A study of industrial hydrogen and syngas supply systems

The potential and incentives required for supplying hydrogen and syngas feedstocks to the U.S. chemical industry from coal gasification systems were evaluated. Future hydrogen and syngas demand for chemical manufacture was estimated by geographic area and projected economics for hydrogen and syngas manufacture was estimated with geographic area of manufacture and plant size as parameters. Natural gas, oil and coal feedstocks were considered. Problem areas presently affecting the commercial feasibility of coal gasification discussed include the impact of potential process improvements, factors involved in financing coal gasification plants, regulatory barriers affecting coal gasification, coal mining/transportation, air quality regulations, and competitive feedstock pricing barriers. The potential for making coal gasification the least costly H2 and syngas supply option. Options to stimulate coal gasification system development are discussed

ncIDP-assign: a SPARKY extension for the effective NMR assignment of intrinsically disordered proteins

Summary: We describe here the ncIDP-assign extension for the popular NMR assignment program SPARKY, which aids in the sequence-specific resonance assignment of intrinsically disordered proteins (IDPs). The assignment plugin greatly facilitates the effective matching of a set of connected resonances to the correct position in the sequence by making use of IDP random coil chemical shifts

Generalized Jordan-Wigner Transformations

We introduce a new spin-fermion mapping, for arbitrary spin $S$ generating the SU(2) group algebra, that constitutes a natural generalization of the Jordan-Wigner transformation for $S=1/2$. The mapping, valid for regular lattices in any spatial dimension $d$, serves to unravel hidden symmetries in one representation that are manifest in the other. We illustrate the power of the transformation by finding exact solutions to lattice models previously unsolved by standard techniques. We also present a proof of the existence of the Haldane gap in $S=$1 bilinear nearest-neighbors Heisenberg spin chains and discuss the relevance of the mapping to models of strongly correlated electrons. Moreover, we present a general spin-anyon mapping for the case $d \leq 2$.Comment: 5 pages, 1 psfigur

Topological Excitations in Compact Maxwell-Chern-Simons Theory

We construct a lattice model of compact (2+1)-dimensional Maxwell-Chern- Simons theory, starting from its formulation in terms of gauge invariant quantities proposed by Deser and Jackiw. We thereby identify the topological excitations and their interactions. These consist of monopolo- antimonopole pairs bounded by strings carrying both magnetic flux and electric charge. The electric charge renders the Dirac strings observable and endows them with a finite energy per unit length, which results in a linearly confining string tension. Additionally, the strings interact via an imaginary, topological term measuring the (self-) linking number of closed strings.Comment: harvmac, CERN-TH. 6906/93, DFUPG 80/9

Beyond the Singularity of the 2-D Charged Black Hole

Two dimensional charged black holes in string theory can be obtained as exact (SL(2,R)xU(1))/U(1) quotient CFTs. The geometry of the quotient is induced from that of the group, and in particular includes regions beyond the black hole singularities. Moreover, wavefunctions in such black holes are obtained from gauge invariant vertex operators in the SL(2,R) CFT, hence their behavior beyond the singularity is determined. When the black hole is charged we find that the wavefunctions are smooth at the singularities. Unlike the uncharged case, scattering waves prepared beyond the singularity are not fully reflected; part of the wave is transmitted through the singularity. Hence, the physics outside the horizon of a charged black hole is sensitive to conditions set behind the past singularity.Comment: 19 pages, 5 figures; v2: refs added, minor typos corrected; v3: references on the infinite blue shift at the inner horizon and minor corrections adde

