⁸⁷Sr/⁸⁶Sr chemostratigraphy of Neoproterozoic Dalradian limestones of Scotland and Ireland: constraints on depositional ages and time scales

New calcite <sup>87</sup>Sr/<sup>86</sup>Sr data for 47 limestones from the metamorphosed and deformed Neoproterozoic-Cambrian Dalradian Supergroup of Scotland and Ireland are used to identify secular trends in seawater <sup>87</sup>Sr/<sup>86</sup>Sr through the Dalradian succession and to constrain its depositional age. Dalradian limestones commonly have Sr greater than 1000 ppm, indicating primary aragonite and marine diagenesis. Low Mn, Mn/Sr less than 0.6, ë<sup>18</sup>O and trace element data indicate that many <sup>87</sup>Sr/<sup>86</sup>Sr ratios are unaltered since diagenesis despite greenschist- to amphibolite-facies metamorphism, consistent with the documented behaviour of Sr and O during metamorphic fluid-rock interaction. Thus, the <sup>87</sup>Sr/<sup>86</sup>Sr data are interpreted largely to reflect <sup>87</sup>Sr/<sup>86</sup>Sr of coeval seawater. Currently available data show that Neoproterozoic seawater <sup>87</sup>Sr/<sup>86</sup>Sr rose from c. 0.7052 at 850-900 Ma to c. 0.7085 or higher in the latest Neoproterozoic. Temporal changes at c. 800 Ma and c . 600 Ma bracket the range in <sup>87</sup>Sr/<sup>86</sup>Sr values of calcite in Grampian. Appin and lowest Argyll Group (c.0.7064-0.7072) and middle and uppermost Argyll Group (c. 0.7082-0.7095) limestones, consistent with a rise in seawater <sup>87</sup>Sr/<sup>86</sup>Sr around 600 Ma. <sup>87</sup>Sr/<sup>86</sup>Sr data are consistent with the sedimentary affinity of the Islay Subgroup with the underlying Appin Group, and with a possible time interval between deposition of Islay and Easdale Subgroup rocks. They indicate that the Dalradian, as a whole, is younger than c. 800 Ma

Long-term memory of subduction processes in the lithospheric mantle: evidence from the geochemistry of basic dykes in the Gardar Province of South Greenland

The rift-related magmas of the Proterozoic Gardar Igneous Province were emplaced across the contact between the South Greenland Archaean craton and the Palaeoproterozoic Ketilidian mobile belt. It has been suggested that the geochemistry of Gardar intrusive rocks in the two areas varies across the craton margin and that this reflects a lithospheric control. However, comparison of the geochemical and isotopic signatures of basic and ultrabasic dykes from across the area shows that there is no systematic variation related to the age of the country rock. All the Gardar basic rocks are inferred to have been derived from the mantle, with relatively little crustal contamination. We suggest that the lithospheric mantle beneath the Gardar Province was enriched by slab-derived fluids during the Ketilidian orogeny (c. 1800 Ma). Subsequent melting of this mantle source was promoted during Gardar rifting when volatile-rich, small-degree melts from the asthenosphere were introduced into the lithospheric mantle, forming enriched metasomites. Ultrabasic lamprophyre dykes in the Gardar Province represent melts derived largely from these metasomites, whereas basaltic magmas were formed by larger-scale melting of the lithospheric mantle, inheriting a subductionrelated signature. There is no evidence that the Gardar magmas were derived from a highly enriched lithospheric keel that had existed since craton formation

A reactive assimilation model for regional-scale cordierite-bearing granitoids: geochemical evidence from the Late Variscan granites of the Central Iberian Zone, Spain

Regional scale biotite and cordierite-bearing granites (s.l.) in the Variscan of the Central Iberian Zone (CIZ) are spatially closely associated with cordierite-rich nebulites and cordierite-bearing two-mica granites, and with cordierite-rich high grade hornfelses and cordieritites (>60% cordierite) that are relatively common in the aureoles of these granites. Building on published field evidence, petrological data are presented which, combined with new chemical and isotopic (Sr-Nd) modelling, indicate that the cordierite-bearing granites cannot be derived by simple anatexis of regional sedimenatry protoliths; but the data are consistent with a process of reactive assimilation that involves the interaction of biotite granite magma with high-grade host rocks ranging from cordierite nebulites to andalusite-bearing cordieritites. The contribution of the postulated cordierite-rich contaminants to the diversity of cordierite granite compositions is modelled using the compositions of regional Lower Cambrian-Upper Neoproterozoic metasedimentary rocks that are generally chemically mature (CaO very rarely exceeds 1.4%). These rocks include specific horizons in which extreme chemical alteration is attributable to sediment reworking during eustatic falls in sea level. Such compositions may account for the presence of the high concentrations in Al that later produced cordieritites. Fractional crystallisation is also important, particularly in generating the more evolved cordierite granite and cordierite biotite muscovite granite compositions. Although assimilation in situ is normally regarded as a minor contributor volumetrically to evolving plutons, in this instance the emplacement of large volumes of granite magma into a high-T-low-P environment significantly increased the potential for reactive assimilation

