Efficient degradation and mineralization of diclofenac in water on ZnMe (Me: Al; Co; Ga) layered double hydroxides and derived mixed oxides as novel photocatalysts

The removal of diclofenac (DCF) from aqueous solutions was attempted using photocatalytic processes, involving a series of novel photocatalysts based on ZnMe (Me: Al; Co; Ga) layered double hydroxides (LDHs) and their derived mixed oxides. The catalysts were characterized using specific techniques. Under solar light, ZnCo and ZnGa catalysts degraded almost completely DCF from water, while the mineralization, expressed by total organic carbon removal, reached $\sim$85%. The degradation mechanisms of DCF photolysis and photocatalytic degradation under solar and UV irradiation were investigated

Synthesis and characterization of catalytic metal semiconductor-doped siliceous materials with ordered structure for chemical sensoring

Sensing materials based on doped mesoporous silica of SBA-15 type were obtained by repeated wet impregnation of the solid with semiconductive oxides (Sn and In) and noble metal (Pt). The mesoporous structure of SBA was preserved during the doping and calcination of the solid, although slight pore size narrowing occurred as shown by the BET adsorption analysis. The solid was deposited by the casting technique as a thin layer on a finger structure. The modifications of its electrical resistance values in the presence of hydrogen and propene (50–400 ppm), at temperature values of 450 °C was used as sensing parameter, in the presence of propene and hydrogen. The sensitivity to propene was higher than that to hydrogen