46 research outputs found
Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex at a glassy carbon electrode in non-aqueous medium
Management information systems - zabezpečení informací
This bachelor work is a research based document. It elaborates briefly on management information systems, their establishment and implementation. It later focuses on their security measures using the support of IS/IT.Tato bakalářská práce se zabývá managementem informačních systémů, jejich bezpečností, tvorbou a implementací. Dále je zaměřena na měření bezpečnosti a na bezpečnost v kontextu IS/IT.Ústav systémového inženýrství a informatikyDokončená práce s úspěšnou obhajobo
ELECTROCHEMICAL OXIDATION OF IODIDE AT A GLASSY CARBON ELECTRODE IN METHYLENE CHLORIDE AT VARIOUS TEMPERATURES
Zum Verhalten von Chlorid an einer Glaskohlenstoffelektrode: Konvolutive cyclische Voltammetrie, Chronopotentiometrie und digitale Simulation
Voltammetric examination of hydroquinone at ordinary and nano-architecture platinum electrodes
The electrochemical behavior of hydroquinone was examined experimentally using cyclic voltammetry, convolution transform, and deconvolution transform at clean ordinary and nanostructured mesoporous platinum electrodes in 1 mol/l HClO4. The cyclic voltammogram of hydroquinone (HQ) at an ordinary Pt electrode displays an anodic peak at 0.610 V and a cathodic peak at 0.117 V, with a scan rate of 50 mV·s–1. Excellent linearity was recorded between the anodic or cathodic peak currents of hydroquinone and the square root of the scan rate (υ1/2). The anodic and cathodic peak potential separation (∆Ep) was found to be 463 ± 3 mV vs. the saturated calomel electrode (SCE). It was noted that the value of peak potential separation increased with increasing the scan rate. The type of electrode reaction at both platinum electrodes in 1 mol/l HClO4 was examined and discussed. The electrochemical parameters and the nature of the mechanistic pathway of the investigated HQ were determined experimentally and ascertained via a numerical simulation method.
Electrochemical Studies of 1,4-Bis[2-(2-pyridyl)-vinyl] Benzene and 1,4-Bis[2-(4-pyridyl) vinyl] Benzene Laser Dyes via Cyclic Voltammetry, Convolutive Voltammetry and Digital Simulation Methods
Voltammetry and determination of metronidazole at a carbon fiber microdisk electrode
The electrochemistry of metronidazole, 1-(hydroxyethyl)-2-methyl-5-nitroimidazole, was investigated at a carbon fiber microdisk electrode in pH 9 Britton Robinson buffer. Under these conditions, the reduction of metronidazole is controlled by both mass transport to the microdisk and adsorption with an equilibrium constant of 4 x 10(3) mol(-1) dm(3) and a saturation coverage of 0.88 x 10(-8) mol cm(-2). The adsorption and accumulation of metronidazole on the surface of the carbon fiber allows its determination at low concentrations by square wave adsorptive stripping voltammetry. A detection limit for metronidazole of 5 x 10(-7) mol dm(-3) and a R.S.D. of 3.7 % at 1 x 10(-6) mol dm(-3) (n = 4) were obtained with a two electrode system with no stirring during the accumulation step. Based on this method, a simple procedure for the determination of metronidazole in urine is described which requires no pre-treatment of the sample before analysis
Coercivity of 3D nanoscale magnetic arrays from self-assembly template methods
We present results of electrochemical deposition of magnetic metals and alloys in the pores of templates prepared by self-assembly from colloidal suspensions of polystyrene latex spheres. This technique has enabled us to create highly ordered magnetic nano-structures with 3D architectures on length scales ranging from 50–1000 nm. Varying the parameters in the preparation (sphere diameter, film thickness and composition) allows us to produce materials with predetermined magnetic parameters