenge. Here, we introduce a low cost and highly scalable room temperature procedure for producing epitaxial CuSCN nanorods on Au(111) by an electrochemical method. Epitaxial CuSCN grows on Au(111) with a high degree of in-plane as well as out-of-plane order with +0.22% coincidence site lattice mismatch. The phase of CuSCN that deposits is a function of the Cu2+/SCN- ratio in the deposition bath. A pure rhombohedral material deposits at higher SCN- concentrations, whereas a mixture of rhombohedral and hexagonal phases deposits at lower SCN- concentrations. A Au/epitaxial CuSCN/Ag diode has a diode quality factor of 1.4, whereas a diode produced with polycrystalline CuSCN has a diode quality factor of 2.1. A highly ordered foil of CuSCN was produced by epitaxial lift-off following a triiodide etch of the thin Au substrate. The 400 nm-thick CuSCN foil had an average 94% transmittance in the visible range and a 3.85 eV direct bandgap