Asymptotic conditions of motion for radiating charged particles

Approximate asymptotic conditions on the motion of compact, electrically charged particles are derived within the framework of general relativity using the Einstein- Infeld-Hoffmann (EIH) surface integral method. While superficially similar to the Abraham-Lorentz and Lorentz-Dirac (ALD) equations of motion, these conditions differ from them in several fundamental ways. They are not equations of motion in the usual sense but rather a set of conditions which these motions must obey in the asymptotic future of an initial value surface. In addition to being asymptotic, these conditions of motion are approximate and apply, as do the original EIH equations, only to slowly moving systems. Also, they do not admit the run- away solutions of these other equations. As in the original EIH work, they are integrability conditions gotten from integrating the empty-space (i.e., source free) Einstein-Maxwell equations of general relativity over closed two-surfaces surrounding the sources of the fields governed by these equations. No additional ad hoc assumptions, such as the form of a force law or the introduction of inertial reaction terms, needed to derive the ALD equations are required for this purpose. Nor is there a need for any of the infinite mass renormalizations that are required in deriving these other equations.Comment: 15 page

Chern_simons Theory of the Anisotropic Quantum Heisenberg Antiferromagnet on a Square Lattice

We consider the anisotropic quantum Heisenberg antiferromagnet (with anisotropy $\lambda$) on a square lattice using a Chern-Simons (or Wigner-Jordan) approach. We show that the Average Field Approximation (AFA) yields a phase diagram with two phases: a Ne{\`e}l state for $\lambda>\lambda_c$ and a flux phase for $\lambda<\lambda_c$ separated by a second order transition at $\lambda_c<1$. We show that this phase diagram does not describe the $XY$ regime of the antiferromagnet. Fluctuations around the AFA induce relevant operators which yield the correct phase diagram. We find an equivalence between the antiferromagnet and a relativistic field theory of two self-interacting Dirac fermions coupled to a Chern-Simons gauge field. The field theory has a phase diagram with the correct number of Goldstone modes in each regime and a phase transition at a critical coupling $\lambda^* > \lambda_c$. We identify this transition with the isotropic Heisenberg point. It has a non-vanishing Ne{\` e}l order parameter, which drops to zero discontinuously for $\lambda<\lambda^*$.Comment: 53 pages, one figure available upon request, Revte

Site-specific perturbations of alpha-synuclein fibril structure by the Parkinson's disease associated mutations A53T and E46K.

PMCID: PMC3591419This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.Parkinson's disease (PD) is pathologically characterized by the presence of Lewy bodies (LBs) in dopaminergic neurons of the substantia nigra. These intracellular inclusions are largely composed of misfolded α-synuclein (AS), a neuronal protein that is abundant in the vertebrate brain. Point mutations in AS are associated with rare, early-onset forms of PD, although aggregation of the wild-type (WT) protein is observed in the more common sporadic forms of the disease. Here, we employed multidimensional solid-state NMR experiments to assess A53T and E46K mutant fibrils, in comparison to our recent description of WT AS fibrils. We made de novo chemical shift assignments for the mutants, and used these chemical shifts to empirically determine secondary structures. We observe significant perturbations in secondary structure throughout the fibril core for the E46K fibril, while the A53T fibril exhibits more localized perturbations near the mutation site. Overall, these results demonstrate that the secondary structure of A53T has some small differences from the WT and the secondary structure of E46K has significant differences, which may alter the overall structural arrangement of the fibrils

Very Long Time Scales and Black Hole Thermal Equilibrium

We estimate the very long time behaviour of correlation functions in the presence of eternal black holes. It was pointed out by Maldacena (hep-th 0106112) that their vanishing would lead to a violation of a unitarity-based bound. The value of the bound is obtained from the holographic dual field theory. The correlators indeed vanish in a semiclassical bulk approximation. We trace the origin of their vanishing to the continuum energy spectrum in the presence of event horizons. We elaborate on the two very long time scales involved: one associated with the black hole and the other with a thermal gas in the vacuum background. We find that assigning a role to the thermal gas background, as suggested in the above work, does restore the compliance with a time-averaged unitarity bound. We also find that additional configurations are needed to explain the expected time dependence of the Poincar\'e recurrences and their magnitude. It is suggested that, while a semiclassical black hole does reproduce faithfully ``coarse grained'' properties of the system, additional dynamical features of the horizon may be necessary to resolve a finer grained information-loss problem. In particular, an effectively formed stretched horizon could yield the desired results.Comment: 30 pages, harvmac, 1 eps figur