Trace element and isotope constraints on crustal anatexis by upwelling mantle melts in the North Atlantic Igneous Province: an example form the Isle of Rum, NW Scotland

Sr and Nd isotope ratios, together with lithophile trace elements, have been measured in a representative set of igneous rocks and Lewisian gneisses from the Isle of Rum in order to unravel the petrogenesis of the felsic rocks that erupted in the early stages of Palaeogene magmatism in the North Atlantic Igneous Province (NAIP). The Rum rhyodacites appear to be the products of large amounts of melting of Lewisian amphibolite gneiss. The Sr and Nd isotopic composition of the magmas can be explained without invoking an additional granulitic crustal component. Concentrations of the trace element Cs in the rhyodacites strongly suggests that the gneiss parent rock had experienced Cs and Rb loss prior to Palaeogene times, possibly during a Caledonian event. This depletion caused heterogeneity with respect to 87Sr/86Sr in the crustal source of silicic melts. Other igneous rock types on Rum (dacites, early gabbros) are mixtures of crustalmelts and and primarymantle melts. Forward Rare Earth Element modelling shows that late stage picritic melts on Rum are close analogues for the parent melts of the Rum Layered Suite, and for the mantle melts that caused crustal anatexis of the Lewisian gneiss. These primary mantle melts have close affinities to Mid-Oceanic Ridge Basalts (MORB), whose trace element content varies from slightly depleted to slightly enriched. Crustal anatexis is a common process in the rift-to-drift evolution during continental break-up and the formation of Volcanic Rifted Margins systems. The ‘early felsic–later mafic’ volcanic rock associations from Rum are compared to similar associations recovered from the now-drowned seaward-dipping wedges on the shelf of SE Greenland and on the Vøring Plateau (Norwegian Sea). These three regions show geochemical differences that result from variations in the regional crustal composition and the depth at which crustal anatexis took place

142Nd/144Nd Inferences on the nature and origin of the source of high 3He/4He magmas

High-precision measurements of 142Nd/144Nd in picrites from the Baffin Bay region that contain the highest 3He/4He ratios yet measured in terrestrial mantle-derived rocks are indistinguishable from the value measured in the terrestrial standard and other modern mantle-derived rocks. The Baffin Island lavas are distinguished from other hotspot lavas by their unusually high 3He/4He and 182W/184W ratios, but their Sr, 142Nd, 143Nd, Hf, and Pb isotopic signatures overlap the values measured in North Atlantic MORB. These features imply either that the mantle source region of high 3He/4He magmas carries the lithophile isotopic signatures of incompatible element depletion, or that the He isotope signature of this source is decoupled from the lithophile isotope tracers in the magmas. The coupled 142Nd–143Nd data are consistent with the magma source acquiring the incompatible element depletion during, or shortly after, Earth formation if the bulk-Earth has a 142Nd/144Nd ratio more similar to the average measured for enstatite chondrites than modern terrestrial rocks. If Earth's initial 142Nd/144Nd was higher than the average of enstatite chondrites, the data are consistent with the traditional interpretation that the depleted-mantle reservoir was formed through the extraction of an incompatible-element-rich reservoir, such as continental crust, after the circa 4 Ga extinction of 146Sm. This explanation, however, fails to account for the high 3He/4He. The Nd isotopic composition of the picrites could reflect a dominant contribution from the incompatible element depleted source of North Atlantic MORB, overprinted by a small (10–20%) contribution from a mantle source with He concentrations at least ten times higher than the depleted mantle along with W isotopic compositions substantially higher than typical of mantle-derived rocks

Reconstruction of deglacial sea surface temperatures in the tropical Pacific from selective analysis of a fossil coral

The Sr/Ca of coral skeletons demonstrates potential as an indicator of sea surface temperatures (SSTs). However, the glacial-interglacial SST ranges predicted from Sr/Ca of fossil corals are usually higher than from other marine proxies. We observed infilling of secondary aragonite, characterised by high Sr/Ca ratios, along intraskeletal pores of a fossil coral from Papua New Guinea that grew during the penultimate deglaciation (130 +/- 2 ka). Selective microanalysis of unaltered areas of the fossil coral indicates that SSTs at similar to 130 ka were &lt;= 1 degrees C cooler than at present in contrast with bulk measurements ( combining infilled and unaltered areas) which indicate a difference of 6-7 degrees C. The analysis of unaltered areas of fossil skeletons by microprobe techniques may offer a route to more accurate reconstruction of past SSTs.</p

High-MgO lavas associated to CFB as indicators of plume-related thermochemical effects: the case of ultra-titaniferous picrite-basalt from the Northern Ethiopian-Yemeni plateau

