Metal sources for the Katanga Copperbelt deposits (DRC) insights from Sr and Nd isotope ratios

The ore deposits of the Central African Copperbelt formed during a multiphase mineralisation process. The basement underlying the Neoproterozoic Katanga Supergroup that hosts the ore, demonstrates the largest potential as metal source. Various ore deposits that formed during different mineralisation phases are taken as case studies, i.e. Kamoto, Luiswishi, Kambove West, Dikulushi and Kipushi (Democratic Republic of Congo, DRC). The Sr and Nd isotopic compositions of gangue carbonates associated with these deposits is determined and compared with those of rocks from several basement units, bordering or underlying the Copperbelt, to infer the metal sources. The mineralising fluid of diagenetic stratiform Cu-Co mineralisation interacted with felsic basement rocks underlying the region. The Co from these deposits is most likely derived from mafic rocks, but this is not observed in the isotopic signatures. Syn-orogenic, stratabound Cu-Co mineralisation resulted mainly from remobilisation of diagenetic sulphides. A limited, renewed contribution of metals from felsic basement rocks might be indicated by the isotope ratios in the western part of the Copperbelt, where the metamorphic grade is the lowest. The mineralising fluid of syn- and post-orogenic, vein-type mineralisations interacted with local mafic rocks, and with felsic basement or siliciclastic host rocks

From volcanic rock powder to Sr and Pb isotope ratios : a fit-for-purpose procedure for multi-collector ICP–mass spectrometric analysis

Geochemical research into volcanic rocks often involves isotopic analysis of whole rock powders. The method of Deniel and Pin (Anal. Chim. Acta, 2001, 426, 95-103) for simultaneous isolation of strontium and lead using extraction chromatography via Sr spec (TM) resin was therefore adapted into a straightforward procedure for Sr and Pb isotope ratio determination by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). The main focus was to reduce their rather extensive and costly cleaning procedures for resin and columns without negatively affecting data quality. It was furthermore demonstrated that non-quantitative Sr and Pb recoveries do not compromise the quality of the isotope data obtained and that no Pb isotopic fractionation occurs on the Sr spec (TM) resin. The accuracy of the analyses was assessed by monitoring rock reference materials. GSJ basalt JB-2, commonly regarded as the most homogeneous Pb isotopic rock reference material, hereby produced one anomalous Pb isotopic composition out of eight analyses, suggesting that JB-2 might also be affected by nugget contamination

Late Neoproterozoic–Cambrian magmatism in Dronning Maud Land (East Antarctica): U–Pb zircon geochronology, isotope geochemistry and implications for Gondwana assembly

Postponed access: the file will be available after 2022-07-28Dronning Maud Land (DML) is a key area for the better understanding of the geotectonic history and amalgamation processes of the southern part of Gondwana. Here, we present comprehensive new zircon U–Pb–Hf–O, whole-rock Sm–Nd isotopic and geochemical data for late Neoproterozoic-Cambrian igneous rocks along a profile from central to eastern DML, which provides new insights into the crustal evolution and tectonics of the region. In central DML, magmatism dominantly occurred at 530–485 Ma, with 650–600 Ma charnockite and anorthosite locally distributed at its eastern periphery. In contrast, eastern DML experienced long-term and continuous granitic magmatism from ca. 650 Ma to 500 Ma. In central DML, the 650–600 Ma samples are characterized by highly elevated δ18O (7.5–9.5‰) associated with slightly negative to positive εHf(t) values (−1 to +3), indicating significant addition of high-δ18O crustal components, such as sedimentary material at the margin of the Kalahari Craton. Evolved Hf isotopic signatures (εHf(t) = −15 to −6) and moderately elevated O isotopic data (δ18O = 6–8‰) of the Cambrian granitic rocks from central DML indicate a significant incorporation of the pre-existing, old continental crust. In eastern DML, the suprachondritic Hf–Nd isotope signatures and moderate δ18O values of the late Neoproterozoic granites (650–550 Ma) from the Sør Rondane Mountains support the view that they mainly originated from crust of the Tonian Oceanic Arc Super Terrane (TOAST). The post-540 Ma granites, however, have more evolved Hf and Nd isotopic compositions, suggesting an increasing involvement of older continental components during Cambrian magmatism. Nd isotopes of the Cambrian granitic rocks in DML display an increasingly more radiogenic composition towards the east with model ages ranging from late Archean to Mesoproterozoic times, which is in line with the isotopic trend of the Precambrian basement in this region. The late Neoproterozoic (>600 Ma) igneous rocks in central and eastern DML were emplaced in two independent subduction systems, at the periphery of the eastern Kalahari Craton and somewhere within the Mozambique Ocean respectively. The accretion and assembly of the TOAST to the eastern margin of the Kalahari Craton and their collision with surrounding continental blocks was followed by extensive post-collisional magmatism due to delamination tectonics and orogenic collapse in the Cambrian. The late Neoproterozoic–Cambrian igneous rocks in DML thus record an orogenic cycle from subduction-accretion, continental collision to post-collisional process during and after the assembly of Gondwana.acceptedVersio

Grenville-age continental arc magmatism and crustal evolution in central Dronning Maud Land (East Antarctica): Zircon geochronological and Hf-O isotopic evidence

This study focusses on the Grenville-age Maud Belt in Dronning Maud Land (DML), East Antarctica, which was located at the margin of the Proto-Kalahari Craton during the assembly of Rodinia. We present new U–Pb zircon ages and Hf–O isotope analyses of mafic and granitic gneisses exposed in the Orvin-Wohlthat Mountains and Gjelsvikfjella, central DML (cDML). The geochronological data indicate continuous magmatic activity from 1160 to 1070 Ma which culminated at 1110–1090 Ma, followed by high-grade metamorphism between 1080 and 1030 Ma. The majority of zircons from the Orvin-Wohlthat Mountains exhibit radiogenic Hf isotopic compositions corresponding to suprachondritic εHf (t) values and Mesoproterozoic model ages, indicating crystallization from predominantly juvenile magmas. However, the involvement of ancient sedimentary material, which were most likely derived from the adjacent Proto-Kalahari Craton, is revealed by a few samples with negative to neutral εHf (t) and significantly elevated δ18O values (8–10‰). Samples from further west, in Gjelsvikfjella have more mantle-like zircon O isotopic compositions and late Paleoproterozoic Hf model ages, indicating the incorporation of ancient, previously mantle-derived continental crust. The rocks in cDML, thus define part of an extensive Mesoproterozoic magmatic arc with subduction under the Proto-Kalahari margin. This involved significant growth of new continental crust, possibly related to slab retreat, accompanied by subordinate recycling of older crustal components. The Maud Belt has previously been correlated with the 1250–1030 Ma Natal Belt in southern Africa, which lay to the west in the context of Gondwana, although this assertion has recently been questioned. Our study supports the latter view in demonstrating that the continental arc magmatism in the Maud Belt appears to be temporally and tectonically unconnected to the accretion of (slightly older) juvenile oceanic islands in the Natal Belt, which, in contrast to the Maud Belt, show subduction polarity away from the craton. We thus speculate that the Namaqua-Natal to Maud Belt contact (exposed in the Heimefront Shear Zone) may represent a changed tectonic environment from arc/continent-continent collision to slightly younger continental margin orogenesis at the westernmost termination of this part of the global Grenville Orogen. The Maud Belt marks the beginning of a major, long-lived accretionary Andean-type tectonic regime on the eastern margin of Proto-Kalahari in the Meso-Neoproterozoic during Rodinia assembly and break-up until the formation of Gondwana.acceptedVersio

Sr isotopes in arcs revisited: tracking slab dehydration using δ88/86Sr and 87Sr/86Sr systematics of arc lavas

Dehydration of the subducting slab is a crucial process in the generation of hydrous convergent margin magmas, yet the exact processes of how and where the slab dehydrates and how these fluids are transported to the mantle wedge remain obscure. Strontium is a “fluid-mobile” element and as such well suited to investigate the source of slab-derived fluids. We employ mass-dependent Sr isotope systematics (δ88/86Sr; the deviation in 88Sr/86Sr of a sample relative to NIST SRM 987) of primitive arc lavas, in tandem with conventional radiogenic 87Sr/86Sr measurements, as a novel tracer of slab dehydration. To characterise the δ88/86Sr composition of subduction zone inputs, we present new δ88/86Sr data for subducting sediments, altered oceanic crust and MORB. Calcareous sediments are isotopically lighter and carbonate-free sediments are isotopically heavier than mid-ocean ridge basalts (MORB). Samples of the altered oceanic crust display elevated 87Sr/86Sr but only the most intensely altered sample has significantly higher δ88/86Sr than pristine MORB. Mafic arc lavas from the Aegean and Mariana arc invariably have a mass-dependent Sr isotope composition that is indistinguishable from MORB and lower 87Sr/86Sr than upper altered oceanic crust. This δ88/86Sr-87Sr/86Sr signature of the arc lavas, in combination with their high but variable Sr/Nd, can only be explained if it is provided by a fluid that acquired its Sr isotope signature in the deeper, less altered part of the subducted oceanic crust. We propose a model where the breakdown of serpentinite in the slab mantle releases a pulse of fluid at sub-arc depths. These fluids travel through and equilibrate with the overlying oceanic crust and induce wet partial melting of the upper altered crust and sediments. This hydrous melt is then delivered to the mantle source of arc magmas as a single metasomatic component. From mass balance it follows that the slab-derived fluid contributes >70% of the Sr budget of both Mariana and Aegean arc lavas. Whereas this fluid-dominated character is unsurprising for the sediment-poor Mariana arc, the Aegean arc sees the subduction of 3–6 km of calcareous sediments that were found to exert very little control on the Sr budget of the arc magmas and are overwhelmed by the fluid contribution