A comprehensive petrological and geochemical dataset is reported in order to define the thermo-compositional characteristics of Ti (Fe)-enriched picrite-basalt lavas (HT2, TiO2 3-7 wt%), erupted close to the axial zone of the inferred Afar mantle plume, at the centre of the originally continuous Ethiopian-Yemeni CFB plateau (ca. 30Ma) which is zonally arranged with progressively lower Ti basalts (HT1, TiO2 2-4 wt%; LT, TiO2 1-3 wt%) toward the periphery. Integrated petrogenetic modelling based on major and trace element analyses of bulk rocks, minerals and melt inclusions in olivines, as well as Sr-Nd-Pb-He-O isotope compositional variations enables us to make several conclusions. 1) The phase equilibria constraints indicate that HT2 primary picrites were generated at ca. 1570°C mantle potential temperatures (Tp) in the pressure range 4-5 GPa whereas the HT1 and LT primary melts formed at shallower level (&lt; 2 to 3 GPa, Tp 1530 °C for HT1 and 1430°C for LT). Thus the Afar plume head was a thermally and compositionally zoned melting region with maximum excess temperatures of 300-350°C with respect to the ambient mantle. 2) The HT2 primary melts upwelled nearly adiabatically to the base of the continental crust (ca. 1 GPa) where fractionation of olivine, followed by clinopyroxene, led to variably differentiated picritic and basaltic magmas. 3) Trace element modelling requires that the primary HT2 melts were generated - either by fractional or batch melting (F 9-10%) - from a mixed garnet peridotite source (85%) with 15% eclogite (derived from transitional MORB protoliths included in Panafrican terranes) that has to be considered a specific Ti-Fe and incompatible element enriched component entrained by the Afar plume. 4) The LT, HT1 and HT2 lavas have 143Nd/144Nd = 0.5131-0.5128, whereas Sr-Pb isotopes are positively correlated with TiO2, varying from 87 Sr/86Sr 0.7032 and 206Pb/204Pb 18.2 in LT basalts to 87Sr/86Sr 0.7044 and 206Pb/204Pb 19.4 in HT2 picrite-basalts. High 3He/4He (15-20 RA) ratios are exclusively observed in HT2 lavas, confirming earlier evidence that these magmas require a component of deep mantle in addition to eclogite, while the LT basalts may more effectively reflect the signature of the pre-existing mantle domains. The comparison between high-MgO (13-22%) lavas from several Phanerozoic CFB provinces (Karoo, Paranà-Etendeka, Emeishan, Siberia, Deccan, North Atlantic Province) shows that they share extremely high mantle potential temperatures (Tp 1550-1700°C) supporting the view that hot mantle plumes are favoured candidates for triggering many LIPs. However, the high incompatible element and isotopic variability of these high-MgO lavas (and associated CFB) suggest that plume thermal anomalies are not necessarily accompanied by significant and specific chemical effects, which depend on the nature of mantle materials recycled during the plume rise, as well as by the extent of related mantle enrichments (if any) on the pre-existing lithospheric section

Coaches’ views on differences in treatment style for male and female clients.

Men are generally more reluctant than women to seek psychological help, perhaps because of negative preconceptions about therapy. We interviewed 20 life coaches to find out whether they had seen gender differences in expectations and outcomes regarding coaching in their male and female clients. Analysis of the interviews, using the grounded theory method, revealed that although almost all coaches described gender differences in help seeking and treatment preferences in their clients, most coaches demonstrated ambivalence about describing such gender differences. Findings are discussed both in terms of cognitive dissonance theory, and in terms of the beta bias hindering the recognition of gender differences. These findings have implications for how coaches (and psychotherapists, psychologists etc) can improve the delivery of their therapy

Macroscopic and spectroscopic analysis of lanthanide adsorption to bacterial cells

This study was designed to combine surface complexation modelling of macroscopic adsorption data with X-ray Absorption Spectroscopic (XAS) measurements to identify lanthanide sorption sites on the bacterial surface. The adsorption of selected representatives for light (La and Nd), middle (Sm and Gd) and heavy (Er and Yb) lanthanides was measured as a function of pH, and biomass samples exposed to 4 mg/L lanthanide at pH 3.5 and 6 were analysed using XAS. Surface complexation modelling was consistent with the light lanthanides adsorbing to phosphate sites, whereas the adsorption of middle and heavy lanthanides could be modelled equally well by carboxyl and phosphate sites. The existence of such mixed mode coordination was confirmed by Extended X-ray Absorption Fine Structure (EXAFS) analysis, which was also consistent with adsorption to phosphate sites at low pH, with secondary involvement of carboxyl sites at high adsorption density (high pH). Thus, the two approaches yield broadly consistent information with regard to surface site identity and lanthanide coordination environment. Furthermore, spectroscopic analysis suggests that coordination to phosphate sites is monodentate at the metal/biomass ratios used. Based on the best-fitting pKa site, we infer that the phosphate sites are located on N-acetylglucosamine phosphate, the most likely polymer on gram-negative cells with potential phosphate sites that deprotonate around neutral pH